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Effect of fluorine doping on the ionic (O2−, H+) conductivity of oxygen-deficient complex oxides

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Abstract

The effect of fluorine doping on the transport properties (oxygen-ion and proton conductivity) of perovskite-related complex oxides Ba2In2O5, Ba4In2Zr2O11, and Ba4Ca2Nb2O11 with various concentrations and degrees of disordering of oxygen vacancies was analyzed. Regardless of the doping mechanism and concentrations and degrees of disordering of oxygen vacancies, the introduction of low concentrations of fluoride ions increases the ionic component of the conductivity due to the appearance of effects of electrostatic repulsion of ions of various nature in the anionic sublattice.

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References

  1. H. Iwahara, Y. Asakura, K. Katahira, M. Tanaka, Solid State Ionics, 2004, 168, 299.

    CAS  Google Scholar 

  2. S. Tao, J. T. S. Irvine, Adv. Mater., 2006, 18, 1581.

    CAS  Google Scholar 

  3. E. Fabbri, L. Bi, D. Pergolesi, E. Traversa, Adv. Mater., 2012, 24, 195.

    CAS  PubMed  Google Scholar 

  4. Ph. Colomban, O. Zaafrani, A. Slodczyk, Membranes, 2012, 2, 493.

    CAS  PubMed  PubMed Central  Google Scholar 

  5. M. Marrony, J. Dailly, ECS Trans., 2017, 78, 3349.

    CAS  Google Scholar 

  6. A. Dubois, S. Ricote, R. J. Braun, ECS Trans., 2017, 78, 1963.

    CAS  Google Scholar 

  7. E. Shin, M. Shin, H. Lee, J.-S. Park, Ceram. Int., 2018, 44, 8423.

    CAS  Google Scholar 

  8. F. Kröger, H. Vink, Solid State Phys., 1956, 3, 307.

    Google Scholar 

  9. J. Wendel, M. Lerch, W. Laqua, J. Solid State Chem., 1999, 142, 163.

    CAS  Google Scholar 

  10. J. S. Lee, J. Fleig, J. Maier, D. Y. Kim, T. J. Chung, J. Am. Ceram. Soc., 2005, 88, 3067.

    CAS  Google Scholar 

  11. J. M. Polfus, T. S. Bjørheim, T. Norby, R. Haugsrud, Phys. Chem. Chem. Phys., 2012, 14, 11808.

    CAS  PubMed  Google Scholar 

  12. J. M. Polfus, T. Norby, R. Haugsrud, Dalton Trans., 2011, 40, 132.

    CAS  PubMed  Google Scholar 

  13. J. M. Polfus, T. Norby, R. Haugsrud, J. Solid State Chem., 2013, 198, 65.

    CAS  Google Scholar 

  14. K. D. Kreuer, Annu. Rev. Mater. Res., 2003, 33, 333.

    CAS  Google Scholar 

  15. D. Medvedev, A. Murashkina, E. Pikalova, A. Podias, A. Demin, P. Tsiakaras, Prog. Mater. Sci., 2014, 60, 72.

    CAS  Google Scholar 

  16. E. C. Camilo de Souza, R. Muccillo, Mater. Res., 2010, 13, 385.

    CAS  Google Scholar 

  17. E. Fabbri, D. Pergolesi, E. Traversa, Chem. Soc. Rev., 2010, 39, 4355.

    CAS  PubMed  Google Scholar 

  18. E. Fabbri, D. Pergolesi, E. Traversa, Sci. Technol. Adv., Mater., 2010, 11, 044301.

    Google Scholar 

  19. L. Malavasi, C. A. J. Fisher, M. S. Islam, Chem. Soc. Rev., 2010, 39, 4370.

    CAS  PubMed  Google Scholar 

  20. S. Tao, J. T. S. Irvine, J. Solid State Chem., 2007, 180, 3493.

    CAS  Google Scholar 

  21. V. P. Gorelov, V. B. Balakireva, Russ. J. Electrochem., 2009, 45, 476.

    CAS  Google Scholar 

  22. E. Fabbri, A. D’Epifanio, E. Di Bartolomeo, S. Licoccia, E. Traversa, Solid State Ionics, 2008, 179, 558.

    CAS  Google Scholar 

  23. P. Sawant, S. Varma, B. N. Wani, S. R. Bharadwaj, Int. J. Hydrogen Energy, 2012, 37 3848.

    CAS  Google Scholar 

  24. G. B. Zhang, D. M. Smyth, Solid State Ionics, 1995, 82, 153.

