An effect was found for the size of monodisperse platinum nanoparticles supported on γ-Al2O3 on their catalytic properties in the Fischer–Tropsch synthesis. The rate of formation of the products of the hydrogenation of carbon monoxide increases with increasing diameter of the supported platinum nanoparticles from 2.7 to 8.4 nm. Such behavior may be attributed to a decrease in the heat of adsorption of CO with increasing size of the platinum nanoparticles.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
P. E. Strizhak, Teor. Éksp. Khim., 49, No. 1, 1-19 (2013). [Theor. Exp. Chem., 49, No. 1, 2-21 (2013) (English translation).]
B. Zhou, S. Hermans, and G. A. Somorjai (eds.), Nanotechnology in Catalysts, Vol. 1, Kluwer Academic/Plenum Publ., New York (2004).
D. Astruc, Nanoparticles and Catalysis, Wiley-VCH Verlag, Weinheim (2008), pp. 1-48.
C. J. Kliewer, C. Aliaga, M. Bieri, et al., J. Am. Chem. Soc., 132, No. 37, 13088-13095 (2010).
H. Huang, F. Hu, H. Huang, et al., Chem. Eng. J., 252, 320-326 (2014).
A. M. Gololobov, I. E. Bekk, G. O. Bragina, et al., Kinet. Katal., 50, No. 6, 864-870 (2009).
G. I. Golodets, N. V. Pavlenko, and A. I. Tripolskii, React. Kinet. Catal. Lett., 34, No. 2, 337-376 (1987).
W. Ma, G. Jacobs, R. A. Keogh, et al., Appl. Catal. A, 437/438, 1-9 (2012).
A. Albarazi, P. Beaunier, and P. da Costa, Int. J. Hydrogen Energy, 38, No. 1, 127-139 (2013).
K. M. Cook, H. D. Perez, C. H. Bartholomew, and W. C. Hecker, Appl. Catal. A, 482, 275-286 (2014).
A. L. Lapidus and A. Yu. Krylova, Ros. Khim. Zh., 44, No. 1, 43-56 (2000).
N. V. Pavlenko and G. I. Golodets, Neftepererab. Neftekhim., 39, 23-30 (1990).
R. C. Reuel and C. H. Bartholomew, J. Catal., 85, 78-88 (1984).
Z. V. Kaidanovych, Ye. Yu. Kalishyn, and P. E. Strizhak, Teor. Éksp. Khim., 48, No. 6, 354-358 (2012). [Theor. Exp. Chem., 48, No. 6, 376-380 (2012) (English translation).]
I. B. Bychko, E. Yu. Kalishin, and P. E. Strizhak, Teor. Éksp. Khim., 47, No. 4, 212-216 (2011). [Theor. Exp. Chem., 47, No. 4, 219-224 (2011) (English translation).]
G. I. Golodets, Teor. Éksp. Khim., 21, No. 5, 549-553 (1985). [Theor. Exp. Chem., 21, No. 5, 525-529 (1985) (English translation).]
Y.-W. Huang and S.-I. Lee, Chem. Phys. Lett., 492, 98-102 (2010).
H. Dunken and V. Lygin, Quantenchemie den Adsorption an Estkorperoberflachen, VEB Deutscher Verlag für Grundstoffindustrie, Leipzig (1978).
This work was carried out within the framework of the Joint Program for Basic Research of the National Academy of Sciences of Ukraine “Fundamental problems of nanostructural systems, nanomaterials, and nanotechnology.”
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 50, No. 4, pp. 232-236, July-August, 2014.
Rights and permissions
About this article
Cite this article
Kaidanovych, Z.V., Deinega, I.V., Kalishyn, Y.Y. et al. Influence of Size of Platinum Nanoparticles Supported on γ-Al2O3 on Their Catalytic Properties in CO Hydrogenation. Theor Exp Chem 50, 232–236 (2014). https://doi.org/10.1007/s11237-014-9371-9
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11237-014-9371-9