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Interaction of l-valinates of biogenic metals with 2-hydroxyethylamines

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Abstract

The interaction of copper(ii), zinc(ii), nickel(ii), and cobalt(ii) l-valinates with 2-hydroxyethylamines, viz., triethanolamine, diethanolamine, and tris(hydroxymethyl)aminomethane, was studied for the first time. Formation of new coordination compounds was confirmed using IR and electronic spectroscopies, mass spectrometry, and elemental analysis. The crystal structure of copper(ii) l-valinate was determined. The thermal stability and antimicrobial activity data for some prepared complexes of l-valine are also presented.

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology, 26 Moscowsky prosp., 190013, St. Petersburg, Russian Federation

    N. S. Kiprova

  2. I. V. Grebenshchikov Institute of Silicate Chemistry of Russian Academy of Sciences, 2 Makarova nab., 199034, St. Petersburg, Russian Federation

    Yu. A. Kondratenko, V. L. Ugolkov & T. A. Kochina

  3. Institute of Earth Sciences, St. Petersburg State University, 7-9 Universitetskaya nab., 199034, St. Petersburg, Russian Federation

    V. V. Gurzhiy

Authors
  1. N. S. Kiprova
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  2. Yu. A. Kondratenko
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  3. V. L. Ugolkov
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  4. V. V. Gurzhiy
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  5. T. A. Kochina
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Corresponding author

Correspondence to Yu. A. Kondratenko.

Additional information

Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1789–1798, September, 2020.

The study was carried out with the use of equipment of Resource Centers of Saint Petersburg State University, viz., of the Centre for Optical and Laser Materials Research, the Centre for X-ray Diff raction Studies, the Chemical Analysis and Materials Research Centre, and the Magnetic Resonance Research Centre.

This work was performed under financial support of the Russian Foundation for Basic Research (Project No. 18-33-00216-mol-a).

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Kiprova, N.S., Kondratenko, Y.A., Ugolkov, V.L. et al. Interaction of l-valinates of biogenic metals with 2-hydroxyethylamines. Russ Chem Bull 69, 1789–1798 (2020). https://doi.org/10.1007/s11172-020-2963-8

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  • DOI: https://doi.org/10.1007/s11172-020-2963-8

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