Abstract
V2O5 and 1 mol% RE-doped V2O5 (RE = La, Er, Yb) thin films were prepared using the sol–gel method. The structure and morphology of the prepared films were investigated using XRD, HRTEM, SAD electron microscopy, FESEM, and EDS. XRD analysis revealed a strong c-axis orientation and noncrystalline structure. Gaussian fitting of the XRD peaks indicates a decrease in the crystallite size with RE doping, which is attributed to the increased internal stress and lattice distortion. TC analysis showed a preferred orientation along the c-axis. HRTEM observations confirmed the crystallinity of the nanosheets. The absorption, transmittance, and reflectance spectra were measured for normal-incidence light in the wavelength range 190–1100 nm. The obtained spectra were used to investigate the linear and non-linear optical properties via various optical parameters, including static refractive index, optical band gap energy, Urbach band tail energy, dispersion energy parameters using the Wemple and DiDomenico (WDD) single-oscillator model, nonlinear refractive index and first and third optical susceptibilities. The doped films exhibited lower optical bandgaps and the investigated linear and nonlinear optical parameters showed significant effects in RE-doped films compared to pure V2O5, indicating potential for various optical applications. The optical limiting of the prepared films was studied using two laser sources (650 nm and 533 nm), revealing significant optical limiting for RE-doped films compared with pure V2O5 films, where the optical limiting effect is related to the oscillator strength and Urbach band tail energy. This study shows that rare-earth doping has a significant impact on the structural and optical properties of V2O5 thin films, making them promising materials for various applications, such as optoelectronic devices and nonlinear optical applications.
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Abdelrazek, M.M., Hannora, A.E., Kamel, R.M., Morad, I., El-Desoky, M.M.: Effect of lanthanum doping on the structure and optical properties of nanocrystalline vanadium pentoxide films prepared by sol–gel method. Opt. Quantum Electron. 55(6), 491–520 (2023)
Abdulgafour, H.I., Zainulabdeen, F.S., Karam, G.S., Mageed, H.C., Najim, A.A., Hassan, F.M.: Synthesis and characterization of Al-doped ZnO thin films as anti-reflection coatings for solar cell applications. Surf. Rev. Lett. (2023). https://doi.org/10.1142/S0218625X24500471
Abyazisani, M., Bagheri-Mohagheghi, M.M., Benam, M.R.: Study of structural and optical properties of nanostructured V2O5 thin films doped with fluorine. Mater. Sci. Semicond. Process. 31, 693–699 (2015)
Adair, R., Chase, L.L., Payne, S.A.: Nonlinear refractive index of optical crystals. Phys. Rev. B 39(5), 3337–3350 (1989)
Afify, H.H., Hassan, S.A., Obaida, M., Abouelsayed, A.: Influence of annealing on the optical properties of monoclinic vanadium oxide VO2 prepared in nanoscale by hydrothermal technique. Phys. E: Low-Dimens. Syst. Nanostruct. 114, 113610–113617 (2019)
