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Effect of calcination temperature on desulfurization performance over Mn x O y supported on MCM-41 at low temperatures

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Abstract

Adsorbents consisting of Mn x O y supported on MCM-41 have been prepared at different calcination temperatures by the ultrasonic assisted impregnation method. The physical properties of these adsorbents have been characterized by thermogravimetric and differential thermal gravimetry, X-ray diffraction, Fourier-transform infrared spectroscopy, temperature-programmed reduction, and nitrogen sorption analysis. The results showed that the adsorbent calcined at 550 °C exhibited the best desulfurization performance. The saturated H2S capacity reached 28.65 mg/g at an adsorption temperature of 25 °C. The saturated H2S capacities of the different adsorbents decreased in the order of their calcination temperatures as follows: 550 > 450 > 350 > 650 °C.

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References

  1. N. Sadegh, E.H. Stenby, K. Thomsen, Fluid Phase Equilib. 392, 24 (2015)

    Article  CAS  Google Scholar 

  2. C. Fauteux-Lefebvre, N. Abatzoglou, N. Braidy et al., Ind. Eng. Chem. Res. 54, 9230 (2015)

    Article  CAS  Google Scholar 

  3. M.P. Chenar, H. Savoji, M. Soltanieh et al., Korean J. Chem. Eng. 28, 902 (2011)

    Article  CAS  Google Scholar 

  4. H.K. Namgung, H.Y. Ahn, J.H. Song, Energy Procedia 14, 1143 (2012)

    Article  CAS  Google Scholar 

  5. W. Xie, L. Chang, D. Wang et al., Fuel 89, 868 (2010)

    Article  CAS  Google Scholar 

  6. A. Samokhvalov, B.J. Tatarchuk, Phys. Chem. Chem. Phys. 13, 3197 (2011)

    Article  CAS  Google Scholar 

  7. S. Yasyerli, Chem. Eng. Process. 47, 577 (2008)

    Article  CAS  Google Scholar 

  8. D. Karayilan, T. Dogu, S. Yasyerli et al., Ind. Eng. Chem. Res. 44, 5221 (2005)

    Article  CAS  Google Scholar 

  9. J. Mi, J. Ren, Y. Zhang, Environ. Eng. Sci. 29, 1026 (2012)

    Article  CAS  Google Scholar 

  10. S. Bennici, A. Gervasini, V. Ragaini, Ultrason. Sonochem. 10, 61 (2003)

    Article  CAS  Google Scholar 

  11. K. Polychronopoulou, J.L.G. Fierro, Appl. Catal. B 57, 125 (2005)

    Article  CAS  Google Scholar 

  12. J.J. Zhang, L. Wang, H. Song et al., Res. Chem. Intermed. 41, 6087 (2015)

    Article  CAS  Google Scholar 

  13. H. Song, J. Gong, H.L. Song et al., Appl. Catal. A 505, 267 (2015)

    Article  CAS  Google Scholar 

  14. H. Gao, F. Xiao, C.B. Ching et al., ACS Appl. Mater. Interfaces 4, 2801 (2012)

    Article  CAS  Google Scholar 

  15. Y.X. Liu, H.X. Dai, J.G. Deng et al., Inorg. Chem. 52, 8665 (2013)

    Article  CAS  Google Scholar 

  16. J. Xu, Y.Q. Deng, Y. Luo et al., J. Catal. 300, 225 (2013)

    Article  CAS  Google Scholar 

  17. Z.F. Zhang, B.S. Liu, F. Wang et al., Appl. Surf. Sci. 313, 961 (2014)

    Article  CAS  Google Scholar 

  18. X. Wang, Q. Kang, D. Li, Appl. Catal. B 86, 166 (2009)

    Article  CAS  Google Scholar 

  19. M. Jin, J.W. Kim, M.K. Ji et al., Powder Technol. 214, 458 (2011)

    Article  CAS  Google Scholar 

  20. Z. Liu, Y. Teng, K. Zhang et al., J Energy Chem. 24, 322 (2015)

    Article  Google Scholar 

  21. B. Pejova, A. Isahi, M. Najdoski, I. Grozdanov, Mater. Res. Bull. 36, 161 (2001)

    Article  CAS  Google Scholar 

  22. E. Laperdrix, G. Costentin, O. Saur et al., J. Catal. 189, 63 (2000)

    Article  CAS  Google Scholar 

  23. H.B. Fang, J.T. Zhao, Y.T. Fang et al., Fuel 108, 143 (2013)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing, 163318, China

    Jiaojing Zhang, Guojian Wang, Wenyi Wang & Hua Song

  2. Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing, 163318, Heilongjiang, China

    Jiaojing Zhang & Hua Song

  3. Institute of Petroleum Economics and Management, Northeast Petroleum University, Daqing, 163318, Heilongjiang, China

    Fengsheng Li

Authors
  1. Jiaojing Zhang
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  2. Guojian Wang
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  3. Wenyi Wang
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  4. Hua Song
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  5. Fengsheng Li
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Correspondence to Hua Song.

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Zhang, J., Wang, G., Wang, W. et al. Effect of calcination temperature on desulfurization performance over Mn x O y supported on MCM-41 at low temperatures. Res Chem Intermed 42, 6003–6012 (2016). https://doi.org/10.1007/s11164-016-2421-2

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  • DOI: https://doi.org/10.1007/s11164-016-2421-2

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