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Cement-Free Refractory Concretes. Part 5. Cement-Free Refractory Concretes Based on Hydraulic Alumina Binders

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Refractories and Industrial Ceramics Aims and scope

CFRC based on alumina hydraulic binders are similar with respect to hardening mechanism to low-cement refractory concretes (LCRC) and ultralow cement concretes (ULCRC). They are characterized by significant strengthening in the heat treatment temperature range 200 – 300°C and severe weakening in the range 600 – 1000°C. By introducing silica sols or microsilica into their composition it is possible not only to reduce or eliminate the weakening effect, but also to increase their strength after firing due to mullite formation. CFRC based on alumina binders have improved thermomechanical properties compared with LCRC. Comparative evaluation of CFRC based on hydraulic binders with other types of refractory concretes is provided.

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References

  1. Yu. E. Pivinskii and M. A. Trubitsyn, “Refractory concretes of new generation. Cement free concretes,” Refractories, 31(7), 435 – 440 (1990).

    Article  Google Scholar 

  2. A. P. Luz, M. A. J. Braulio, and V. C. Pandolfelli, Refractory Castable Engineering, Goller Verlag GmbH, Baden-Baden, Germany (2015).

    Google Scholar 

  3. S. Banerjee, Monolithic Refractories: a Comprehensive Handbook. World Scientific, The American Ceramic Society: Singapore (1998).

    Book  Google Scholar 

  4. Yu. E. Pivinskii, Refractory and Ceramic Materials: in 2 Vol [in Russian], Stroizdat SPb, St. Petersburg (2003).

    Google Scholar 

  5. M. Nouri-Khezrabad, M. A. Braulio, V. C. Pandolfelli, et al., “Nano-bonded refractory castables,” Ceram. Int., 39, 3479 – 3497 (2013).

    Article  CAS  Google Scholar 

  6. I. R. Sarkar, “Nanotechnology in refractory castables an overview,” Refractories World Forum, 10(1), 22 – 31 (2018).

    Google Scholar 

  7. Chr. Parr, J. M. Auvray, M. Szepizdyn, et al., “A review of bond systems for monolithic castable refractories,” Refractories World Forum, 7(2), 62 – 72 (2015).

  8. Y. Hongo, “P-alumina bonded castable refractories,” Taikabutsu Overseas, 9(1), 35 – 38 (1988).

    Google Scholar 

  9. W. Ma and P.W. Brown, “Mechanisms of reaction of hydratable aluminas,” J. Am. Ceram. Soc., 82(2), 453 – 456 (1999).

    Article  CAS  Google Scholar 

  10. New Almatis Alphabond 300 global product data sheet. GP-RCP/015/R04/1207/MSDS 834 (2004).

  11. Raymond P. Rachet, Rainer Kockegey-Lorenz, Gunter Buchel, et al., “Improvements in workability behavior of calcium-free hydratable alumina binders,” Proceeding of the UNITECR’O5, 2005, American Ceramic Society, Orlando.

    Google Scholar 

  12. R. Salomdo, M. A. Kawamura, A. D. V. Souza, and T. Sakihama, “Hydratable alumina-bonded suspensions. Evolution of microstructure and physical properties during first heating,” Interceram Refractories Manual, 28 – 37 (2017).

  13. Ju Zhang, QuanliJia, ShuaiYan, et al., “Microstructure and properties of hydratable alumina bonded bauxite-andalusite based castables,” Ceram. lnt., No. 42, 310 – 316 (2016).

    CAS  Google Scholar 

  14. Yu. E. Pivinskii, “Cement-free refractory concretes. Part 1. General information. HCBS and ceramic concretes,” Refract. Ind. Ceram., 60(5), 430 – 438 (2019).

    Article  CAS  Google Scholar 

  15. Yu. E. Pivinskii, P. V. Dyakin, E. M. Grishpun, and A. M. Gorokhovskii, “Cement-free refractory concretes. Part 2. High-alumina and corundum ceramic concretes,” Refract. Ind. Ceram., 60(6), 566 – 573 (2019).

    Article  CAS  Google Scholar 

  16. Yu. E. Pivinskii, “Cement-free refractory concretes. Part 3. Very fine forms of alumina as effective components of refractory concretes,” Novye Ogneupory, No. 1, 28 – 38 (2020).

  17. Yu. E. Pivinskii, “Cement-free refractory concretes. Part 4. Refractory concretes based on silica sol binder,” Novye Ogneupory, No. 3, 20 – 29 (2020).

  18. M. A. Braulio, C. Tontrup, J. Medeiros, and Y. C. Pandolfelli, “Colloidal alumina as a refractory binder,” Proceedings of 35th Alajar Congress, Lima, Peru (2000).

