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Fabrication of electrochemical nanosensor based on carbon paste electrode modified with graphene oxide nano-ribbons and 3-(4′-amino-3′-hydroxy-biphenyl-4-yl)-acrylic acid for simultaneous detection of carbidopa and droxidopa

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Abstract

Bulk modification of carbon paste electrode (CPE) with graphene oxide nanoribbon and 3-(4′-amino-3′-hydroxy-biphenyl-4-yl) -acrylic acid (3,4′-AA-GONR/CPE) was used to develop a new electro-chemical sensor for sensitive determination of droxidopa and carbidopa at physiological pH. Chronoamperometry, differential pulse voltammetry, and cyclic voltammetry were employed to evaluate electro-chemical responses of as-prepared modified electrodes. A linear dependence of oxidation peak current on the concentration of droxidopa within a range between 0.02 and 300.0 μM was also observed with determination limit of 10.0 nM (S/N = 3). Desirable reproducibility, stability, and selectivity were seen in as-prepared 3,4′-AA-GONR/CPE, implying hopeful uses for concurrent detection of droxidopa and carbidopa.

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Acknowledgements

The authors acknowledge the financial support provided for this project (No. 97000115) by the Bam University of Medical Sciences, Bam, Iran and Kerman University of Medical Sciences, Kerman, Iran.

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Authors and Affiliations

  1. School of Medicine, Bam University of Medical Sciences, Bam, Iran

    Peyman Mohammadzadeh Jahani

  2. Research Center for Tropical and Infectious Diseases, Kerman University of Medical Sciences, Kerman, Iran

    Somayeh Tajik & Mohammad Reza Aflatoonian

  3. Environment Department, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran

    Hadi Beitollahi & Somayeh Mohammadi

  4. Leishmaniasis Research Center, Kerman University of Medical Sciences, Kerman, Iran

    Mohammad Reza Aflatoonian

Authors
  1. Peyman Mohammadzadeh Jahani
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  2. Somayeh Tajik
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  3. Hadi Beitollahi
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  4. Somayeh Mohammadi
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  5. Mohammad Reza Aflatoonian
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Correspondence to Peyman Mohammadzadeh Jahani or Somayeh Tajik.

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Mohammadzadeh Jahani, P., Tajik, S., Beitollahi, H. et al. Fabrication of electrochemical nanosensor based on carbon paste electrode modified with graphene oxide nano-ribbons and 3-(4′-amino-3′-hydroxy-biphenyl-4-yl)-acrylic acid for simultaneous detection of carbidopa and droxidopa. Res Chem Intermed 45, 5143–5157 (2019). https://doi.org/10.1007/s11164-019-03908-y

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