Skip to main content
SpringerLink
Log in

The relationship between self-organization, physicochemical properties, and biological activity of low-concentration solutions of p-aminobenzoic acid

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The self-organization and the physicochemical properties of aqueous solutions (1•10–11—1•10–2 mol L–1) of p-aminobenzoic acid (PABA) kept both under ambient conditions and in the absence of external physical fields were studied by dynamic light scattering and conductometry. It was shown that in aqueous solutions of PABA in the 1•10–10—1•10–3 mol L–1 concentration range, nanosized molecular assemblies (supramolecular domains and nanoassociates) of 100—300 nm size, stable in the temperature range of 25—40 °C, are formed. In the low-concentration range, PABA concentrations in aqueous solutions of 10–10—10–9 mol L–1 and 10–5—10–4 mol L–1 are optimal for waste water treatment.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. M. Bremener, Vitaminy i ikh klinicheskoe primenenie [Vitamins and Their Clinical Applications], Meditsina, Moscow, 1966, 417 pp. (in Russian).

    Google Scholar 

  2. M. D. Mashkovskii, Lekarstvennye Sredstva [Pharmaceutical Products], Meditsina, Moscow, 1998, 1424 pp. (in Russian).

    Google Scholar 

  3. Yu. D. Beletskii, Para-aminobenzoinaya kislota — novoe biologicheski aktivnoe soedinenie [para-Aminobenzoic Acid as a New Biologically Active Compound], Izd. Rostov. Univ., Rostov-on-Don, 1993, 59 pp. (in Russian).

    Google Scholar 

  4. N. S. Silant´eva, in Khimicheskii mutagenez v sozdanii sortov s novymi svoistvami [Chemical Mutagenesis in the Creation of Varieties with New Properties], Nauka, Moscow, 1986, p. 262 (in Russian).

    Google Scholar 

  5. S. V. Vasil´eva, G. P. Zhizhina, I. A. Rapoport, Dokl. Phys. Chem. (Engl. Transl.), 1980, 252, 755 [Dokl. Akad. Nauk, 1980, 252, 755].

    Google Scholar 

  6. G. N. Shangin-Berezovskii, S. A. Moloskin, O. S. Rykhletskaya, Khimicheskii mutagenez v sozdanii sortov s novymi svoistvami [Chemical Mutagenesis in the Creation of Varieties with New Properties], Nauka, Moscow, 1986, p. 243 (in Russian).

    Google Scholar 

  7. M. Jager, W. Groenink, R. B. Guivernau, E. Andersson, N. Angelova, M. Ponec, J. Bouwstra, Pharmac. Res., 2006, 23, 951.

    Article  CAS  Google Scholar 

  8. Yu. Zhang, J. Wang, M. Xu, Colloids and Surfaces B: Biointerfaces, 2010, 75, 179.

    Article  CAS  Google Scholar 

  9. S. Gracin, M. Uusi-Penttila, E. C. Rasmuson, Cryst. Growth Design, 2005, 5, 1787.

    Article  CAS  Google Scholar 

  10. E. B. Burlakova, Zh. Vsesoyuz. khim. o-va im. D. I. Mendeleeva, 1999, 43, No. 5, 3 [Mendeleev Chem. J. (Engl. Transl.), 1999, 43, No. 5].

  11. Hormesis: a Revolution in Biology, Toxicology and Medicine, Springer, New York, 2009.

  12. I. S. Ryzhkina, L. I. Murtazina, Yu. V. Kiseleva, A. I. Konovalov, Dokl. Phys. Chem. (Engl. Transl.), 2009, 428, 196 [Dokl. Akad. Nauk, 2009, 428, 487].

    Article  CAS  Google Scholar 

  13. A. I. Konovalov, I. S. Ryzhkina, L. I. Murtazina, Byull. izobret., Poleznye modeli [Invent. Bull. Useful Models], 2010, 24 (in Russian).

    Google Scholar 

  14. A. I. Konovalov, I. S. Ryzhkina, Russ. Chem. Bull. (Int. Ed.), 2011, 60, 1 [Izv. Akad. Nauk, Ser. Khim., 2014, 1].

    Article  CAS  Google Scholar 

  15. I. S. Ryzhkina, L. I. Murtazina, A. I. Konovalov, Dokl. Phys. Chem. (Engl. Transl.), 2011, 440, 201 [Dokl. Akad. Nauk, 2011, 440, 778].

    Article  CAS  Google Scholar 

  16. I. S. Ryzhkina, Yu. V. Kiseleva, L. I. Murtazina, N. P. Pal´mina, V. V. Belov, E. L. Mal´tseva, E. D. Sherman, A. P. Timosheva, A. I. Konovalov, Dokl. Phys. Chem. (Engl. Transl.), 2011, 438, 109 [Dokl. Akad. Nauk, 2011, 438, 635].

