Abstract
Novel tri-amine functionalized graphene oxide (TGO) material was synthesized using organo silane {3-[2-(2-amino ethyl amino) ethyl amino] propyl trimethoxy silane, AEPTMS}. The solid catalyst was completely characterized by varied characterization techniques, such as X-ray diffraction, FTIR, Raman, TEM and SEM. The tri-amine group grafting over the graphene oxide surface was established by FT-IR study. The TGO catalyst exhibited remarkable activity for the Henry reaction, producing p-hydroxynitrostyrene, with conversion (93%) and excellent selectivity (100%). The conversion efficiency of the catalyst material sustained for three cycles.
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The authors acknowledge the support received from the School of Chemistry and Physics and College of Agriculture, Engineering and Science, University of KwaZulu-Natal, Durban, South Africa in the form of research facilities and financial support.
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Funding was provided by National Research Foundation, South Africa.
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Rana, S., Bhaskaruni, S.V.H.S. & Jonnalagadda, S.B. Tri-amine functionalized graphene oxide for co-operative catalyst in the Henry reaction. Res Chem Intermed 44, 2157–2167 (2018). https://doi.org/10.1007/s11164-017-3220-0
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DOI: https://doi.org/10.1007/s11164-017-3220-0