Physicomechanical properties and structure of mullite-corundum unmolded refractories are investigated and tests of a pilot batch of refractory products for various purposes are conducted. The effect of the adding nanosize SiO2 (1 wt.%) on strength, structural (density, porosity) and operational properties of unmolded refractories is studied. Results show that this additive contributes to formation of a structure with high apparent density and compressive strength (2.93 and 2.98 g/cm3, 87.3 and 162.1 MPa, respectively for two types of refractories), reduces open porosity from 20 to 14%, and also increases the life of refractory products (according to operating duration) by 25 – 35% compared with basic refractory life. The use of SiO2 nanoparticle additives reduces refractory product and raw material consumption for their manufacture, and also increases production profitability.
Similar content being viewed by others
References
F. Tomšů and S. Palčo, “Refractory monolithics versus shaped refractory products,” Interceram., 66(1), 20 – 23 (2017).
E. Ouedraogo, M. Roosefid, and N. Prompt, “Refractory concretes uniaxial compression behavior under high temperature testing conditions,” J. Eur. Ceram. Soc., 31(15), 2763 – 2774 (2011).
R. Sarkar, “Binders for refractory castables: an overview,” Int. Ceram. Rev., 69(4), 44 – 53 (2020).
I. D. Kashcheev, K. K. Strelov, and P. S. Mamykin, Refractory Chemical Technology [in Russian], Intermet Inzhiniring, Moscow (2007).
I. D. Kashcheev, and K. K. Strelov, Properties and Application of Refractories: Ref. Ed. [in Russian], Teplotekhnik, Moscow (2004).
L. Xu, Y. Liu, and M. Chen, “An accurate correlation between high temperature performance and cement content of the high-alumina refractory castables,” Ceram. Int., 48(15), 22601 – 22607 (2022).
N. Zhou, “New castables and their role in advancements in monolithic refractories,” Interceram., 55(1), 24 – 26 (2006).
S. Hossain and P. Roy, “Development of waste derived nanolakargiite bonded high alumina refractory castable for high temperature applications,” Ceram. Int., 45(13), 16202 – 16213 (2019).
W. Lee, W. Vieira, and S. Zhang, “Castable refractory concretes,” Int. Mater. Rev., 46(3), 145 – 167 (2001).
D. Suvorov, B. Khaydarov, and D. Lysov, “Nanomodification of refractories with finely-dispersed additives with the use of a vortex electromagnetic homogenizer,” IOP Conference Series: Mater. Sci. Eng., 718 (2020).
D. Suvorov, A. Yudin, B. Khaydarov, et al., “Synthesis and research of aluminum oxide additives for refractory composite materials, Refract. Ind. Ceram., 62(5), 535 – 540 (2022).
H. Son, S. Park, and J. Jang, “Effect of nano-silica on hydration and conversion of calcium aluminate cement,” Construction and Building Materials, 169, 819 – 825 (2018.)
J. Roy, S. Chandra, and S. Maitra, “Nanotechnology in castable refractory,” Ceram. Int., 45 (2019).
S. Otroj, A. Sagaeian, and A. Daghighi, “The effect of nano-size additives on the electrical conductivity of matrix suspension and properties of self-flowing low-cement high alumina refractory castables,” Ceram. Int., 36, 1411 – 1416 (2010).
J. Chen, C. Liang, B. Li, and E. Wang, “The effect of nano-γ-Al2O3 additive on early hydration of calcium aluminate cement,” Construction and Building Materials, 158, 755 – 760 (2018).
H. Mohammadi, M. Nilforoushan, and M. Tayebi, “Effect of nanosilica addition on bioactivity and in vivo properties of calcium aluminate cement,” Ceram. Int., 46(4), 4335 – 4343 (2020).
C. Guo, E. Wang, X. Hou, et al., “Characterization and mechanism of early hydration of calcium aluminate cement with anatase-TiO2 nanospheres additive,” Construction and Building Materials, 261, Article No. 119922 (2020).
V. Pinto, A. Luz, and O. Borges, “ Binder effect on ZnAl2O4-containing high alumina refractory castables,” Ceram. Int., 48(8), 11401 – 11409 (2022).
J. Quanlia, Z. Jub, and Z. Ying, “Effect of microsilica addition on the properties of colloidal silica bonded bauxite-andalusite based castables,” Ceram. Int., 44(3), 3064 – 3068 (2018).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Novye Ogneupory, No. 9, pp. 44 – 48, September, 2022.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Suvorov, D.S., Khaidarov, B.B., Lysov, D.V. et al. Effect of Adding Nanosize SiO2 on Physicomechanical Properties and Durability of a Refractory Component Industrial Batch. Refract Ind Ceram 63, 522–526 (2023). https://doi.org/10.1007/s11148-023-00760-x
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11148-023-00760-x