    Article  CAS  Google Scholar 

  17. I. S. Ryzhkina, Yu. V. Kiseleva, L. I. Murtazina, O. A. Mishina, E. D. Sherman, A. I. Konovalov, Dokl. Phys. Chem. (Engl. Transl.), 2012, 447, 203 [Dokl. Akad. Nauk, 2012, 447, 179].

    Article  CAS  Google Scholar 

  18. I. S. Ryzhkina, L. I. Murtazina, E. D. Sherman, Yu. N. Valitova, E. A. Kataev, A. I. Konovalov, Dokl. Phys. Chem. (Engl. Transl.), 2010, 433, 142 [Dokl. Akad. Nauk, 2010, 433, 647].

    Article  CAS  Google Scholar 

  19. I. S. Ryzhkina, L. I. Murtazina, E. D. Sherman, M. E. Pantyukova, E. M. Masagutova, T. P. Pavlova, S. V. Fridland, A. I. Konovalov, Dokl. Phys. Chem. (Engl. Transl.), 2011, 438, 98 [Dokl. Akad. Nauk, 2011, 438, 207].

    Article  CAS  Google Scholar 

  20. L. I. Murtazina, I. S. Ryzhkina, O. A. Mishina, Yu. V. Kiseleva, T. P. Pavlova, S. V. Fridland, Vestn. Kazan. Tekhnol. Un-ta [Bull. Kazan. Technol. Univ.], 2013, 16, No. 1, 175 (in Russian).

  21. Yu. Yu. Lur´e, Analiticheskaya khimiya promyshlennykh stochnykh vod [Analytical Chemistry of Indistrial Waste Water], Khimiya, Moscow, 1984, 448 pp. (in Russian).

    Google Scholar 

  22. A. I. Konovalov, I. S. Ryzhkina, L. I. Murtazina, A. P. Timosheva, R. R. Shagidullin, A. V. Chernova, L. V. Avvakumova, S. G. Fattakhov, Russ. Chem. Bull. (Int. Ed.), 2008, 57, 1231 [Izv. Akad. Nauk, Ser. Khim., 2008, 1207].

    Article  CAS  Google Scholar 

  23. A. I. Konovalov, I. S. Ryzhkina, Melafen: mekhanizm deistviya i oblasti primeneniya [Melaphene: Mechanism of Action and Applications], Eds S. G. Fattakhov, V. V. Kuznetsov, N. V. Zagoskina, Pechat´—Serviz XXI vek, Kazan´, 2014, 408 pp. (in Russian).

  24. M. Sedlak, D. Rak, J. Phys. Chem. B, 2013, 117, 2495.

    Article  CAS  Google Scholar 

  25. N. Marchettini, E. Del Giudice, V. Voeikov, E. Tiezzi, J. Theoret. Biol., 2010, 265, 511.

    Article  CAS  Google Scholar 

  26. T. Yinnon, C. Yinnon, Modern Phys. Lett. B, 2012, 26, 1150006.

    Article  Google Scholar 

  27. T. Yinnon, V. Elia, Int. J. Modern Phys. B, 2013, 27, 1350005.

    Article  Google Scholar 

  28. P. Bharmoria, H. Gupta, V. P. Mohandas, P. K. Ghosh, A. Kumar, J. Phys. Chem. B, 2012, 116, 11712.

    Article  CAS  Google Scholar 

  29. V. Bardik, V. Gotsulskii, E. Pavlov, N. Malomuzh, D. Nerukh, I. Yanchuk, S. Lavoryk, J. Mol. Liq., 2012, 176, 60.

    Article  CAS  Google Scholar 

  30. D. Hagmeyer, J. Ruesing, T. Fenske, H.-W. Klein, C. Schmuck, W. Schrader, M. E. M. da Piedade, M. Epple, RSC Adv., 2012, 2, 4690.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan´ Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan´, Russian Federation

    O. A. Mishina, L. I. Murtazina, I. S. Ryzhkina & A. I. Konovalov

Authors
  1. O. A. Mishina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. I. Murtazina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. S. Ryzhkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. I. Konovalov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. I. Murtazina.

Additional information

Dedicated to Academician of the Russian Academy of Sciences V. I. Minkin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0590—0596, March, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mishina, O.A., Murtazina, L.I., Ryzhkina, I.S. et al. The relationship between self-organization, physicochemical properties, and biological activity of low-concentration solutions of p-aminobenzoic acid. Russ Chem Bull 64, 590–596 (2015). https://doi.org/10.1007/s11172-015-0904-8

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-015-0904-8

Key words

Search

Navigation