Results of studies of Al2O3 suspensions made with different CaO and SrO contents are presented. The pH level increased with an increase in the content of CaO and SrO in the Al2O3 suspensions. The dynamic viscosity of the Al2O3 suspensions grew exponentially as the CaO content increased from 0.45 to 2.25 mol% and SrO, from 0.42 to 2.14 mol%. Reflections of CaAl12O19 and SrAl12O19 were observed in sintered materials of suspensions to which CaO and SrO, respectively, were introduced. These compounds had a lamellar structure.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11148-022-00727-4/MediaObjects/11148_2022_727_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11148-022-00727-4/MediaObjects/11148_2022_727_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11148-022-00727-4/MediaObjects/11148_2022_727_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11148-022-00727-4/MediaObjects/11148_2022_727_Fig4_HTML.png)
Similar content being viewed by others
References
W. H. Tuan, R. Z. Chen, T. C. Wang, et al., “Mechanical properties of Al2O3/ZrO2 composites,” J. Eur. Ceram. Soc., 22(16), 2827 – 2833 (2002).
W. Burger and H. G. Richter, “High strength and toughness alumina matrix composites by transformation toughening and ‘in situ’ platelet reinforcement (ZPTA) — The new generation of bioceramics,” Key Eng. Mater., 192 – 195, 545 – 548 (2000).
E. G. Zemtsova, A. V. Monin, V. M. Smirnov, et al., “Formation and mechanical properties of aluminum-oxide ceramics based on aluminum oxide micro- and nanoparticles,” Fiz. Mezomekh., 17(6), 53 – 58 (2014).
V. V. Myl’nikov, A. I. Pronin, and E. A. Chernyshev, “Research of ceramic materials’ influence on functionality of cutting instrument,” Tr. Nizhegorod. Gos. Tekh. Univ. (NGTU) im. R. E. Alekseeva, No. 1 (86), 227 (2011).
J. J. Kruzic, R. K. Nalla, J. H. Kinney, and R. O. Ritchie, “Crack blunting, crack bridging and resistance-curve fracture mechanics in dentin: Effect of hydration,” Biomaterials, 24(28), 5209 – 5221 (2003).
L. I. Podzorova, A. A. Il’icheva, O. I. Pen’kova, et al., “Al2O3-based ceramic composites with a high brittle fracture resistance,” Inorg. Mater., 55(6), 628 – 633 (2019).
L. I. Podzorova, A. A. Il’icheva, V. P. Sirotinkin, et al., “Ceramic composites of the zirconium dioxide and aluminum oxide system including strontium hexaaluminate,” Glass Ceram., 78(5), 231 – 236 (2021).
K. Cui, T. Fu, Y. Zhang, et al., “Microstructure and mechanical properties of CaAl12O19 reinforced Al2O3-Cr2O3 composites,” J. Eur. Ceram. Soc., 41(15), 7935 – 7945 (2021).
J. Li, E. A. Medina, J. K. Stalick, et al., “Structural studies of CaAl12O19, SrAl12O19, La2/3+δAl12–δO19, and CaAl10NiTiO19 with the hibonite structure; Indications of an unusual type of ferroelectricity,” Z. Naturforsch. B: J. Chem. Sci., 71(5), 475 – 484 (2016).
N. Yu. Cherkasova, A. A. Bataev, S. V. Veselov, et al., “Effect of percent content of SrAl12O19 on crack resistance of aluminum zirconium ceramic,” Ogneupory Tekh. Keram., No. 4/5, 18 – 23 (2019).
A. Tsetsekou, C. Agrafiotis, and A. Milias, ”Optimization of the rheological properties of alumina slurries for ceramic processing applications. Part I: Slip-casting,” J. Eur. Ceram. Soc., 21(3), 363 – 373 (2001).
R. I. Kuzmin, N. Y. Cherkasova, A. A. Bataev, et al., “Strontium hexaaluminate formation in alumina and alumina-zirconia matrixes,” Ceram. Int., 47(5), 6854 – 6859 (2021).
A. Altay and M. A. Gulgun, “Microstructural evolution of calcium-doped α-alumina,” J. Am. Ceram. Soc., 86(4), 623 – 629 (2003).
D. A. Rani, Y. Yoshizawa, K. Hirao, and Y. Yamauchi, “Effect of rare-earth dopants on mechanical properties of alumina,” J. Am. Ceram. Soc., 87(2), 289 – 292 (2004).
Z. D. I. Sktani, N. A. Rejab, A. F. Z. Rosli, et al., “Effects of La2O3 addition on microstructure development and physical properties of harder ZTA–CeO2 composites with sustainable high fracture toughness,” J. Rare Earths, 39(7), 844 – 849 (2021).
The research was supported by the Russian Science Foundation, Grant No. 21-79-00306; https://rscf.ru/project/21-79-00306/. The research was performed using equipment at the CUC Structure and Mechanical and Physical Properties of Materials at NSTU.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Novye Ogneupory, No. 6, pp. 17 – 20, June, 2022.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Cherkasova, N.Y., Kuz’min, R.I., Antropova, K.A. et al. Rheological Characteristics of Suspensions and Structure of Al2O3–CaO and Al2O3–SrO Composites. Refract Ind Ceram 63, 311–314 (2022). https://doi.org/10.1007/s11148-022-00727-4
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11148-022-00727-4