Al-Assiri, M., El-Desoky, M., Alyamani, A., Al-Hajry, A., Al-Mogeeth, A., Bahgat, A.: Spectroscopic study of nanocrystalline V2O5· nH2O films doped with Li ions. Opt. Laser Technol. 42(6), 994–1003 (2010a)
Al-Assiri, M., et al.: Spectroscopic study of nanocrystalline V2O5· nH2O films doped with Li ions. J Opt. 42(6), 994–1003 (2010b)
Aldebert, P., Baffier, N., Gharbi, N., Livage, J.: Layered structure of vanadium pentoxide gels. Mater. Res. Bull. 16(6), 669–676 (1981)
Amlouk, A., Boubaker, K., Amlouk, M., Bouhafs, M.: Study of ytterbium doping effects on structural, mechanical and opto-thermal properties of sprayed ZnO thin films using the Boubaker Polynomials Expansion Scheme (BPES). J. Alloy. Compd. 485(1–2), 887–891 (2009)
Anyaegbunam, F.N.C., Augustine, C.: A study of optical band gap and associated urbach energy tail of chemically deposited metal oxides binary thin films. Dig. J. Nanomater. Biostruct. 3(3), 847–856 (2018)
Asha Hind, P., Patil, P.S., Gummagol, N.B., Rajendra, B.V.: Investigation of structure, morphology, photoluminescence, linear and third-order nonlinear optical properties of Sn1−xLaxO2 thin films for optical limiting applications. J. Alloys Compd. 892, 162070–162078 (2022)
Bahgat, A., Ibrahim, F., El-Desoky, M.: Electrical and optical properties of highly oriented nanocrystalline vanadium pentoxide. Thin Solid Films 489(1–2), 68–73 (2005)
Bahgat, A.A., Abd Rabo, A.S., Mahdy, I.A., Mahmoud, E.A.: Spectral features of Ge50− ySbxTe50− x+ y alloys where 0⩽ x⩽ 15 and 0⩽ y⩽ 30 in thin film state. Opt. Laser Technol. 40(8), 1061–1067 (2008)
Bahgat, A., Ibrahim, F., El-Desoky, M.: Nanocrystalline vanadium pentoxide xerogel properties and hydrogen sensing. AIP Conf. Proc. 1370(1), 61–67 (2011)
Caglar, M., Caglar, Y., Ilican, S.: The determination of the thickness and optical constants of the ZnO crystalline thin film by using envelope method. J. Optoelectron. Adv. Mater. 8(4), 1410–1413 (2006)
Chain, E.E.: Optical properties of vanadium dioxide and vanadium pentoxide thin films. Appl. Opt. 30(19), 2782–2787 (1991)
Cheng, J., Wang, J., Hou, J., Wang, H., Zhang, L.: Effect of polishing-induced subsurface impurity defects on laser damage resistance of fused silica optics and their removal with HF acid etching. Appl. Sci. 7, 1–23 (2017)
Chernova, N.A., Roppolo, M., Dillon, A.C., Whittingham, M.S.: Layered vanadium and molybdenum oxides: batteries and electrochromics. J. Mater. Chem. 19(17), 2526–2552 (2009)
Chikhale, L.P., Patil, J.Y., Rajgure, A.V., Shaikh, F.I., Mulla, I.S., Suryavanshi, S.S.: Structural, morphological and gas sensing properties of undoped and Lanthanum doped nanocrystalline SnO2. Ceram. Int. 40(1), 2179–2186 (2014)
Dan, S., Chatterjee, S., Paramanik, S., Pal, A.J.: Necessity of Quantifying urbach energy through scanning tunneling spectroscopy. J. Phys. Chem. Lett. 13, 1660–1667 (2022)
Dultsev, F., Vasilieva, L., Maroshina, S., Pokrovsky, L.: Structural and optical properties of vanadium pentoxide sol–gel films. Thin Solid Films 510(1–2), 255–259 (2006)
