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Poly[4-(1′-pyrenyl)styrene]: synthesis, photophysical properties, and practical application as a sensor for nitroaromatic explosives

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Abstract

Poly[4-(1′-pyrenyl)styrene was synthesized for the first time, its photophysical properties were explored, and among them, the fluorescence with a high absolute quantum yield was discovered. Data acquired using the fluorescent titration revealed the opportunity to detect model nitroaromatic explosives at detection limits varying in the range from 10−6 to 10−7 mol L−1. The results reported herein for the homopolymer were compared with the corresponding data for poly[styrene-co-4-(1′-pyrenyl)styrene] copolymer synthesized previously.

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Funding

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (Project No. AAAA-A19-119011790132-7) and carried out using the equipment of the Center for Collective Use «Spectroscopy and Analysis of Organic Compounds» at the Postovsky Institute of Organic Synthesis of the Russian Academy of Sciences (Ural Branch).

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Authors and Affiliations

  1. I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22/20 ul. S. Kovalevskoy, 620137, Ekaterinburg, Russian Federation

    M. Zen Eddin, E. F. Zhilina, A. I. Dubovik, M. I. Kodess, M. A. Ezhikova, G. L. Rusinov, E. V. Verbitskiy & V. N. Charushin

  2. Ural Federal University named after the First President of Russia B. N. Yeltsin, 19 ul. Mira, 620002, Ekaterinburg, Russian Federation

    M. Zen Eddin, A. I. Dubovik, G. L. Rusinov, E. V. Verbitskiy & V. N. Charushin

  3. University of Aleppo, Mouhafaza str., Aleppo, Syria

    M. Zen Eddin

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  1. M. Zen Eddin
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  2. E. F. Zhilina
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  3. A. I. Dubovik
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  4. M. I. Kodess
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  5. M. A. Ezhikova
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  6. G. L. Rusinov
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  7. E. V. Verbitskiy
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  8. V. N. Charushin
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Corresponding author

Correspondence to M. Zen Eddin.

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No human or animal subjects were used in this research.

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The authors declare no competing interests.

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Dedicated to Academician of the Russian Academy of Sciences M. P. Egorov on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 11, pp. 2717–2725, November, 2023.

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Zen Eddin, M., Zhilina, E.F., Dubovik, A.I. et al. Poly[4-(1′-pyrenyl)styrene]: synthesis, photophysical properties, and practical application as a sensor for nitroaromatic explosives. Russ Chem Bull 72, 2717–2725 (2023). https://doi.org/10.1007/s11172-023-4077-6

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  • DOI: https://doi.org/10.1007/s11172-023-4077-6

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