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Effect of reducing gas on the hydrogen production by thermo-oxidation of water over 1%Rh/Ce0.6Zr0.4O2

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Abstract

We have studied the effect of the reducing gas (H2, CO and CH4) on the hydrogen production by thermo-oxidation of water over the 1%Rh/Ce0.6Zr0.4O2 catalyst prepared by impregnation. The catalyst is characterized by hydrogen chemisorption (Hc), before and after catalytic decomposition of water, temperature-programmed desorption, temperature-programmed reduction, X-ray diffraction and scanning electron microscopy. The catalyst is reduced in situ at 500 °C (4 h) under H2, CO or CH4 flows and flushed with Ar gas. Then, pulses of water (1 μL/pulse) are injected at 500 °C under Ar flow (30 mL/min). The results show clearly that the reducing gas has a strong effect on the H2 production which follows the order: H2 > CH4 > > CO. H2 chemisorption measurements at room temperature highlight a strong metal–support interaction over fresh reduced catalysts which decreases after water decomposition (reduced centers + H2O → oxidized centers + H2).

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Acknowledgements

The authors thank Dr. O. Mahraoua for his technical assistance.

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Authors and Affiliations

  1. Laboratory of Materials and Application to the Environment, Faculty of Chemistry, USTHB, BP 32, 16111, Algiers, Algeria

    B. Benaziza & A. Benamar

  2. Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry, USTHB, BP 32, 16111, Algiers, Algeria

    N. Helaili & M. Trari

  3. Université François-Rabelais de Tours, GREMAN UMR 7347 CNRS, IUT de Blois 15 rue de la chocolaterie CS 2903, 41029, Blois Cedex, France

    M. Zaghrioui & M. Anouti

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  1. B. Benaziza
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  2. A. Benamar
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  3. N. Helaili
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  4. M. Zaghrioui
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  6. M. Trari
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Benaziza, B., Benamar, A., Helaili, N. et al. Effect of reducing gas on the hydrogen production by thermo-oxidation of water over 1%Rh/Ce0.6Zr0.4O2. Res Chem Intermed 47, 649–661 (2021). https://doi.org/10.1007/s11164-020-04291-9

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  • DOI: https://doi.org/10.1007/s11164-020-04291-9

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