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Decomposition of methanol on ZnO(CeO2, La2O3)-CuO-NiO-based monoliths

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Abstract

An influence of nickel oxide as a component of ZnO(CeO2, La2O3)-CuO-NiO/Al2O3 based catalysts, supported by structured ceramic monoliths, on their operation in methanol decomposition is studied. The results obtained, including with use of XRD, SEM, TPR techniques, show that NiO-doping causes promoting effect achieving 90–96 % of hydrogen yield as a target product at moderate temperatures of 250–320 °C. We attribute this effect to a decreased reducibility of a copper oxide within the catalyst composition.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kiev, 03028, Ukraine

    Andriy Yu. Kapran, Svitlana N. Orlyk & Sergiy O. Soloviev

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  1. Andriy Yu. Kapran
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  2. Svitlana N. Orlyk
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  3. Sergiy O. Soloviev
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Correspondence to Andriy Yu. Kapran.

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Kapran, A.Y., Orlyk, S.N. & Soloviev, S.O. Decomposition of methanol on ZnO(CeO2, La2O3)-CuO-NiO-based monoliths. Reac Kinet Mech Cat 114, 135–145 (2015). https://doi.org/10.1007/s11144-014-0765-4

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  • DOI: https://doi.org/10.1007/s11144-014-0765-4

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