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MnOx effect on the performance of Cu-based catalysts in ethynylation of formaldehyde for 1,4-butynediol synthesis

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Abstract

A Cu-based catalyst has been widely used in ethynylation of formaldehyde for synthesis of 1,4-butynediol. Herein, bismuth, magnesium, and manganese species were separately doped into Cu-based catalysts by a co-precipitation method and applied in ethynylation reaction. All catalysts were characterized through X-ray diffraction (XRD), Transmission electron microscope (TEM), H2 temperature-programmed reduction (H2-TPR), scanning electron microscopy (SEM) and elements mapping, Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). The results show that Mn-doped Cu-based catalysts exhibit the best yield of 1,4-butynediol (65%). It is mainly due to CuO in CuO/MnOx catalysts with smaller particle size, better dispersibility and the electronic synergy between copper and manganese species. Moreover, CuO/MnOx-15 catalysts prepared by optimized conditions can further improve the yield and selectivity of 1,4-butynediol to 76% and 96% and remain selectivity of 1,4-butynediol unchanged in about 50 h, which is higher than that of the commercial catalyst (yield of 62%, selectivity of 90%).

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Acknowledgements

This research is financially supported by the Natural Science Foundation of Xinjiang Uygur Autonomous Region (2019D01C046), the Doctoral Scientific Research Foundation of Xinjiang University, China (BS160226), and the State Key Laboratory of Fine Chemicals, Dalian University of Technology (KF 2103).

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Authors and Affiliations

  1. Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education and Xinjiang Uyghur Autonomous Region, College of Chemical Engineering of Xinjiang University, Urumqi, 830017, China

    Guihua Yang, Feng Gao, Linxue Yang & Jide Wang

  2. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, China

    Guihua Yang

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  1. Guihua Yang
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  2. Feng Gao
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  3. Linxue Yang
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Correspondence to Guihua Yang.

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Yang, G., Gao, F., Yang, L. et al. MnOx effect on the performance of Cu-based catalysts in ethynylation of formaldehyde for 1,4-butynediol synthesis. Reac Kinet Mech Cat 135, 2611–2627 (2022). https://doi.org/10.1007/s11144-022-02265-z

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  • DOI: https://doi.org/10.1007/s11144-022-02265-z

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