Abstract
Composite materials (CMs) were synthesized on the basis of nanoporous silicate glasses (PGs) with small additives of P2O5 and fluoride ions doped by silver bromide in the presence or in the absence of cerium or erbium. The obtained CMs were characterized by a complex of methods (X-ray powder diffraction (XRD) technique, energy-dispersive X-ray spectroscopy, and UV-Vis-NIR spectroscopy). According to the XRD data, the CMs contain the cubic phases of AgBr (No. 01-071-3754) and KBr (No. 01-089-3620). It was foundby energy-dispersive X-ray spectroscopy that the concentrations of oxygen, silicon, potassium, and silver are uniformly distributed over the whole thickness of the samples. The optical properties of the CMs depending on their composition and heat treatment temperature (in the range from 120 to 870 °C) were compared. The absorption bands characteristic of molecular clusters and nanoparticles of silver, as well as cerium and erbium ions were revealed.
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The authors are grateful to A. V. Antonov (A. P. Karpinsky Russian Geological Research Institute, St. Petersburg) for studies of the composite materials by energydispersive X-ray spectroscopy.
This work was carried out in terms of the state assignment of the I. V. Grebenshchikov Institute of Silicate Chemistry (Russian Academy of Sciences) in the framework of the Program of Basic Research of State Academies of Sciences for 2013-2020 (Theme No. AAAA-A19-119022290087-1).
Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9—13, 2019, St. Petersburg, Russia).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 0920–0925, May, 2020.
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Girsova, M.A., Kurilenko, L.N., Anfimova, I.N. et al. Phase composition and optical properties of composite materials doped by silver bromide and Ce3+ or Er3+ ions. Russ Chem Bull 69, 920–925 (2020). https://doi.org/10.1007/s11172-020-2849-9
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DOI: https://doi.org/10.1007/s11172-020-2849-9