The absorption spectra of water molecules enclosed in cavities of nanoscale silicon pores have been experimentally recorded. Experimental data have been interpreted within the framework of the approximation of absorption spectra by Gaussian-type contours. Experimental dependences of the intensity of these contours on the pore size are obtained. To interpret this dependence for the contour corresponding to chemically noninteracting particles, the mathematical apparatus of the analytical description of the thermodynamic ideal gas properties is used. The position of the extremes of the experimental curve is accurately described with the appropriate choice of the approximation parameter of the model under consideration.
Similar content being viewed by others
References
Yu. A. Efimov and Yu. I. Naberukhin, Faraday Discuss. Chem. Soc., 85, 117–123 (1988).
L. N. Sinitsa and A. A. Lugovskoy, J. Chem. Phys., 133, 204506 (1–5) (2010).
A. Del Maestro, N. S. Nichols, T. R. Prisk, et al., Nature Commun., 13, 3168 (2022).
J. I. Kapusta and C. Gale, Finite-Temperature Field Theory, Cambridge University Press, New York (2006).
Yu. B. Rumer and M. Sh. Ryvkin, Thermodynamics, Statistical Physics, and Kinetics, Mir, Moscow (1980).
P. O. Kazinski and M. A. Shipulya, Ann. Phys., 10, No. 326, 2658–2693 (2011).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 63–67, October, 2022.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Lugovskoy, A.A., Shipulya, M.A. Nonextensive Contributions to the Effective Action of an Ensemble of Chemically Non-Interacting H2O Molecules Enclosed in the Cavity of Nanoscale SiO2 Pores. Russ Phys J 65, 1676–1680 (2023). https://doi.org/10.1007/s11182-023-02817-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11182-023-02817-3