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Carbon Diffusion within Periclase During Melting

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Refractories and Industrial Ceramics Aims and scope

Physicochemical possibilities are considered for entry of carbon into the structure of fuzed MgO during crystallization from a melt. It is established that fuzed periclase contains carbon, which during periclase grinding is concentrated at the surface of MgO crystals. With fine milling in a vibration mill carbon concentration is higher at the surface of MgO than with milling in a jet mill, and comprises 41.40 and 35.42 wt.% respectively. Melting MgO in an experimental electric arc furnace confirms the possibility of preparing periclase saturated with carbon.

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Notes

  1. K. G. Zemlyanoi, “Effect of grinding methods on sintering materials in the system Al2O3–MgO–SiO2–CaO–Cr2O3,” Diss. Cand. Tech. Sci., Ekaterinburg (2013).

References

  1. I. D. Kashcheev, Oxide-Carbon Refractories [in Russian], Intermet Inzhiniring, Moscow (2000).

    Google Scholar 

  2. V. G. Sivash, V. A. Prepelitsyn, and N. A. Mityushov, Fuzed Periclase [in Russian], Ural. Rabochii, Ekaterinburg (2001).

    Google Scholar 

  3. A. M. Cherepanov and S. G. Tresvyatskii, Highly Refractory Materials and Objects Made from Oxides [in Russian], Metallurgiya, Moscow (1964).

    Google Scholar 

  4. G. Routschka and H. Wutnow, Refractory Materials : Design-Properties-Testing, Vulkan-Verlab GmbH, Essen (2012).

    Google Scholar 

  5. I. S. Kulikov, Oxide Thermodynamics: Reference edition [in Russian], Metallurgiya, Moscow (1986).

    Google Scholar 

  6. B. S. Mamykin, I. D. Kashcheev, and V. A. Perepelitsyn, “Effect of carbon on growth of magnesium oxide crystals from a gas phase,” Izv. Akad. Nauk SSSR, Neorgan. Materialy, No. 7, 1218 – 1223 (2969).

  7. M. I. Rogalin and E. F. Chalykh, Handbook for Carbon-Graphite Materials [in Russian], Khimiya, Leningrad (1974).

    Google Scholar 

  8. V. P. Elyutin, Yu. A. Pavlov, V. P. Polyakov, et al., Reaction of Metal Oxides with Carbon [in Russian], Metallurgiya, Moscow (1976).

    Google Scholar 

  9. A. Kurdyumov, V. G. Malogolovets, N. V. Novikov, et al., Polymorphic Modification of carbon and Boron Nitride: Reference edition [in Russian], Metallurgiya, Moscow (1994).

    Google Scholar 

  10. E. P. Abramov, A. A. Vyatkin, I. D. Kashcheev, and B. P. Aleksandrov, RF. Patent 188807, MPK C 04 B 35/04, 35.657, Method for preparing black periclase, Publ. 2003, Byul. No. 12.

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Correspondence to I. D. Kashcheev.

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Translated from Novye Ogneupory, No. 11, pp. 26 – 30, November, 2014.

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Kashcheev, I.D., Zemlyanoi, K.G. Carbon Diffusion within Periclase During Melting. Refract Ind Ceram 55, 511–515 (2015). https://doi.org/10.1007/s11148-015-9755-y

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  • DOI: https://doi.org/10.1007/s11148-015-9755-y

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