Skip to main content
SpringerLink
Log in

New type of oscillatory processes—oxidative carbonylation of alkynes in the homogeneous catalysis by Pd complexes. Phenylacetylene

  • Published:
Reaction Kinetics, Mechanisms and Catalysis Aims and scope Submit manuscript

Abstract

The purpose of this review is to acquaint readers with the main results of concentration oscillation studies in the reaction of phenylacetylene oxidative carbonylation proceeding under the conditions of homogeneous metal complex catalysis. It was shown that the oscillatory regime is realized in the range of concentrations and partial pressures limited by some rigorous frames. Some interesting features of this process were studied. The products of this reaction have been identified.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Field RJ, Burger M (1985) Oscillations and traveling waves in chemical systems. Wiley, New York

    Google Scholar 

  2. Bruk LG, Temkin ON (1993) State of research and prospects of the development of syntheses based on carbon monoxide and acetylenic compounds. Khim Prom 5:57–63 (In Russian)

    Google Scholar 

  3. Bruk LG, Oshanina IV, Zakieva AS, Kozlova AP, Temkin ON (1998) Critical phenomena in the homogeneous catalytic process of acetylene carbonylation to maleic anhydride. Kinet Catal 39(2):183–186 (In Russian)

    Google Scholar 

  4. Zhabotinskii AM (1974) Concentration oscillations. Nauka, Moscow (In Russian)

    Google Scholar 

  5. Gray P, Scott SK (1994) Chemical oscillations and instabilities. Non-linear chemical kinetics. Clarendon Press, Oxford

    Google Scholar 

  6. Epstein IR, Pojman JA (1998) An introduction to nonlinear chemical dynamics. Oxford University Press, New York

    Google Scholar 

  7. Tayson JJ (1976) BZ-reaction. Springer, Berlin

    Google Scholar 

  8. Slin’ko MM, Jaeger NI (1994) Oscillating heterogeneous catalytic systems. Elsevier, Amsterdam

    Google Scholar 

  9. Ivanitskii GR, Krinskii VI, Sel’kov EE (1978) Mathematical cell biophysics. Nauka, Moscow (In Russian)

    Google Scholar 

  10. Shul’akovsky GM, Temkin ON, Bykanova NV, Nyrkova AN (1985) Chemical kinetics in catalysis: kinetic models of liquid-phase reactions. IPC, Chernogolovka (In Russian)

    Google Scholar 

  11. Malashkevich AV, Bruk LG, Temkin ON (1997) New oscillating reaction in catalysis by metal complexes: a mechanism of alkyne oxidative carbonylation. J Phys Chem A 101(51):9825–9827

    Article  CAS  Google Scholar 

  12. Gorodsky SN, Zakharov AN, Kulik AV, Bruk LG, Temkin ON (2001) Kinet Catal 42(2):280

    Google Scholar 

  13. Gorodsky SN, Kalenova ES, Bruk LG, Temkin ON (2003) Rus Chem Bull 7:1452

    Google Scholar 

  14. Gorodsky SN, Novakovic K (2010) Fine Chem Technol 5(5):47 (In Russian)

    Google Scholar 

  15. Gorodsky SN, Kurdukov AV, Temkin ON (2008) Fine Chem Technol 5(1):35 (In Russian)

    Google Scholar 

  16. Gorodsky SN (2011) Fine Chem Technol 6(6):3 (In Russian)

    Google Scholar 

  17. Gorodsky SN, Bruk LG, Istomina AE, Kurdiukov AV, Temkin ON (2009) Top Catal 52(6–7):557

    Article  CAS  Google Scholar 

  18. Gorodsky SN (2009) Proceeds of EuropaCat IX, catalysis for a sustainable world, Spain, Salamanca, August 30–September 4, p 579

  19. Gorodsky SN (2011) Proceeds of 43rd IUPAC world chemistry congress. San-Juan, Puerto Rico, July 30–August 5, p 426

  20. Novakovic K, Grosjean C, Scott SK, Whiting A, Willis MJ, Wright AR (2007) Achieving pH and Qr oscillations in a palladium catalysed phenylacetylene oxidative carbonylation reaction using an automated reactor system. Chem Phys Lett 435:142–147

