Spectral, luminescent, and lasing characteristics of chromene dyes and their julolidine analogs emitting in the red spectral range are investigated experimentally and theoretically. It is shown that the cause for a low lasing efficiency of oxochromene compared with iminochromene is a high intersystem crossing to the T 1 state and the presence of the induced T 1→T n absorption in the region of the luminescence band.
Similar content being viewed by others
References
O. García, R. Sastre, I. Garcìa-Moreno, et al., J. Phys. Chem., C112, No. 38, 14710–14713 (2008).
O. García, R. Sastre, D. del Agua, et al., J. Phys. Chem., C111, 1508–1516 (2007).
A. Costela, L. Cerdán, and I. García-Moreno, Prog. Quantum Electron., 37, 348–382 (2013).
H. Jelinkova, ed., Lasers for Medical Applications. Diagnostics, Therapy and Surgery, Woodhead Publishing (2013).
D. Schneider, T. Rabe, T. Riedl, et al., Adv. Mater., 17, No. 1, 31–34 (2005).
D. Amarasinghe, A. Ruseckas, A. E. Vasdekis, et al., Appl. Phys. Lett., 91, 011105 (2007).
T. Woggon, S. Klinkhammer, and U. Lemmer, Appl. Phys., B99, No. 1, 47–51 (2010).
M. Punke, T. Woggon, M. Stroisch, et al., Proc. SPIE, 6659-8 (2007).
J. W. Nibler, J. R. Mcdonald, and A. B. Harvey, Opt. Commun., 18, No. 3, 371–373 (1976).
I. M. Pritula, O. N. Bezrovnaya, V. M. Puzikov, et al., Funct. Mater., 19, No. 3, 378–383 (2012).
A. K. Aimukhanov, N. Kh. Ibraev, E. V. Seliverstova, et al., Opt. Atm. Okeana, 26, No. 10, 871–876 (2013).
V. I. Alekseeva, O. L. Kaliya, E. A. Luk’yanets, et al., Method of synthesis of 3-(benzazolyl)-substituted-7-diethylaminocoumarins, RF Patent No. 93035094/04 (November 10, 1997).
J. R. Lakowicz, Principles of Fluorescence Spectroscopy, Springer Science & Business Media (2010).
O. S. Wolfbeis, ed., Springer Series on Fluorescence. Methods and Applications, Springer Verlag, Heidelberg; Berlin (2008).
B. F. Minaev, R. R. Valiev, E. N. Nikonova, et al., J. Phys. Chem., A119, No. 10, 1948–1956 (2015).
A. D. Becke, J. Chem. Phys., 98, 5648 (1993).
A. A. Granovsky, J. Chem. Phys., 134, 214113 (2011).
A. A. Granovsky, Firefly version 8, http://classic.chem.msu.su/gran/firefly/index.html.
G. V. Mayer, V. Ya. Artyukhov, O. K. Bazyl′, et al., Electronically Excited States and Photochemistry of Organic Compounds [in Russian], Nauka, Novosibirsk (1997).
R. R. Valiev, A. N. Sinelnikov, Y. V. Aksenova, et al., Spectrochimica Acta, A117, 323–329 (2014).
R. R. Valiev, E. N. Telminov, T. A. Solodova, et al., Spectrochimica Acta, 128, 137–140 (2014).
R. R. Valiev, V. N. Cherepanov, V. Ya. Artyukhov, et al., Phys. Chem. Chem. Phys., 14, 11508–11517 (2012).
S. Yu. Nikonov, V. Ya. Artyukhov, and T. N. Kopylova, Russ. Phys. J., 52, No. 3, 275–285 (2009).
T. N. Kopylova, V. Ya. Artyukhov, S. Yu. Nikonov, et al., Russ. Phys. J., 56, No. 4, 389–397 (2013).
S. Yu. Nikonov, T. N. Kopylova, and R. M. Gadirov, Certificate of State Registration of Computer Program No. 2012616456 (Priority Date: May 17, 2012).
V. I. Zemskii, Yu. L. Kolesnikov, and I. K. Meshkovskii, Physics and Technology of Pulsed Dye Lasers [in Russian], Publishing House of University of Information Technologies, Mechanics, and Optics, St. Petersburg (2005).
V. V. Maslov, M. I. Dzyubenko, S. N. Kovalenko, et al., Sov. J. Quantum Electron., 17, No. 8, 998–1002 (1987).
V. G. Plotnikov, Russ. Chem. Rev., 49, No. 2, 172–189 (1980).
T. N. Kopylova, F. G. Samsonova, R. M. Gadirov, et al., Opt. Spectrosc., 100, No. 1, 34–40 (2006).
R. R. Valiev, E. N. Tel’minov, T. A. Solodova, Chem. Phys. Let, 588, 184–187 (2013).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 3–8, January, 2016.
Rights and permissions
About this article
Cite this article
Kopylova, T.N., Gadirov, R.M., Nikonov, S.Y. et al. Stimulated Emission of Active Media in the Red Spectral Range. Russ Phys J 59, 1–7 (2016). https://doi.org/10.1007/s11182-016-0731-x
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11182-016-0731-x