El-Desoky, M.M., Ali, M.A., Afifi, G., Imam, H.: Annealing effects on the structural and optical properties of growth ZnO thin films fabricated by pulsed laser deposition (PLD). J. Mater. Sci.: Mater. Electron. 25, 5071–5077 (2014)
El-Desoky, M.M., El-Barbary, G.A., El Refaey, D.E., El-Tantawy, F.: Optical constants and dispersion parameters of La-doped ZnS nanocrystalline films prepared by sol–gel technique. Optik 168, 764–777 (2018)
El-Desoky, M.M., Abdulrazek, M.M., Sharaby, Y.A.: Characterization and optical properties of reduced graphene oxide doped nano-crystalline vanadium pentoxide. Opt. Quantum Electron. 52(6), 315–344 (2020a)
El-Desoky, M.M., Abdulrazek, M.M., Sharaby, Y.A.: Fabrication and electrical properties of reduced graphene oxide doped nanocrystalline vanadium pentoxide films. Mater. Sci. Eng., B 261, 114676–114685 (2020b)
Long, M., Tang, L., Wang, D., Li, Y., Shuai, Z.: electronic structure and carrier mobility in graphdiyne sheet and nanoribbons: theoretical predictions. Acs Nano 5, 2593–2600 (2011)
Fang, D., et al.: Influence of Al doping on structural and optical properties of Mg–Al co-doped ZnO thin films prepared by sol–gel method. J. Alloy. Compd. 589, 346–352 (2014)
Farag, A.A.M., Ashery, A., Shenashen, M.A.: Optical absorption and spectrophotometric studies on the optical constants and dielectric of poly (o-toluidine)(POT) films grown by spin coating deposition. Phys. B 407(13), 2404–2411 (2012)
Fasasi, A.Y., et al.: Effect of precursor solvents on the optical properties of copper oxide thin films deposited using spray pyrolysis for optoelectronic applications. Am. J. Mater. Synth. Process 3(2), 12–22 (2018)
Frumar, M., Jedelský, J., Frumarova, B., Wagner, T., Hrdlička, M.: Optically and thermally induced changes of structure, linear and non-linear optical properties of chalcogenides thin films. J. Non-Cryst. Solids 326, 399–404 (2003)
Ghobadi, N.: Band gap determination using absorption spectrum fitting procedure. Int. Nano Lett. 3(1), 2 (2013)
Girisun, T.C.S., Dhanuskodi, S.: Nonlinear optical susceptibilities of diglycinyl thiourea for frequency conversion and optical limiting applications. Chem. Phys. Lett. 491(4–6), 248–253 (2010)
Gomaa, H.M., Yahia, I.S., Zahran, H.: Novel Empirical Correlation Between the Optical Refractive Index and Energy Bandgap in Semiconductors: Comparative Study. 2021
González-Leal, J.: The Wemple–DiDomenico model as a tool to probe the building blocks conforming a glass. Phys. status solidi (b) 250(5), 1044–1051 (2013)
Hameed, T.A., El Radaf, I.M., Elsayed-Ali, H.E.: Characterization of CuInGeSe 4 thin films and Al/n–Si/p–CuInGeSe 4/Au heterojunction device. J. Mater. Sci.: Mater. Electron. 29, 12584–12594 (2018)
Hassanien, A.S.: Studies on dielectric properties, opto-electrical parameters and electronic polarizability of thermally evaporated amorphous Cd50S50− xSex thin films. J. Alloy. Compd. 671, 566–578 (2016)
Herve, P., Vandamme, L.K.J.: General relation between refractive index and energy gap in semiconductors. Infrared Phys. Technol. 35(4), 609–615 (1994)
Hilborn, R.C.: Einstein coefficients, cross sections, f values, dipole moments, and all that. arXiv preprint physics/0202029, 2002.
