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Electrochemical and nonelectrochemical analyses of cardo polyesters at the metal/0.5 M H2SO4 interface for corrosion protection

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Abstract

With the aim of decreasing the corrosion of metal specimens, two polyesters, namely 4-(1-(4-methoxyphenyl)cyclohexyl)phenyl 3-oxobutanoate (MPOB) and 4-(1-(4-methoxyphenyl)cyclohexyl)phenyl 10-oxoundecanoate (MPOU), were synthesized and utilized as corrosion inhibitors. The synthesized polyesters were characterized by Fourier-transform infrared (FT-IR) and nuclear magnetic resonance spectral analyses, followed by thermogravimetric and differential scanning calorimetry analyses. The protective effect of the polyesters on mild-steel specimens in 0.5 M H2SO4 medium was evaluated by nonelectrochemical and electrochemical methods. Gravimetric measurements revealed a decreased corrosion rate with increasing concentration of the inhibitors, reaching a maximum inhibition efficiency of 79.88% for MPOB and 92.98% for MPOU at 1000 ppm concentration at room temperature. The obtained experimental data were best fit by the Langmuir adsorption isotherm, suggesting monolayer adsorption. Thermodynamic parameters supported a physisorption mechanism. Electrochemical impedance spectroscopy showed increased charge-transfer resistance (Rct), in turn decreasing the double-layer capacitance and thereby favoring good inhibition of corrosion of mild steel. Mixed-type inhibition was revealed by potentiodynamic polarization analysis, suppressing anodic metal dissolution and cathodic hydrogen evolution. The mode of adsorption of the inhibitors on the mild-steel surface was additionally evaluated by morphological study using FT-IR and atomic force microscopy (AFM) analyses.

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Acknowledgements

This paper was supported by the KU Research Professor Program of Konkuk University.

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  1. Chan Basha Nusrath Unnisa and Ill-Min Chung contributed equally to this work.

Authors and Affiliations

  1. Department of Chemistry, PSGR Krishnammal College for Women, Coimbatore, India

    Chan Basha Nusrath Unnisa, Subramanian Chitra, Gowraraju Nirmala Devi, Ayyasamy Kiruthika & Venkatesan Hemapriya

  2. Department of Chemistry, VIT University, Vellore, India

    Selvaraj Mohana Roopan

  3. Department of Crop Science, College of Sanghur Life Science, Konkuk University, Seoul, 05029, South Korea

    Ill-Min Chung, Seung-Hyun Kim & Mayakrishnan Prabakaran

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  1. Chan Basha Nusrath Unnisa
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Unnisa, C.B.N., Chitra, S., Nirmala Devi, G. et al. Electrochemical and nonelectrochemical analyses of cardo polyesters at the metal/0.5 M H2SO4 interface for corrosion protection. Res Chem Intermed 45, 5425–5449 (2019). https://doi.org/10.1007/s11164-019-03910-4

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