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Nitration of N-(fluorodinitroethyl)pyrazoles

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Abstract

Conditions for the introduction of the nitro group at the position 4 of N-(fluorodinitroethyl)pyrazoles bearing an electron-withdrawing substituent at the position 3 were found. The structures of the products were established by multinuclear NMR spectroscopy and X-ray crystallographic analysis.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    A. G. Gladyshkin, I. L. Dalinger & A. B. Sheremetev

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. A. Anisimov & I. V. Ananyev

  3. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    I. V. Ananyev

  4. N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation

    A. N. Pivkina

Authors
  1. A. G. Gladyshkin
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  2. A. A. Anisimov
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  3. I. V. Ananyev
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  4. A. N. Pivkina
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  5. I. L. Dalinger
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  6. A. B. Sheremetev
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Corresponding author

Correspondence to A. B. Sheremetev.

Additional information

Dedicated to Academician of the Russian Academy of Sciences V. A. Tartakovsky on the occasion of his 90th birthday.

The study was financially supported by the Russian Science Foundation (the synthesis and characterization of compounds performed by I. L. Dalinger and A. B. Sheremetev were supported by Project No. 20-13-00289; the crystal packing analysis carried out by A. A. Anisimov and I. V. Ananyev was supported by Project No. 22-13-00238). The X-ray diffraction data were obtained using the equipment of the Center for Molecular Structure Studies of the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences with the financial support from the Ministry of Science and Higher Education of the Russian Federation.

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izyestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1701–1709, August, 2022.

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Gladyshkin, A.G., Anisimov, A.A., Ananyev, I.V. et al. Nitration of N-(fluorodinitroethyl)pyrazoles. Russ Chem Bull 71, 1701–1709 (2022). https://doi.org/10.1007/s11172-022-3580-5

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