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Synthesis and properties of N-ferrocenylalkylated pyrroles

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Abstract

A series of N-ferrocenylalkyl pyrroles were synthesized by intermolecular redox amination of ferrocenyl ketones and formylferrocene with pyrroline. The racemic mixtures were separated into enantiomers using high performance liquid chromatography. The structure of N-ferrocenylmethylpyrrole was determined by X-ray diffraction.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    K. Ya. Zherebker, A. N. Rodionov, M. M. Il’in, A. A. Korlyukov, D. E. Arkhipov, Yu. A. Belousov & A. A. Simenel

  2. N. I. Pirogov Russian National Research Medical University, 1 ul. Ostrovityanova, 117997, Moscow, Russian Federation

    A. A. Korlyukov & D. E. Arkhipov

  3. Moscow State Mining University, 6 Leninsky prosp., 119991, Moscow, Russian Federation

    A. A. Simenel

Authors
  1. K. Ya. Zherebker
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  2. A. N. Rodionov
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  3. M. M. Il’in
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  4. A. A. Korlyukov
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  5. D. E. Arkhipov
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  6. Yu. A. Belousov
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  7. A. A. Simenel
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Correspondence to A. A. Simenel.

Additional information

Dedicated to Academician of the Russian Academy of Sciences Yu. N. Bubnov on the occasion of his 80th birthday and to the 60th anniversary of the foundation of A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2281–2284, October, 2014.

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Zherebker, K.Y., Rodionov, A.N., Il’in, M.M. et al. Synthesis and properties of N-ferrocenylalkylated pyrroles. Russ Chem Bull 63, 2281–2284 (2014). https://doi.org/10.1007/s11172-014-0735-z

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  • DOI: https://doi.org/10.1007/s11172-014-0735-z

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