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Radical polymerization of methyl methacrylate in the presense of bis[4,6-di-tert-butyl-N-(2,6-dimethylphenyl)-o-iminobenzosemiquinono]cobalt(II)

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Abstract

Radical polymerization of methyl methacrylate was studied in the presence of initiating systems based on bis[4,6-di-tert-butyl-N-(2,6-dimethylphenyl)-o-iminobenzosemiquinono]-cobalt(II) and hydrocarbon halo derivatives of different structure. The introduction of amines in the polymerizing system was found to lead to a significant increase in the polymerization rate. The polymerization proceeds via the atom transfer mechanism, which was confirmed by detection of ω-terminal chlorine atoms in the macromolecules by NMR, the linear dependence of the polymer molecular weight on conversion of monomer, and the synthesis of block-copolymers.

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Authors and Affiliations

  1. N. I. Lobachevsky State University of Nizhny Novgorod, 5 korp., 23 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    E. V. Kolyakina & D. F. Grishin

  2. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    A. I. Poddel’skii

Authors
  1. E. V. Kolyakina
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  2. A. I. Poddel’skii
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  3. D. F. Grishin
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Correspondence to D. F. Grishin.

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According to the materials of International Conference “Organometallic and Coordination Chemistry: Fundamental and Applied Aspects” (September 1–7, 2013, Nizhny Novgorod).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0987–0996, April, 2014.

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Kolyakina, E.V., Poddel’skii, A.I. & Grishin, D.F. Radical polymerization of methyl methacrylate in the presense of bis[4,6-di-tert-butyl-N-(2,6-dimethylphenyl)-o-iminobenzosemiquinono]cobalt(II). Russ Chem Bull 63, 987–996 (2014). https://doi.org/10.1007/s11172-014-0538-2

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  • DOI: https://doi.org/10.1007/s11172-014-0538-2

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