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Induced Absorption Spectra of a Crystal Violet Dye

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Russian Physics Journal Aims and scope

Using the pump-probe method, the short-lived induced and long-lived absorption capacity of a crystal violet (CV) dye is studied in various solvents. The solvents selected for this study are water, dimethyl sufoxide (DMSO), and isopropyl and ethyl alcohols. The formation of triplet-triplet states of CV is observed in these solvents under excitation by the 4-th harmonic nanosecond radiation of a Nd:YAG-laser (wavelength 266 nm, average power 25.5 mW, pulse repetition frequency 3 Hz, pulse duration 10 ns, and peak power 10−12 MW/cm2). It is shown that the nonstationary spectra of induced absorption of CV in ethanol contain two bands at 400 and 485 nm. In isopropyl alcohol, both singlet-singlet and long-lived triplet-triplet absorption of CV > 17.2 ns is recorded at room temperature in the region of 400–500 nm.

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Authors and Affiliations

  1. National Research Tomsk State University, Tomsk, Russia

    N. G. Dmitrieva, E. N. Bocharnikova & D. M Ezhov

  2. Siberian State Medical University, Tomsk, Russia

    N. G. Dmitrieva

Authors
  1. N. G. Dmitrieva
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  2. E. N. Bocharnikova
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  3. D. M Ezhov
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Correspondence to N. G. Dmitrieva.

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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 96–101, November, 2021.

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Dmitrieva, N.G., Bocharnikova, E.N. & Ezhov, D.M. Induced Absorption Spectra of a Crystal Violet Dye. Russ Phys J 64, 2089–2095 (2022). https://doi.org/10.1007/s11182-022-02560-1

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