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Synthesis of ZnO–SnO2 nanocomposites: impact of polyethylene glycol on morphological, luminescence and photocatalytic properties

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Abstract

Zinc oxide-doped tin dioxide (ZnO–SnO2) nanomaterials were prepared by a sol–gel method with and without different amounts (0.5, 1.0 and 2.0 g) of polyethylene glycol (PEG). The prepared nanocomposites were characterized for structural, surface and optical properties. The effect of a PEG on the prepared ZnO–SnO2 nanocomposites was investigated. The photocatalytic activities of the synthesized nanocomposites were evaluated by methylene blue dye degradation under UV illumination. The ZnO–SnO2 nanocomposites prepared with 2.0 g of PEG showed the highest degradation efficiency of 87.30%, suggesting that adding PEG enhances the photocatalytic performance of ZnO–SnO2 nanocomposites due to increased inhibition of e/h+ pair recombination and efficient generation of superoxide radical anions and hydroxyl radicals.

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References

  1. R. Javed, M. Ahmed, I. Haq, S. Nisa, M. Zia, Mater. Sci. Eng. C 79, 108 (2017)

    Article  CAS  Google Scholar 

  2. S. Kumar, R. Nigam, V. Kundu, N. Jaggi, J. Mater. Sci. Mater. Electron. 26, 3268 (2015)

    Article  CAS  Google Scholar 

  3. X. An, F. Teng, P. Zhang, C. Zhao, X. Pan, Z. Zhang, E. Xie, J. Alloys Compd. 614, 373 (2014)

    Article  CAS  Google Scholar 

  4. R.A. Zargar, M.A. Bhat, I.R. Parrey, M. Arora, J. Kumar, A.K. Hafiz, Optik 127, 6997 (2016)

    Article  CAS  Google Scholar 

  5. P.K. Baitha, J. Manam, J. Rare Earth 33, 805 (2015)

    Article  CAS  Google Scholar 

  6. J. Kong, Z. Rui, H. Ji, Y. Tong, Catal. Today 258, 75 (2015)

    Article  CAS  Google Scholar 

  7. T. Tharsika, A.S.M.A. Haseeb, M.F.M. Sabri, Thin Solid Films 558, 283 (2014)

    Article  CAS  Google Scholar 

  8. D.E. Tanasa, C.G. Piuleac, S. Curteanu, E. Popovici, J. Mater. Sci. 48, 8029 (2013)

    Article  CAS  Google Scholar 

  9. X.-J. Wen, C.-G. Niu, L. Zhang, D.-W. Huang, G.-M. Zeng, Ceram. Int. 43, 1922 (2017)

    Article  CAS  Google Scholar 

  10. H. Guo, C.-G. Niu, X.-J. Wen, L. Zhang, C. Liang, X.-G. Zhang, D.-L. Guan, N. Tang, G.-M. Zeng, J. Colloid Interface Sci. 513, 852 (2018)

    Article  CAS  PubMed  Google Scholar 

  11. H. Guo, C.-G. Niu, L. Zhang, X.-J. Wen, C. Liang, X.-G. Zhang, D.-L. Guan, N. Tang, G.-M. Zeng, ACS Sustain. Chem. Eng. 6, 8003 (2018)

    Article  CAS  Google Scholar 

  12. C. Liang, C.-G. Niu, L. Zhang, X.-J. Wen, S.-F. Yang, H. Guo, G.-M. Zeng, J. Hazard. Mater. 361, 245 (2019)

    Article  CAS  PubMed  Google Scholar 

  13. H. Guo, C.-G. Niu, D.-W. Huang, N. Tang, C. Liang, L. Zhang, X.-J. Wen, Y. Yang, W.-J. Wang, G.-M. Zeng, Chem. Eng. J. 360, 349 (2019)

    Article  CAS  Google Scholar 

  14. M. Zhang, G. Sheng, J. Fu, T. An, X. Wang, X. Hu, Mater. Lett. 59, 3641 (2005)

    Article  CAS  Google Scholar 

  15. S.-J. Lee, C.-S. Hwang, J.-E. Pi, M.-K. Ryu, H. Oh, S.H. Cho, J.-H. Yang, S.-H.K. Park, H.Y. Chu, Mater. Lett. 122, 94 (2014)

