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Alkylation of 1-alkoxy-3-methyl-1-triazene 2-oxide sodium salts

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Abstract

1-Alkoxy-3-methyl-1-triazene 2-oxide sodium salts react with chloromethyl methyl sulfide to give a mixture of 1-alkoxy-3-methyl-3-(methylthiomethyl)-1-triazene 2-oxides and 3-alkoxy-1-methyl-3-(methylthiomethyl)-1-triazene 2-oxides. The reaction of these triazene oxide sodium salts with 3,3-dialkyl-1-chloromethoxy-1-triazene 2-oxides produces a complex mixture of product bearing the oxytriazene moieties of the starting alkoxy-1-triazene 2-oxides bonded with the methylene group as a key structural fragment.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    G. A. Smirnov, P. B. Gordeev, S. V. Nikitin, G. V. Pokhvisneva, Yu. A. Strelenko, T. V. Ternikova & O. A. Luk´yanov

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  1. G. A. Smirnov
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  2. P. B. Gordeev
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  3. S. V. Nikitin
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  4. G. V. Pokhvisneva
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  5. Yu. A. Strelenko
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  6. T. V. Ternikova
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  7. O. A. Luk´yanov
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Corresponding author

Correspondence to G. A. Smirnov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2851—2856, December, 2015.

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Smirnov, G.A., Gordeev, P.B., Nikitin, S.V. et al. Alkylation of 1-alkoxy-3-methyl-1-triazene 2-oxide sodium salts. Russ Chem Bull 64, 2851–2856 (2015). https://doi.org/10.1007/s11172-015-1237-3

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  • DOI: https://doi.org/10.1007/s11172-015-1237-3

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