    Google Scholar 

  19. R. Lorenz, G. Buchel, A. Buhr, et al., “Improved workability of calcia free alumina binder alphabond for non-cement castables,” Proceedings of the 47th International Colloquium on Refractories, Aachen, Germany (2004).

    Google Scholar 

  20. Yu. E. Pivinskii and V. Yu. Belousovo, “A study of components of the binding (matrix) system of new refractory concretes. Part 1. Components and general characteristics of binding systems,” Refract. Ind. Ceram., 40(11), 548 – 552, (1999).

    Article  CAS  Google Scholar 

  21. Yu. E. Pivinskii, Rheology of Dispersed Systems, HCBS, and ceramic Concretes. Elements of nanotechnology in Silicate Materials Science: in 3 Vol. [in Russian], Politekhnika, St. Petersburg (2012).

    Google Scholar 

  22. I. A. Kainarskii, É. V. Degtyareva, and I. G. Orlova, Corundum Refractories and Ceramics [in Russian], Metallurgiya, Moscow (1981).

    Google Scholar 

  23. G. Byukhel’, I. Shtinnessen, D. Girish, et al., “Nature of concrete ageing containing Alphabond and aluminocalcium cement,” Novye Ogneupory, No. 3, 127 – 133 (2007).

  24. M. R. Ishmael, P. Bonadia, and V. S. Pandolfelli,” Thermomechanical properties of colloidal silica containing castables,” Refractories Applications and News, 15(1), 19 – 23 (2010).

    Google Scholar 

  25. M. Myhre and K. Sunde, “Alumina based castables with very low contents of hydraulic compound. Part. 2. Strength of high temperature reactions of no-cement castables with hydraulic alumina and microsilica,” Proc. UNITECR ‘95, Kyoto, Japan, Part 2, 317 – 324 (1995).

  26. A. R. Studdart and V. S. Pandolfeli, “The thermomechanical behavior zero cement high-alumina castables,” Amer. Ceram. Soc. Bull., 79(10), 53 – 60 (2000).

    Google Scholar 

  27. Yu. E. Pivinskii, “Ceramic castables stage in the evaluation of flow-cement refractory concretes. Part 1,” Refract. Ind. Ceram., 41(1/2), 3 – 7 (2000).

    Article  CAS  Google Scholar 

  28. Yu. E. Pivinskii, Fundamentals of the technology of ceramoconcrete,” Refractories, 19(1/2), 102 – 111 (1978).

    Article  Google Scholar 

  29. Yu. E. Pivinskii and O. G. Us’yarov, “A new generation of unshaped refractories,” Refract. Ind. Ceram., 47(1), 30 – 36 (2006).

    Article  CAS  Google Scholar 

  30. W. Zhong, R. Hubner, N. Rodrigez, and V. S. Pandolfeli, “Effect of hydratable alumina binder on the creep begavior of cement-free high-alumina refractory castables,” UNITECR 97 Congress Proceedings, 3, 1337 – 1346.

  31. Yu. E. Pivinskii and P. V. Dyakin, “Preparation and properties of corundum HCBS and ceramic concretes. Part l. Mixed HCBS in the system electrocorundum – very fine quartz glass,” Refract. Ind. Ceram., 51(1), 25 – 31 (2010).

    Article  CAS  Google Scholar 

  32. Yu. E. Pivinskii and P. V. Dyakin, “Preparation and properties of corundum HCBS and ceramic concretes. Part 2. Composition and properties of compacted ceramic concretes,” Refract. Ind. Ceram., 51(1), 39 – 46 (2010)

    Article  CAS  Google Scholar 

  33. Yu. E. Pivinskii and P. V. Dyakin, “Preparation and properties of corundum HCBS and ceramic concretes. Part 3. Casting and volume constancy of ceramic concretes,” Refract. Ind. Ceram., 51(1), 88 – 94 (2010).

    Article  CAS  Google Scholar 

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Correspondence to Yu. E. Pivinskii.

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Translated from Novye Ogneupory, No. 7, pp. 25 – 35, July, 2020.

Continuation. Parts 1 – 4 of the article published in Novye Ogneupory Nos. 9 and 11 (2019) and Nos. 1 and 3 (2020).

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Pivinskii, Y.E., Dyakin, P.V. Cement-Free Refractory Concretes. Part 5. Cement-Free Refractory Concretes Based on Hydraulic Alumina Binders. Refract Ind Ceram 61, 374–383 (2020). https://doi.org/10.1007/s11148-020-00489-x

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  • DOI: https://doi.org/10.1007/s11148-020-00489-x

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