The possibility of measuring the concentration of alkane molecules – methane, ethane, propane, butane, pentane, and hexane – at the maximum permissible concentration (MPC) and higher (with concentrations in the range from 4∙1014 to 1017 cm−3) by a Raman lidar with optimal parameters in the synchronous photon counting mode in the atmospheric boundary layer at altitudes up to 1.5 km is estimated. It has been shown that with the Raman lidar operating at a wavelength of 532 nm, the concentrations of all examined molecules in the atmosphere can be detected on the MPC level: methane can be detected in the entire sensing range up to 1500 m, ethane up to 767 m, propane up to 941 m, butane up to 707 m, pentane up to 518 m, and hexane up to 185 m for a measurement time of 10 s.
Similar content being viewed by others
References
V. Е. Privalov, A. E. Fotiadi, and V. G. Shemanin, Lasers and Ecological Monitoring of the Atmosphere [in Russian], Lan Publishing House, Saint Patersburg (2013).
Hygienic Standards GN 2.1.6.3492-17 (with changes accepted on May 31, 2018) “Maximum permissible concentrations (MPC) of polluting substances in atmospheric air of urban and rural settlements,” Moscow (2017).
E. I. Voronina, V. E. Privalov, and V. G. Shemanin, Opt. Mem. Neural Netw. (Inf. Opt.), 19, No. 1, 69−76 (2010).
V. E. Privalov and V. G. Shemanin, Meas. Tech., 9, 933–938 (2016).
S. M. Bobrovnikov, G. G. Matvienko, O. A. Romanovskii, et al. Lidar Spectroscopic Gas Analysis of the Atmosphere [in Russian], Publishing House of the Institute of Atmospheric Optics SB RAS, Tomsk (2014).
V. E. Zuev and V. V. Zuev, Remote Optical Sensing of the Atmosphere [in Russian], Gidrometeoizdat, Saint Petersburg (1992).
V. P. Yushkov, Opt. Atm. Okeana, 30, No. 04, 315–328 (2017); DOI: 10.15372/AOO20170409.
Yu. S. Balin, G. P. Kokhanenko, M. G. Klemasheva, et al., Opt. Atmos. Okeana, 30, No. 12, 1065−1068 (2017); DOI: 10.15372/AOO20171210.
A. P. Chaikovsky, Ya. O. Grudo, Ya. A. Karol, et al., J. Appl. Spectrosc., 82, No. 5, 779–787 (2015).
V. E. Privalov and V. G. Shemanin, Bull. Russ. Acad. Sci.: Phys., 79, No. 2, 149–159 (2015).
G. N. Glazov, Statistical Problems of Laser Sensing of the Atmosphere [in Russian], Nauka, Novosibirsk (1987).
R. Mezheris, Laser Remote Sensing [Russian translation], Mir, Moscow (1987).
V. E. Privalov and V. G. Shemanin, Parameters of Lidars for Remote Sensing of Gas Molecules and Aerosol in the Atmosphare, Publishing House of Baltic State Technical Univessity, Saint Petersburg (2001).
V. A. Donchenko, M. V. Kabanov, B. V. Kaul, and I. V. Samokhvalov, Atmospheric Electrooptics [in Russian], Publishing House of Scientific-Technology Literature, Tomsk (2010).
E. D. Hinkley, ed., Laser Monitoring of the Atmosphere [Russian translation], Mir, Moscow (1979).
L. M. Sverdlov, M. A. Kovner, and E. P. Krainov, Vibrational Spectra of Polyatomic Molecules [in Russian], Nauka, Moscow (1970).
A. M. Prokhorov, ed., Handbook of Lasers, Vol. 1 [in Russian], Sovetskoe Radio, Moscow (1978).
V. E. Privalov and V. G. Shemanin, Meas. Tech., 57, No 12, 1356–1360 (2015).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 157–164, February, 2022.
Rights and permissions
Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Privalov, V.E., Shemanin, V.G. Raman Lidar Sensing of Saturated Hydrocarbon Molecules in the Atmospheric Boundary Layer. Numerical Modeling. Russ Phys J 65, 365–374 (2022). https://doi.org/10.1007/s11182-022-02644-y
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11182-022-02644-y