    CAS  Google Scholar 

  25. I. E. Animitsa, E. N. Dogodaeva, S. S. Nokhrin, O. A. Kosareva, A. Ya. Neiman, Russ. J. Electrochem., 2010, 46, 734.

    CAS  Google Scholar 

  26. I. Animitsa, A. Neiman, N. Kochetova, B. Melekh, A. Sharafutdinov, Solid State Ionics, 2003, 162–163, 63.

    Google Scholar 

  27. I. Animitsa, N. Tarasova, Ya. Filinkova, Solid State Ionics, 2012, 207, 29.

    CAS  Google Scholar 

  28. N. A. Tarasova, Ya. V. Filinkova, I. E. Animitsa, Russ. J. Electrochem., 2013, 49, 45.

    CAS  Google Scholar 

  29. N. Tarasova, I. Animitsa, Solid State Ionics, 2014, 264, 69.

    CAS  Google Scholar 

  30. N. A. Tarasova, I. E. Animitsa, K. G. Belova, Russ. J. Electrochem., 2017, 53, 813.

    CAS  Google Scholar 

  31. N. Tarasova, I. Animitsa, A. Galisheva, 3D Research, 2017, 8, 27.

    Google Scholar 

  32. I. E. Animitsa, N. A. Tarasova, T. A. Denisova, Ya. V. Baklanova, Russ. J. Struct. Chem., 2016, 57, 910.

    CAS  Google Scholar 

  33. N. A. Tarasova, I. E. Animitsa, K. G. Belova, Bull. Russ. Acad. Sci., Physics, 2017, 81, 632.

    CAS  Google Scholar 

  34. N. Tarasova, Ph. Colomban, I. Animitsa, J. Phys. Chem. Solids, 2018, 118, 32.

    CAS  Google Scholar 

  35. N. Tarasova, I. Animitsa, Solid State Sci., 2019, 87, 87.

    CAS  Google Scholar 

  36. A. Rolle, S. Daviero-Minaud, P. Roussel, A. Rubbens, R. N. Vannier, Solid State Ionics, 2018, 179, 771.

    Google Scholar 

  37. J. Bielecki, S. F. Parker, D. Ekanayake, S. M. H. Rahman, L. Borjesson, M. Karlsson, J. Mater. Chem., 2014, A2, 16915.

    Google Scholar 

  38. M.-J. Xu, Yi. Ni, Z.-Q. Li, S.-L. Wang, X.-H. Liu, X.-M. Dou, Chin. Phys. B, 2011, 20, 063101.

    Google Scholar 

  39. R. D. Shannon, Acta Crystallogr., 1976, A32, 751.

    CAS  Google Scholar 

  40. J. Liu, E. P. Kharitonova, C.-G. Duan, W.-N. Mei, R. W. Smith, J. R. Hardy, Chem. Faculty Public., 2004, Paper 7.

  41. M. Nazarov, Moldav. J. Phys. Sci., 2010, 9, 5.

    Google Scholar 

  42. G. B. Zhang, D. M. Smyth, Solid State Ionics, 1995, 82, 161.

    CAS  Google Scholar 

  43. I. Animitsa, Russ. J. Electrochem., 2009, 45, 668.

    CAS  Google Scholar 

  44. A. E. Ushakov, O. V. Merkulov, A. A. Markov, M. V. Patrakeev, I. A. Leonidov, Ceram. Int., 2018, 44, 11301.

    CAS  Google Scholar 

  45. J. Liu, Z. Jin, L. Miao, J. Ding, H. Tang, Z. Gong, R. Peng, W. Liu, Int. J. Hydrogen Energy, 2019, 44, 11079.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Ural Federal University, Institute of Natural Sciences and Mathematics, 19 ul. Mira, 620002, Ekaterinburg, Russian Federation

    N. A. Tarasova

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  1. N. A. Tarasova
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Correspondence to N. A. Tarasova.

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Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).

Published in Russian in Izyestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1253–1263, July, 2020.

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Tarasova, N.A. Effect of fluorine doping on the ionic (O2−, H+) conductivity of oxygen-deficient complex oxides. Russ Chem Bull 69, 1253–1263 (2020). https://doi.org/10.1007/s11172-020-2895-3

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  • DOI: https://doi.org/10.1007/s11172-020-2895-3

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