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Influence of Guest Molecules on the Crystal Lattice Structure and Porous Structure Characteristics of Coordination Polymers

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Theoretical and Experimental Chemistry Aims and scope

The influence of guest molecules, including the solvent, on the structure of porous coordination polymers (PCP) and, as a consequence, their adsorption properties is analyzed. It was suggested that the nature of the solvent can predetermine the selectivity of PCP adsorption only when the solvent acts as a template in the formation of such a polymer. In contrast to PCP with rigid crystal lattices, the characteristics of PCP with labile lattices and their adsorption properties depend significantly on the nature of guest molecules.

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The author thanks Prof. V. V. Pavlishchuk, Prof. V. G. Ilyin, and Dr. A. V. Shvets for critical comments offered in a discussion of this work.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine

    S. V. Kolotilov

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  1. S. V. Kolotilov
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Correspondence to S. V. Kolotilov.

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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 51, No. 5, pp. 291–296, September-October, 2015.

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Kolotilov, S.V. Influence of Guest Molecules on the Crystal Lattice Structure and Porous Structure Characteristics of Coordination Polymers. Theor Exp Chem 51, 301–306 (2015). https://doi.org/10.1007/s11237-015-9429-3

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  • DOI: https://doi.org/10.1007/s11237-015-9429-3

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