    Article  CAS  Google Scholar 

  16. M.M. Rashad, A.A. Ismail, I. Osama, I.A. Ibrahim, A.-H.T. Kandil, Arab. J. Chem. 7, 71 (2014)

    Article  CAS  Google Scholar 

  17. W. Li, S. Ma, Y. Li, G. Yang, Y. Mao, J. Luo, D. Gengzang, X. Xu, S. Yan, Sens. Actuators B 211, 392 (2015)

    Article  CAS  Google Scholar 

  18. A.D. Bhagwat, S.S. Sawant, B.G. Ankamwar, C.M. Mahajan, J. Nano-Electron. Phys. 7, 37 (2015)

    Google Scholar 

  19. Y. Liu, M. Liu, Adv. Eng. Mater. 8, 89 (2006)

    Article  CAS  Google Scholar 

  20. E.H. Jo, H. Chang, S.K. Kim, K.M. Roh, J. Kim, H.D. Jang, Mater. Lett. 131, 244 (2014)

    Article  CAS  Google Scholar 

  21. M. Faisal, A.A. Ibrahim, F.A. Harraz, H. Bouzid, M.S. Al-Assiri, A.A. Ismail, J. Mol. Catal. A Chem. 397, 19 (2015)

    Article  CAS  Google Scholar 

  22. V.V. Namboodiri, R.S. Varma, Green Chem. 3, 146 (2001)

    Article  CAS  Google Scholar 

  23. Z. Li, Y. Xiong, Y. Xie, Inorg. Chem. 42, 8105 (2003)

    Article  CAS  PubMed  Google Scholar 

  24. E. Shen, C. Wang, E. Wang, Z. Kang, L. Gao, C. Hu, L. Xu, Mater. Lett. 58, 3761 (2004)

    Article  CAS  Google Scholar 

  25. V. Rajendran, K. Anandan, Mater. Sci. Semicond. Proce. 15, 393 (2012)

    Article  CAS  Google Scholar 

  26. K. Subramanyam, N. Sreelekha, G. Murali, D.A. Reddy, R.P. Vijayalakshmi, Phys. B 454, 86 (2014)

    Article  CAS  Google Scholar 

  27. Q.P. Wang, D.H. Zhang, Z.Y. Xue, X.T. Hao, Appl. Surf. Sci. 201, 123 (2002)

    Article  CAS  Google Scholar 

  28. X.M. Fan, J.S. Lian, L. Zhao, Y.H. Liu, Appl. Surf. Sci. 252, 420 (2005)

    Article  CAS  Google Scholar 

  29. R. Lamba, A. Umar, S.K. Mehta, S.K. Kansal, Talanta 131, 490 (2015)

    Article  CAS  PubMed  Google Scholar 

  30. M. Jung, S. Kim, S. Ju, Opt. Mater. 33, 280 (2011)

    Article  CAS  Google Scholar 

  31. M. Aziz, S.S. Abbas, W.R.W. Baharom, Mater. Lett. 91, 31 (2013)

    Article  CAS  Google Scholar 

  32. E.H. Jo, H. Chang, S.K. Kim, K.M. Roh, J. Kim, H.D. Jang, Mater. Lett. 131, 244 (2014)

    Article  CAS  Google Scholar 

  33. C.-H. Zhou, X.-Z. Zhao, B.-C. Yang, D. Zhang, Z.-Y. Li, K.-C. Zhou, J. Colloid Interface Sci. 374, 9 (2012)

    Article  CAS  PubMed  Google Scholar 

  34. Z. Khodami, A. Nezamzadeh-Ejhieh, J. Mol. Catal. A Chem. 409, 59 (2015)

    Article  CAS  Google Scholar 

  35. F. Gao, Y. Li, Y. Zhao, W. Wan, G. Du, X. Ren, H. Zhao, J. Alloys Compd. 703, 354 (2017)

    Article  CAS  Google Scholar 

  36. V. Rajendran, K. Anandan, Mater. Sci. Semicond. Process. 15, 393 (2012)

    Article  CAS  Google Scholar 

  37. V. Agrahari, M.C. Mathpal, S. Kumar, M. Kumar, A. Agarwal, J. Mater. Sci. Mater. Electron. 27, 6020 (2016)

    Article  CAS  Google Scholar 

  38. P. Sangeetha, V. Sasirekha, V. Ramakrishnan, J. Raman Spectrosc. 42, 1634 (2011)

    Article  CAS  Google Scholar 

  39. N. Bhardwaj, A. Pandey, D.K. Avasthi, S. Mohapatra, J. Alloys Compd. 680, 155 (2016)

    Article  CAS  Google Scholar 

  40. W. Chen, D. Ghosh, S. Chen, J. Mater. Sci. 43, 5291 (2008)

    Article  CAS  Google Scholar 

  41. M. Ali, F.B. Bouaifel, B. Sieber, H. Elhouichet, A. Addad, L. Boussekey, M. Ferid, R. Boukherrou, Superlattices Microstruct. 91, 225 (2016)

    Article  CAS  Google Scholar 

  42. J. Wang, Z. Chen, Y. Liu, C.-H. Shek, C.M.L. Wu, J.K.L. Lai, Sol. Energy Mater. Sol. Cells 128, 254 (2014)

    Article  CAS  Google Scholar 

  43. V.K. Tomer, S. Duhan, Sens. Actuators B 223, 750 (2016)

    Article  CAS  Google Scholar 

  44. P.V. Reddy, S.V. Reddy, B.S. Reddy, Mater. Today Proc. 3, 1752 (2016)

    Article  Google Scholar 

  45. W. Tian, T. Zhai, C. Zhang, S.-L. Li, X. Wang, F. Liu, D. Liu, X. Cai, K. Tsukagoshi, D. Golberg, Y. Bando, Adv. Mater. 25, 4625 (2013)

    Article  CAS  PubMed  Google Scholar 

  46. A. Hamrouni, N. Moussa, F. Parrino, A.D. Paola, A. Houas, L. Palmisano, J. Mol. Catal. A Chem. 390, 133 (2014)

    Article  CAS  Google Scholar 

  47. J. Ge, X. Wang, C. Li, S. Wang, L. Wang, R. Qu, Z. Wang, Chem. Eng. J. 359, 1056 (2019)

    Article  CAS  Google Scholar 

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Acknowledgements

The authors extend their appreciation to King Abdul-Aziz City for Sciences and Technology (KACST), Kingdom of Saudi Arabia for funding this work under Grant No. 1-17-01-010-0023.

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Correspondence to Atif Mossad Ali or Adel A. Ismail.

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Ali, A.M., Ghazwani, N.A., Algarni, H. et al. Synthesis of ZnO–SnO2 nanocomposites: impact of polyethylene glycol on morphological, luminescence and photocatalytic properties. Res Chem Intermed 45, 3089–3106 (2019). https://doi.org/10.1007/s11164-019-03780-w

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