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Nano-[Cu-4C3NSP](Cl)2 as a new catalyst for the preparation of pyrimido[4,5-b]quinoline derivatives

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Abstract

Nano-Cu-(4-chloro-3-nitrophenyl-salicylaldimine-pyranopyrimidine dione)(Cl)2 {nano-[Cu-4C3NSP](Cl)2} as a new Schiff base complex and catalyst was designed and successfully tested as a catalyst on the reaction of 7-amino-5-(4-chloro-3-nitrophenyl)-2,4-dioxo-2,3,4,5-tetrahydro-1H-pyrano[2,3-d]pyrimidine-6-carbonitrile with salicylaldehyde and Cu(Cl)2·2H2O. Nano-[Cu-4C3NSP](Cl)2 was fully characterized using Fourier transform infrared spectroscopy, energy-dispersive X-ray spectroscopy, thermal gravimetric analysis, mass spectroscopy, field emission scanning electron microscopy, SEM–EDS elemental mapping and transmission electron microscopy. {Nano-[Cu-4C3NSP](Cl)2} was successfully used as an efficient catalyst for the preparation of pyrimido[4,5-b]quinoline derivatives in high yields (73–95%).

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Funding

Funding was provided by Sayyed Jamaleddin Asadabadi University.

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Authors and Affiliations

  1. Department of Chemical Engineering, Hamedan University of Technology, Hamedan, 65155, Iran

    Ahmad Reza Moosavi-Zare & Hamid Goudarziafshar

  2. Department of Chemistry, Sayyed Jamaleddin Asadabadi University, Asadabad, 6541861841, Iran

    Zahra Bahrami

Authors
  1. Ahmad Reza Moosavi-Zare
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  2. Hamid Goudarziafshar
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  3. Zahra Bahrami
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Correspondence to Ahmad Reza Moosavi-Zare or Hamid Goudarziafshar.

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Moosavi-Zare, A.R., Goudarziafshar, H. & Bahrami, Z. Nano-[Cu-4C3NSP](Cl)2 as a new catalyst for the preparation of pyrimido[4,5-b]quinoline derivatives. Res Chem Intermed 49, 507–523 (2023). https://doi.org/10.1007/s11164-022-04901-8

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