    Article  CAS  Google Scholar 

  21. Novakovic K, Grosjean C, Scott SK, Whiting A, Willis MJ, Wright AR (2008) The influence of oscillations on product selectivity during the palladium-catalysed phenylacetylene oxidative carbonylation reaction. Phys Chem Chem Phys 10:749–753

    Article  CAS  Google Scholar 

  22. Grosjean C, Novakovic K, Scott SK, Whiting A, Willis MJ, Wright AR (2008) Product identification and distribution from the oscillatory versus non-oscillatory palladium (II) iodide-catalysed oxidative carbonylation of phenylacetylene. J Mol Catal A 284:33–39

    Article  CAS  Google Scholar 

  23. Novakovic K, Mukherjee A, Willis M, Wright A, Scott SK (2009) The influence of reaction temperature on the oscillatory behaviour in the palladium-catalysed phenylacetylene oxidative carbonylation reaction. Phys Chem Chem Phys 11:9044–9049

    Article  CAS  Google Scholar 

  24. Gorodsky SN (2001) Development of the kinetic model of self-oscillatory process of alkynes oxidative carbonylation catalyzed by palladium complexes. PhD thesis in Chemistry. Lomonosov’s MITHT, Moscow

  25. Vanag VK, Alfimov MV (1993) J Phys Chem A 97(9):1884

    Article  CAS  Google Scholar 

  26. Noyes RM (1990) J Phys Chem A 94(11):4404

    Article  CAS  Google Scholar 

  27. Kuhnert L (1986) React Kinet Catal Lett 31(1):227

    Article  CAS  Google Scholar 

  28. Temkin ON, Shul’akovsky GM, Bruk LG (1983) Chim Prom 5:22

    Google Scholar 

  29. Temkin ON, Kaliya OL, Zhir-Lebed’ LN, Golodov VA, Bruk LG, Mehryakova NG (1978) On the mechanism of carbon monoxide reactions in aqueous and alcoholic solutions of palladium complexes. Homogeneous oxidation. Nauka, Alma-Ata, vol 17, pp 3–33 (In Russian)

  30. Temkin ON, Bruk LG (1983) Pd(I) complexes in coordination chemistry and catalysis. Uspechy khimii 52(2):206–243 (In Russian)

    CAS  Google Scholar 

  31. Bruk LG, Flid VR, Temkin ON, Ustenko IS, Goncharova ZV (1978) Reac Kinet Catal Lett 9:303

    Article  CAS  Google Scholar 

  32. Fadeev SI, Gainova IA, Berezin AYU (1995) Application of the “STEP” package for the numerical study of nonlinear equations systems and autonomous systems of general form. Institute of Mathematics, Novosibirsk (In Russian)

    Google Scholar 

  33. Temkin ON, Zeigarnik AV, Valdes-Perez RE, Bruk LG (2000) Kinet Catal 41(3):331

    Article  Google Scholar 

  34. Ellison P, Feinberg M, Yue M-H, Saltsburg H (2000) J Mol Catal A Chem 154:169

    Article  CAS  Google Scholar 

  35. Aris R (1965) Introduction to the analysis of the chemical reactors. Prentice-Hall, Englewood Cliffs

    Google Scholar 

  36. Volter BV, Sal’nikov IE (1982) Stability of work regimes of the chemical reactors, 2nd edn. Khimiya, Moscow (In Russian)

    Google Scholar 

Download references

Acknowledgements

The author would like to express his sincere gratitude to all colleagues who took part in obtaining of the experimental data, discussing theoretical assumptions and conclusions.

Author information

Authors and Affiliations

  1. Lomonosov’s MITHT, 86 Vernadsky Av, Moscow, Russia

    S. N. Gorodsky

Authors
  1. S. N. Gorodsky
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. N. Gorodsky.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 2758 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gorodsky, S.N. New type of oscillatory processes—oxidative carbonylation of alkynes in the homogeneous catalysis by Pd complexes. Phenylacetylene. Reac Kinet Mech Cat 123, 93–112 (2018). https://doi.org/10.1007/s11144-017-1300-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11144-017-1300-1

Keywords

Search

Navigation