The Ni-based coatings with different chromium carbide contents were deposited on H4140 steel by a plasma transferred arc process. The corrosion behavior of Ni-based chromium carbide coatings in a 0.5 mol/l HCl solution was studied by means of the potentiodynamic polarization curve, electrochemical impedance, and immersion corrosion test. The coatings were metallurgically bonded with the substrate. The addition of Cr3C2 particles resulted in more Cr-rich carbides in the coatings. In a 0.5 mol/l HCl solution, the four as-received coatings show active anodic dissolution due to the joint action of hydrogen and chlorine ions. With an increase in the Cr3C2 content, the corrosion potential of coatings shifts in the positive direction, the corrosion current density decreases, and the corrosive resistance of the coating is enhanced. The galvanic corrosion occurred between the Cr-rich carbides and the γ-Ni matrix phase, the coatings reinforced with chromium carbide particles showed preferential selective corrosion of the γ-Ni matrix phase. The cracks and pits are migration channels of the corrosion medium into the coating, causing a more serious corrosion damage.
Similar content being viewed by others
References
L. Fan, H. Y. Chen, Y. H. Dong, et al., “Wear and corrosion resistance of laser-cladded Fe-based composite coatings on AISI 4130 steel,” Int. J. Miner. Metall. Mater., 25, 128–140 (2018).
S. S. Liu, H. Y. Chen, X. Zhao, et al., “Corrosion behavior of Ni-based coating containing spherical tungsten carbides in hydrochloric acid solution,” J. Iron Steel Res. Int., 26, 191–199 (2019).
S. W. Huang, M. Samandi, and M. Brandt, “Abrasive wear performance and microstructure of laser clad WC/Ni layers,” Wear, 256, 1095–1105 (2004).
D. Bartkowski, A. Mùynarczak, A. Piasecki, et al., “Microstructure, microhardness and corrosion resistance of Stellite-6 coatings reinforced with WC particles using laser cladding,” Opt. Laser Technol., 68, 191–201 (2015).
J. E. Cho, S. Y. Hwang, and K. Y. Kim, “Corrosion behavior of thermal sprayed WC cermet coatings having various metallic binders in strong acidic environment,” Surf. Coat. Technol., 200, 2653–2662 (2006).
T. Liyanage, G. Fisher, and A. P. Gerlich, “Influence of alloy chemistry on microstructure and properties in NiCrBSi overlay coatings deposited by plasma transferred arc welding (PTAW),” Surf. Coat. Technol., 205, 759–765 (2010).
G. Q. Chen, X. S. Fu, Y. H. Wei, et al., “Microstructure and wear properties of nickel-based surfacing deposited by plasma transferred arc welding,” Surf. Coat. Technol., 228, 276–282 (2013).
D. Kesavan and M. Kamaraj, “The microstructure and high temperature wear performance of a nickel base hardfaced coating,” Surf. Coat. Technol., 204, 4034–4043 (2010).
P. Xu, C. X. Lin, C. Y. Zhou, et al., “Wear and corrosion resistance of laser cladding AISI 304 stainless steel/Al2O3 composite coatings,” Surf. Coat. Technol., 238, 9–14 (2014).
C. S. Ramesh and C. K. Srinivas, “Friction and wear behavior of laser-sintered iron-silicon carbide composites,” J. Mater. Process. Technol., 209, 5429–5436 (2009).
A. Surzhenkov, M. Antonov, D. Goljandin, et al., “High-temperature erosion of Fe-based coatings reinforced with cermet particles,” Surf. Eng., 32, 624–630 (2016).
L. Fan, Y. H. Dong, H. Y. Chen, et al., “Wear properties of plasma transferred arc Fe-based coatings reinforced by spherical WC particles,” J. Wuhan Univ. Technol.-Mater. Sci. Ed., 34, 433–439 (2019).
Z. F. Ni, Y. S. Sun, F. Xue, et al., “Microstructure and properties of austenitic stainless steel reinforced with in situ TiC particulate,” Mater. Design, 32, 1462–1467 (2011).
D. W. Zhang, T. C. Lei, and F. J. Li, “Laser cladding of stainless steel with Ni-Cr3C2 for improved wear performance,” Wear, 251, 1372–1376 (2001).
B. Q. Wang and Z. R. Shui, “The hot erosion behavior of HVOF chromium carbide-metal cermet coatings sprayed with different powders,” Wear, 253, 550–557 (2002).
M. A. Zavareh, A. A. D. Sarhan, B. B. A. Razak, et al., “The tribological and electrochemical behavior of HVOF-sprayed Cr3C2-NiCr ceramic coating on carbon steel,” Ceram. Int., 41, 5387–5396 (2015).
C. O. A. Olsson and D. Landolt, “Passive films on stainless steels-chemistry, structure and growth,” Electrochim. Acta, 48, 1093–1104 (2003).
Y. Wang, S. L. Jiang , Y. G. Zheng, et al., “Electrochemical behaviour of Fe-based metallic glasses in acidic and neutral solutions,” Corros. Sci., 63, 159–173 (2012).
G. Hu, H. Meng, and J. Liu, “Microstructure and corrosion resistance of induction melted Fe-based alloy coating,” Surf. Coat. Technol., 251, 300–306 (2014).
S. F. Guo, F. S. Pan, H. J. Zhang, et al., “Fe-based amorphous coating for corrosion protection of magnesium alloy,” Mater. Design, 108, 624–631 (2016).
S. Katakam, V. Kumar, S. Santhanakrishnan, et al., “Laser assisted Fe-based bulk amorphous coating: Thermal effects and corrosion,” J. Alloys Compd., 604, 266–272 (2014).
A. Davoodi, M. Pakshir, M. Babaiee, et al., “A comparative H2S corrosion study of 304L and 316L stainless steels in acidic media,” Corros. Sci., 53, 399–408 (2011).
Q. L. Wu, W. G. Li, and N. Zhong, “Corrosion behavior of TiC particle-reinforced 304 stainless steel,” Corros. Sci., 53, 4258–4264 (2011).
M. M. Verdian, K. Raeissi, and M. Salehi, “Corrosion performance of HVOF and APS thermally sprayed NiTi intermetallic coatings in 3.5% NaCl solution,” Corros. Sci., 52, 1052–1059 (2010).
Y. Huang and X. Zeng, “Investigation on cracking behavior of Ni-based coating by laser-induction hybrid cladding,” Appl. Surf. Sci., 256, 5985–5992 (2010).
Y. H. Dong, L. Fan, H. Y. Chen, et al., “Corrosion behavior of plasma transferred arc Fe-based coating reinforced by spherical tungsten carbide in hydrochloric acid solutions,” J. Wuhan Univ. Technol.-Mater. Sci. Ed., 35, 299–309 (2020).
J. Wang, L. Li, and W. Tao, “Crack initiation and propagation behavior of WC particles reinforced Fe-based metal matrix composite produced by laser melting deposition,” Opt. Laser Technol., 82, 170–182 (2016).
Acknowledgments
The work was financially supported by the Science & Technology Program of Shanghai Jian Qiao University (No. SJQ19012).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Problemy Prochnosti, No. 1, pp. 107 – 116, January – February, 2021.
Rights and permissions
About this article
Cite this article
Fan, L., Liu, S.S., Chen, H.Y. et al. Corrosion Behavior of Ni-Based Coatings Reinforced with Chromium Carbide Particles Deposited by Plasma Transferred Arc in a Hydrochloric Acid Solution. Strength Mater 53, 106–115 (2021). https://doi.org/10.1007/s11223-021-00266-2
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11223-021-00266-2