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Triton X-100 stabilized Pd nanoparticles and their catalytic application in one-pot sequential Heck and Hiyama coupling in water

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Abstract

In situ-generated palladium nanoparticles (Pd NPs) using Triton X-100 non-ionic surfactant-catalyzed one-pot sequential Hiyama and Heck coupling reactions in water under aerobic conditions has been demonstrated. The reaction was highly efficient for the synthesis of symmetrical stillbenes utilizing arenediazonium salts and vinyl triethoxy silane. The in situ-generated Pd NPs were characterized by transmission electron microscopy analysis and had a size below 20 nm. The aqueous system containing the surfactant along with the Pd NPs was recycled five times, without significant loss of catalytic activity.

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Acknowledgements

One of authors DSG gratefully acknowledges Department of Science and Technology, New Delhi, India, for financial assistance under Start-up research Grant (No. SB/FT/CS-145/2014).

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Authors and Affiliations

  1. Department of Chemistry, Vivekanand College, Kolhapur, Maharashtra, 416003, India

    D. S. Gaikwad, K. A. Undale & D. B. Patil

  2. Department of Chemistry, Shivaji University, Kolhapur, Maharashtra, 416 004, India

    D. M. Pore

  3. Department of Chemistry, Bharatratna Indira Gandhi College of Engineering, Kegaon, Solapur, Maharashtra, 413 255, India

    A. A. Kamble

Authors
  1. D. S. Gaikwad
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  2. K. A. Undale
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  3. D. B. Patil
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  4. D. M. Pore
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  5. A. A. Kamble
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Correspondence to D. S. Gaikwad.

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Gaikwad, D.S., Undale, K.A., Patil, D.B. et al. Triton X-100 stabilized Pd nanoparticles and their catalytic application in one-pot sequential Heck and Hiyama coupling in water. Res Chem Intermed 44, 265–275 (2018). https://doi.org/10.1007/s11164-017-3102-5

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