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Highly Dispersed Powders in Boride–Silicide Systems

  • THEORY, MANUFACTURING TECHNOLOGY, AND PROPERTIES OF POWDERS AND FIBERS
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Powder Metallurgy and Metal Ceramics Aims and scope

Nanosized composite powders with a composition of titanium diboride–silicides of group IV–VI transition metals are obtained in boride–silicide systems by mechanochemical synthesis for 5–30 min. The initiation effect of TiB2 on the formation of silicide phases during joint mechanochemical synthesis is shown. It is established that the powder particles are 40–70 nm in size. The powders tend to agglomerating. The properties of hot-pressed compacted TiB2–20 wt.% MoSi2 samples are studied: ultimate bending strength 421 ± 29 MPa; microhardness 25 ± 0.8 GPa. Electrolytic Ni–TiB2–MoSi2 coating possesses high wear-resistance in sliding friction and can be recommended for hardening and recovering the surfaces of machinery and mechanical parts.

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References

  1. T. I. Serebryakova, V. A. Neronov, and P. D. Peshev, High-Temperature Borides [in Russian], Metallurgiya, Moscow (1991), 367 p.

    Google Scholar 

  2. T. Ya. Kosolapova (Ed.), Properties, Production, and Application: Handbook [in Russian], Metallurgiya, Moscow (1986), 928 p.

  3. G. V. Samsonov, L. A. Dvorina, and B. M. Rud’, Silicides [in Russian], Metallurgiya, Moscow (1979), 272 p.

  4. K. Biswas, B. Basu, A. R. Suri, and K. Chattopadhyay, “A TEM study on TiB2–MoSi2 composite: microstructure development and densification mechanism,” Scr. Mater., 54, 1363–1368 (2006).

    Article  Google Scholar 

  5. A. Mukhopadhyay, G. B. Raju, B. Basu, and K. Suri, “Correlation between phase evolution, mechanical properties and instrumented indentation response of TiB2–based ceramics,” J. Eur. Ceram. Soc., 29, 505–516 (2009).

    Article  Google Scholar 

  6. T. S. R. Ch. Murthy, J. K. Sonber, C. Subramanian, et al., “A new TiB2–CrSi2 composite — densification, characterization and oxidation studies,” Int. J. Refract. Met. Hard Mater., 28, No. 4, 529–540 (2010).

    Article  Google Scholar 

  7. G. B. Raju and B. Basu, “Oxidation kinetics and mechanism of hot-pressed TiB2–MoSi2 composites,” J. Am. Ceram. Soc., 91, No. 10, 3320–3327 (2008).

    Article  Google Scholar 

  8. P. Yu. Butyagin, “On dynamics of mechano-chemical synthesis,” Dokl. AN SSSR, 319, No. 2, 384–388 (1991).

    Google Scholar 

  9. P. Yu. Butyagin, “Problems and prospects of development of mechanochemistry,” Usp. Khimii, 63, No. 12, 1031–1043 (1994).

    Google Scholar 

  10. K. N. Yegorychev, V. V. Kurbatkina, E. Yu. Nesterova, et al., “Studying interaction in titanium–silicon system, when using mechanical activation of starting components,” Izv. Vuzov. Tsvet. Metall., No. 2, 49–54 (1996).

    Google Scholar 

  11. K. N. Yegorychev, V. V. Kurbatkina, and K. V. Kolesnichenko, “Interaction in titanium–boron–silicon, titanium–carbon–silicon, and titanium–carbon–silicon systems, when using mechanical activation of starting components,” Izv. Vuzov. Tsvet. Metall., No. 2, 47–50 (1999).

  12. E. P. Shelekhov, O. N. Pripisnov, and S. I. Rupasov, “Diffusion and phase formation in mechanically activated systems Cr–C, Cr–Si, Cr–B,” Izv. Vuzov. Tsvet. Metall., No. 6, 66–71 (2001).

  13. B. K. Yen, “Self-propagating exothermic reactions between silicon and transition metals of groups IV–VI induced by mechanical alloying,” J. Appl. Phys., 89, No. 2, 1477–1482 (2001).

    Article  Google Scholar 

  14. L. Takacs, “Self-sustaining reactions induced by boll milling: An overview,” Int. J. Self-Propag. High-Temp. Syn., 18, No. 4, 276–282 (2009).

    Article  Google Scholar 

  15. B. K. Yen, “X-ray diffraction study of mechanochemical synthesis and formation mechanisms of zirconium carbide and zirconium silicides,” J. All. Compd., 268, Nos. 1–2, 266–269 (1998).

    Article  Google Scholar 

  16. R. B. Schwariz, S. R. Srinivasen, J. J. Petrovic, and C. J. Maggiore, “Synthesis of molybdenum disilicide by mechanical alloying,” Mater. Sci. Eng. A, 155, Nos. 1–2, 75–83 (1992).

    Article  Google Scholar 

  17. C. Suryanarayana (Ed.), Non-equilibrium Processing of Materials, 1-st Ed. Vol 2, Pergamon Materials Series, Oxford (1999), p. 437.

  18. K. N. Yegorychev, A. G. Yermiliv, and S. I. Rupasov, “Effect of mechanical activation on the interaction in Mo–Si system,” Izv. Vuzov. Tsvet. Metall., No. 1, 52–57 (1996).

  19. D. Radev and D. Klissurski, “Mechanochemical synthesis and SHS of diborides of titanium and zirconium,” J. Mater. Synthesis Proc., 9, No. 3, 131–136 (2001).

    Article  Google Scholar 

  20. K. B. Shelimov and P. Yu. Butyagin, “Explosive mechanochemical synthesis of refractory compounds,” Dokl. AN SSSR, 316, No. 6, 1439–1443 (1991).

    Google Scholar 

  21. T. S. R. Ch. Murthy, B. Basu, A. Srivastava, et al., “Tribological properties of TiB2 and TiB2–MoSi2 ceramic composites,” J. Eur. Ceram. Soc., 26, No. 7, 1293–1300 (2006).

    Article  Google Scholar 

  22. I. M. Fedorchenko, Yu. A. Guslienko, and A. P. Epik, “Composite nickel–boron electrolytic coatings,” Powder Metall. Met. Ceram., 11, No. 8, 626–628 (1972).

    Google Scholar 

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Correspondence to D. P. Zyatkevich.

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Translated from Poroshkovaya Metallurgiya, Vol. 56, Nos. 9–10 (517), pp. 3–13, 2017.

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Makarenko, G.N., Krushinska, L.A., Timofeeva, I.I. et al. Highly Dispersed Powders in Boride–Silicide Systems. Powder Metall Met Ceram 56, 487–495 (2018). https://doi.org/10.1007/s11106-018-9920-1

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  • DOI: https://doi.org/10.1007/s11106-018-9920-1

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