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Evaluation of the scaling parameters of lignin macromolecules

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Abstract

The results of a study of the topological structure of lignin from Betula pendula birch twigs are presented. The molecular properties of dilute solutions of lignin in DMF were investigated by the sedimentation velocity and translational diffusion methods, and by viscosimetry. The molecular weights of fractions, the conformational parameters, and the Tsvetkov-Klenin hydrodynamic invariant were determined. Correlations between the hydrodynamic, conformational, and fractal parameters of lignin were studied. Lignin from birch twigs was found to be a randomly branched polymer.

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Authors and Affiliations

  1. Institute of Biology, Komi Scientific Center, Ural Branch of the Russian Academy of Sciences, 28 ul. Kommunisticheskaya, 167982, Syktyvkar, Russian Federation

    L. S. Kocheva

  2. Syktyvkar State University, 55 Oktyabrskiy prosp., 167001, Syktyvkar, Russian Federation

    L. S. Kocheva, A. P. Karmanov & Yu. A. Karmanova

  3. Institute of Geology, Komi Scientific Center, Ural Branch of the Russian Academy of Sciences, 54 ul. Pervomajskaya, 167982, Syktyvkar, Russian Federation

    A. P. Karmanov

Authors
  1. L. S. Kocheva
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  2. A. P. Karmanov
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  3. Yu. A. Karmanova
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Correspondence to L. S. Kocheva.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2036–2039, September, 2014.

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Kocheva, L.S., Karmanov, A.P. & Karmanova, Y.A. Evaluation of the scaling parameters of lignin macromolecules. Russ Chem Bull 63, 2036–2039 (2014). https://doi.org/10.1007/s11172-014-0696-2

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  • DOI: https://doi.org/10.1007/s11172-014-0696-2

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