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On the Influence of Transitions Between Distinct Adsorption States on the Desorption Kinetics of Molecules

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Russian Physics Journal Aims and scope

A model is proposed for desorption of molecules via a precursor state in the presence of two distinct chemisorption states on the surface. Analytical expressions describing the temporal evolution of the concentration of molecules in chemisorbed states are obtained. It is shown that redistribution of molecules between the chemisorbed states can lead to a non-monotonic time dependence of the concentration of molecules in one of the states in the early stages of desorption, as well as to a significant change in the spectra of temperature programmed desorption.

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References

  1. J. E. Lennard-Jones, Trans. Faraday Soc., 28, 333–359 (1932).

    Article  Google Scholar 

  2. W. Liu, S. N. Filimonov, J. Carrasco, and A. Tkatchenko, Nat. Commun., 4, 2569 (2013).

    ADS  Google Scholar 

  3. R. Peköz, K. Johnston, and D. Donadio, J. Phys. Chem. C, 118, 6235–6241 (2014).

    Google Scholar 

  4. P. S. Weiss and D. M. Eigler, Phys. Rev. Lett., 71, 3139–3142 (1993).

    Article  ADS  Google Scholar 

  5. B. Borovsky, M. Krueger, and E. Ganz. Phys. Rev. B, 57, R4269 (1998)

    Article  ADS  Google Scholar 

  6. G. P. Lopinski, D. J. Moffatt, and R. A. Wolkow, Chem. Phys. Lett., 282, 305–312 (1998).

    Article  ADS  Google Scholar 

  7. R. A. Wolkow and D. J. Moffatt, J. Chem. Phys., 103, 10698 (1995).

    Article  Google Scholar 

  8. D. Lock, S. Sakulsermsuk, R. E. Palmer, and P. A. Sloan, J. Phys. Cond. Mater., 27, 054003 (2015).

    Article  ADS  Google Scholar 

  9. D. E. Brown, D. J. Moffatt, and R. A. Wolkow, Science, 279, 542–544 (1998).

    Article  ADS  Google Scholar 

  10. P. Kisliuk, J. Phys. Chem. Solids, 3, 95–101 (1957).

    Article  ADS  Google Scholar 

  11. D. A. King, Surf. Sci., 64, 43–51 (1977).

    Article  ADS  Google Scholar 

  12. R. Gorte and L. D. Schidmt, Surf. Sci., 76, 559–573 (1978).

    Article  ADS  Google Scholar 

  13. C. D. MacPherson, D. Q. Hu, and K. T. Leung, Solid State Commun., 80, 217–220 (1991).

    Article  ADS  Google Scholar 

  14. S. Gokhale, P. Trischberger, D. Menzel, et al., J. Chem. Phys., 108, 5554–5564 (1998).

    Article  ADS  Google Scholar 

Download references

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Authors and Affiliations

  1. National Research Tomsk State University, Tomsk, Russia

    S. N. Filimonov & Yu. Yu. Hervieu

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  1. S. N. Filimonov
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  2. Yu. Yu. Hervieu
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Correspondence to S. N. Filimonov.

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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 7–12, June, 2016.

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Filimonov, S.N., Hervieu, Y.Y. On the Influence of Transitions Between Distinct Adsorption States on the Desorption Kinetics of Molecules. Russ Phys J 59, 762–767 (2016). https://doi.org/10.1007/s11182-016-0834-4

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  • DOI: https://doi.org/10.1007/s11182-016-0834-4

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