Jerominek, H., Picard, F., Vincent, D.: Vanadium oxide films for optical switching and detection. Opt. Eng. 32(9), 2092–2099 (1993)
Jeyalakshmi, K., Vijayakumar, S., Nagamuthu, S., Muralidharan, G.: Effect of annealing temperature on the supercapacitor behaviour of β-V2O5 thin films. Mater. Res. Bull. 48(2), 760–766 (2013)
Kaelble, E.F.: Handbook of X-Rays: For Diffraction, Emission, Absorption, and Microscopy. ACS Publications, Washington (1967)
Kang, D., Jeon, E., Kim, S., Lee, J.: Lanthanide-doped upconversion nanomaterials: recent advances and applications. BioChip J. 14(1), 124–135 (2020)
Kenny, N., Kannewurf, C.R., Whitmore, D.H.: Optical absorption coefficients of vanadium pentoxide single crystals. J. Phys. Chem. Solids 27(8), 1237–1246 (1966)
Khmissi, H., Mahmoud, S.A., Akl, A.A.: Investigation of thermal annealing effect on the microstructure, morphology, linear and non-linear optical properties of spray deposited nanosized V2O5 thin films. Optik 227, 165979–165999 (2021)
Klein, L.C.: Sol-gel optics: processing and applications. Springer, Berlin (2013)
Kumar, V., Singh, J.K.: Model for calculating the refractive index of different materials (2010)
Lee, S.-W., et al.: UV degradation and recovery of perovskite solar cells. Sci Rep. 6, 38150–38159 (2016)
Legendre, J.-J., Aldebert, P., Baffier, N., Livage, J.: Vanadium pentoxide gels: II. Structural study by x-ray diffraction. J. Colloid Interface Sci. 94, 84–89 (1983)
Legrouri, A., Baird, T., Fryer, J.R.: Electron optical studies of fresh and reduced vanadium pentoxide-supported rhodium catalysts. J. Catal. 140(1), 173–183 (1993)
Li, L., et al.: The determination of the thickness and optical constants of the microcrystalline silicon thin film by using envelope method. Optoelectron. Adv. Mater. Rapid Commun. 3(6), 625–630 (2009)
Li, Z., Sun, H., Xu, J., Zhu, Q., Chen, W., Zakharova, G.S.: The synthesis, characterization and electrochemical properties of V3O7· H2O/CNT Nanocomposite. Solid State Ionics 262, 30–34 (2014)
Mady, H.A., Negm, S.E., Moghny, A.A., Abd-Rabo, A., Bahgat, A.: Study of optical properties of highly oriented nanocrystalline V 2 O 5· nH 2 O films doped with K ions. J. Sol-Gel. Sci. Technol. 62(1), 18–23 (2012)
Mahmoud, S.A.: Characterization of thorium dioxide thin films prepared by the spray pyrolysis technique. Solid State Sci. 4(2), 221–228 (2002)
Morigaki, K., Ogihara, C.: Amorphous semiconductors: Structure, optical, and electrical properties. In: Springer Handbook of Electronic and Photonic Materials: Springer, pp. 1–1 (2017)
Moss, T.S.: Relations between the refractive index and energy gap of semiconductors. Phys. status solidi (b) 131(2), 415–427 (1985)
Mrabet, C., Boukhachem, A., Amlouk, M., Manoubi, T.: Improvement of the optoelectronic properties of tin oxide transparent conductive thin films through lanthanum doping. J. Alloy. Compd. 666, 392–405 (2016)
Nagaraja, K.K., Pramodini, S., Kumar, A.S., Nagaraja, H.S., Poornesh, P., Kekuda, D.: Third-order nonlinear optical properties of Mn doped ZnO thin films under cw laser illumination. Opt. Mater. 35(3), 431–439 (2013)
Nagaraju, D.H., Wang, Q., Beaujuge, P., Alshareef, H.N.: Two-dimensional heterostructures of V2O5 and reduced graphene oxide as electrodes for high energy density asymmetric supercapacitors. J. Mater. Chem. A 2(40), 17146–17152 (2014)
Najim, A.A.: Synthesis and characterization of bismite nano-island thin films for optoelectronic applications. Mater. Sci. Semicond. Process. 121, 105334 (2021)
