Features are studied for sintering materials prepared by semidry compaction using potassium polytitanate as a precursor powder, modified with cobalt compounds and given preliminary heat treatment at 700°C. Phase composition, thermomechanical and electrophysical properties of ceramic specimens synthesized at 700, 950, and 1100°C are studied. The mechanism of processes occurring during sintering the ceramic studied at different temperatures and its effect of ceramic properties is studied. It is shown that at 700°C optimum properties are exhibited by ceramic specimens sintered below 750°C. The possibility is considered of using ceramic of this type within the composition of thermoelectric and thermoelectrochemical units intended for energy accumulation from dissipated heat of metallurgical production furnace equipment.
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References
S. Somiya, Advanced Technical Ceramics, Acad. Press Inc., Tokyo (1988).
T. Sanchez-Monjaras, A. V. Gorokhovsky, and J. I. Escalante-Garcia, “Molten salt synthesis and characterization of polytitanate ceramic precursors with varied TiO2/K2O molar ratio,” J. Amer. Ceram. Soc., 91(9), 3058 – 3065 (2008).
A. V. Gorokhovsky, A. I. Palagin, L. G. Panova, et al., “Production of submicro-nanosize potassium polytitanates and composite materials based on them,” Nanotekhnika, No. 19, 38 – 44(2009).
A. V. Kovnev, V. G. Goffman, A. V. Gorokhovsky, et al., “Impedance spectroscopy of potassium polytittanate modified with cobalt salts,” Élektrokhim. Énergetika, No. 3, 110 – 116 (2014).
E. I. Burmakin and G. Sh. Shektman, “Potassium-cation conductivity in K3 – 2x P x PO4 solid solutions,” Fiz. Tverd. Tela., 56(6), 1176 – 1179 (2014).
A. V. Gorokhovsky, E. V. Tretyachenko, J. I. Escalante-Garcia, et al., “Modified amorphous layered titanates as precursor materials to produce heterostructured nanopowders and ceramic nanocomposites,” J. Alloy. Compd., 586, S494 – S497 (2014).
E. V. Tretyachenko, A. V. Gorokhovsky, G. Y. Yurkov, et al., “Adsorption and photo-catalytic properties of layered lepidocrocite-like quasi-amorphous compounds based on modified potassium polytitanate,” Particuology, 17, 22 – 28 (2014).
T. Yu. Vergent’ev, E. Yu. Koroleva, D. A. Kurdyukov, et al., Behavior of low-frequency conductivity of nanocomposite silver iodide in the region of super-ion phase transiton,” Fiz. Tved. Tela., 55(1), 157 – 162 (2013).
The work was carried out with financial support of the RF Ministry of Education and Science within the scope of a state assignment (project No. 1242).
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Gorshkov, N.V., Goffman, V.G., Khoryukov, A.S. et al. High-Temperature Engineering Ceramic Based on Complex Titanates Having a Hollandite Structure. Refract Ind Ceram 57, 413–416 (2016). https://doi.org/10.1007/s11148-016-9995-5
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DOI: https://doi.org/10.1007/s11148-016-9995-5