Experiments on the uniform distribution of carbon nanotubes in the copper matrix using different ball milling methods were performed. The effect of different preparation processes for carbon nanotube (CNT)-reinforced copper matrix composites on their conductivity and mechanical properties was also analyzed. High-performance carbon nanotube-reinforced copper matrix composites containing 1 vol.% CNT by the best preparation process termed flake ball milling (FBM) possess good interface bonding strength not only with CNT evenly dispersed in the copper matrix but also with the CNT morphology and structure having the utmost integrity. Tensile strength increased by 30% with an elongation of 26% and electrical conductivity of 85% IACS as compared to a pure copper block prepared from the same FBM powders.
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Y. S. Chen, A. Malkovskiy, X. Q. Wang, et al., “Selection of single-walled carbon nanotube with narrow diameter distribution by using a PPE–PPV copolymer,” ACS Macro Lett., 1, 246–251 (2012).
J. D. Leeds, J. T. Fourkas, and Y. Wang, “Achieving ultrahigh concentrations of fluorescent single-walled carbon nanotubes using small-molecule viscosity modifiers,” Small, 9, 241–247 (2013).
X. Q. Wang and Y. Pang, “Selective dispersion of single-walled carbon nanotubes by a cationic surfactant,” RSC Adv., 3, Issue 47, 25097–25102 (2013).
S. Rotkin and Y. Gogotsi, “Analysis of non-planar graphitic structures: from arched edge planes of graphite crystals to nanotubes,” Mater. Res. Innov., 5, 191–200 (2002).
S. I. Cha, K. T. Kim, S. N. Arshad, et al., “Extraordinary strengthening effect of carbon nanotubes in metal-matrix nanocomposites processed by molecular-level mixing,” Adv. Mater., 17, 1377–1381 (2005).
H. S. Kwon, M. Estili, K. Takagi, et al., “Combination of hot extrusion and spark plasma sintering for producing carbon nanotube reinforced aluminum matrix composites,” Carbon, 47, 570–577 (2009).
C. He, N. Q. Zhao, C. S. Shi, et al., “An approach to obtaining homogeneously dispersed carbon nanotubes in Al powders for preparing reinforced Al-matrix composites,” Adv. Mater., 19, 1128–1132 (2007).
X. Z. Kai, Z. Q. Li, G. L. Fan, et al., “Strong and ductile particulate reinforced ultrafine-grained metallic composites fabricated by flake powder metallurgy,” Scripta Mater., 68, 555–558 (2013).
L. Jiang, Z. Q. Li, X. Z. Kai, et al., “An approach to the uniform dispersion of a high volume fraction of carbon nanotubes in aluminum powder,” Carbon, 49, 1965–1971 (2011).
L. Jiang, Z. Q. Li, G. L. Fan, et al., “The use of flake powder metallurgy to produce carbon nanotube (CNT)/aluminum composites with a homogenous CNT distribution,” Carbon, 50, 1993–1998 (2012).
H. J. Choi, G. B. Kwon, G. Y. Lee, and D. H. Bada, “Reinforcement with carbon nanotubes in aluminum matrix composites,” Scripta Mater., 59, 360–363 (2008).
H. Li, A. Misra, Z. Horita, et al., “Strong and ductile nanostructured Cu-carbon nanotube composite,” Appl. Phys. Lett., 95, 071907-1–071907-3 (2009).
Z. Y. Liu, B. L. Xiao, W. G. Wang, and Z. Y. Ma, “Developing high-performance aluminum matrix composites with directionally aligned carbon nanotubes by combining friction stir processing and subsequent rolling,” Carbon, 62, 35–42 (2013).
S. J. Yoo, S. H. Han, and W. J. Kim, “A combination of ball milling and high-ratio differential speed rolling for synthesizing carbon nanotube/copper composites,” Carbon, 61, 487–500 (2013).
D. H. Nam, Y. K. Kim, S. I. Cha, and S. H. Hong, “Effect of CNTs on precipitation hardening behavior of CNT/Al–Cu composites,” Carbon, 50, 4809–4814 (2012).
D. H. Nam, S. I. Cha, B. K. Lim, et al., “Synergistic strengthening by load transfer mechanism and grain refinement of CNT/Al–Cu composites,” Carbon, 50, 2417–2423 (2012).
J. Y. Hwang, B. K. Lim, J. Tiley, et al., “Interface analysis of ultra-high strength carbon nanotube/nickel composites processed by molecular level mixing,” Carbon, 57, 282–287 (2013).
K. T. Kim, J. Eckert, S. B. Menzel, et al., “Grain refinement assisted strengthening of carbon nanotube reinforced copper matrix nanocomposites,” Appl. Phys. Lett., 92, 121901-1–121901-3 (2008).
K. T. Kim, S. I. Cha, T. Gemming, et al., “The role of interfacial oxygen atoms in the enhanced mechanical properties of carbon-nanotube reinforced metal matrix nano-composites,” Small, 4, 1936–1940 (2008).
F. Wang, S. Arai, and M. Endo, “The preparation of multi-walled carbon nanotubes with a Ni–P coating by an electroless deposition process,” Carbon, 43, 1716–1721 (2005).
Acknowledgments
The authors would like to thank Z. C. Wang, Y. T. Wen and other members of the School of National Defense Science & Technology, Yanshan University. This study was supported by the National Basic Research Program of China (2010CB71600).
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Translated from Problemy Prochnosti, No. 1, pp. 164 – 171, January – February, 2015.
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Guo, C.H., Zhan, Z.J. & Zhang, D.D. Influence of Different Preparation Processes on the Mechanical Properties of Carbon Nanotube-Reinforced Copper Matrix Composites. Strength Mater 47, 143–149 (2015). https://doi.org/10.1007/s11223-015-9640-4
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DOI: https://doi.org/10.1007/s11223-015-9640-4