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Application of Fe3O4@SiO2@sulfamic acid magnetic nanoparticles as recyclable heterogeneous catalyst for the synthesis of imine and pyrazole derivatives in aqueous medium

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Abstract

Sulfamic acid supported on Fe3O4@SiO2 superpara magnetic nanoparticles was successfully applied as a recyclable solid acid catalyst with a large density of sulfamic acid groups for the synthesis of pyrazole derivatives, an important class of potentially bioactive compounds. The products are obtained in high yield from the one-pot reaction procedure involving dicarbonyl compounds and hydrazines/hydrazides. This new method totally avoids the use of toxic or expensive solvents and organic acids in this reaction.

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Acknowledgment

We gratefully acknowledge the support of this work by the Birjand University Research Council.

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Authors and Affiliations

  1. Department of Chemistry, College of Sciences, University of Birjand, Birjand, 97175-615, Iran

    B. Zakerinasab, M. A. Nasseri & M. M. Samieadel

  2. Department of Chemistry, Payam Noor University, Birjand, Iran

    H. Hassani

Authors
  1. B. Zakerinasab
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  2. M. A. Nasseri
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  3. H. Hassani
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  4. M. M. Samieadel
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Correspondence to B. Zakerinasab.

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Zakerinasab, B., Nasseri, M.A., Hassani, H. et al. Application of Fe3O4@SiO2@sulfamic acid magnetic nanoparticles as recyclable heterogeneous catalyst for the synthesis of imine and pyrazole derivatives in aqueous medium. Res Chem Intermed 42, 3169–3181 (2016). https://doi.org/10.1007/s11164-015-2204-1

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