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Organic conductor θ-(BEDT-TTF)Cd1.38I3 with layered perovskite-like structure

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Abstract

The organic conductor θ-(BEDT-TTF)Cd1.38I3 (1) (BEDT-TTF is bis(ethylenedithio)- tetrathiafulvalene) with layered perovskite-like structure was synthesized. In the crystal structure of 1, θ-type organic conducting layers, which are built up from BEDT-TTF stacks, alternate with inorganic insulating layers. The latter are composed of CdI6 octahedra and CdI4 tetrahedra linked together to form a two-dimensional anionic network. Measurements of the temperature dependence of the electrical resistance demonstrated that compound 1 is a semiconductor.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    E. I. Zhilyaeva, G. V. Shilov, A. M. Flakina & R. N. Lyubovskaya

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  1. E. I. Zhilyaeva
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  2. G. V. Shilov
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  3. A. M. Flakina
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  4. R. N. Lyubovskaya
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Correspondence to E. I. Zhilyaeva.

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Zhilyaeva, E.I., Shilov, G.V., Flakina, A.M. et al. Organic conductor θ-(BEDT-TTF)Cd1.38I3 with layered perovskite-like structure. Russ Chem Bull 67, 252–254 (2018). https://doi.org/10.1007/s11172-018-2066-y

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  • DOI: https://doi.org/10.1007/s11172-018-2066-y

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