Najim, A.A., Gbashi, K.R., Salih, A.T.: Synthesis and characterization of nanocrystalline ba-doped Mn3O4 hausmannite thin films for optoelectronic applications. Int. J. Nanosci. 20(05), 2150040 (2021)
Najim, A.A., Hassan, F.M., Rasheed, H.S., Ismail, H., Darwoysh, H.H.: Experimental investigation to determine the optical properties of (Fe2O3)1–x(NiO)x thin films prepared by PLD technique for NLO applications. Opt. Mater. 121, 111602 (2021)
Nwofe, P., Reddy, K.R., Tan, J., Forbes, I., Miles, R.: Thickness dependent optical properties of thermally evaporated SnS thin films. Phys. Proc. 25, 150–157 (2012)
. Pankove, J.: Absorption. In: Optical Processes in Semiconductors: Prentice-Hall, Inc Englewood Cliffs, New Jersey, 1971, pp. 34–86
Parida, M.R., Vijayan, C., Rout, C.S., Sandeep, C.S.S., Philip, R., Deshmukh, P.C.: Room temperature ferromagnetism and optical limiting in V2O5 nanoflowers synthesized by a novel method. J. Phys. Chem. C 115(1), 112–117 (2011)
Pepe, Y., Tutel, Y., Yildiz, E.A., Karatay, A., Unalan, H.E., Elmali, A.: Thermally induced phase transition and defect-assisted nonlinear absorption and optical limiting in nanorod morphology V2O5 thin films. Adv. Eng. Mater. 23(10), 2100468 (2021)
Petkov, V., Trikalitis, P.N., Bozin, E.S., Billinge, S.J.L., Vogt, T., Kanatzidis, M.G.: Structure of V2O5.nH2O xerogel solved by the atomic pair distribution function technique. J. Am. Chem. Soc. 124(34), 10157–10162 (2002)
Prociow, E., Zielinski, M., Sieradzka, K., Domaradzki, J., Kaczmarek, D.: Electrical and optical study of transparent V-based oxide semiconductors prepared by magnetron sputtering under different conditions. Radioengineering 20(1), 204–208 (2011)
Ramana, C., Hussain, O., Naidu, B.S., Reddy, P.: Spectroscopic characterization of electron-beam evaporated V2O5 thin films. Thin Solid Films 305(1–2), 219–226 (1997)
Rasheed, H.S., Abdulgafour, H.I., Hassan, F.M., Najim, A.A.: Synthesis, characterization, and gas-sensing performance of macroporous Zn-doped NiO thin films for ammonia gas detection. J. Mater. Sci. Mater. Electron. 33(23), 18187–18198 (2022)
Ravinder, G., Sreelatha, C.J., Ganesh, V., Shkir, M., Anis, M., Rao, P.C.: Thickness-dependent structural, spectral, linear, nonlinear and z-scan optical studies of V2O5 thin films prepared by a low-cost sol-gel spin coating technique. Mater. Res. Express 6(9), 096403 (2019)
Ravindra, N.M., Auluck, S., Srivastava, V.K.: On the Penn gap in semiconductors. Phys. Status Solidi (b) 93(2), K155–K160 (1979)
Reddy, R.R., et al.: Interrelationship between structural, optical, electronic and elastic properties of materials. J. Alloy. Compd. 473(1–2), 28–35 (2009)
Roose, B., et al.: Mesoporous SnO2 electron selective contact enables UV-stable perovskite solar cells. Nano Energy 30, 517–522 (2016)
Roose, B., et al.: A Ga-doped SnO2 mesoporous contact for UV stable highly efficient perovskite solar cells. J. Mater. Chem. A 6(4), 1850–1857 (2018)
Sallam, O.I., Abdel Maksoud, M.I.A., Kassem, S.M., Awed, A.S., Elalaily, N.A.: Enhanced linear and nonlinear optical properties of erbium/ytterbium lead phosphate glass by gamma irradiation for optoelectronics applications. Appl. Phys. A 128(9), 819–832 (2022)
Sánchez-González, J., Díaz-Parralejo, A., Ortiz, A., Guiberteau, F.: Determination of optical properties in nanostructured thin films using the Swanepoel method. Appl. Surf. Sci. 252(17), 6013–6017 (2006)
Schneider, K.: Optical properties and electronic structure of V2O5, V2O3 and VO2. J. Mater. Sci.: Mater. Electron. 31(13), 10478–10488 (2020)
Sharma, A., Khan, P., Pathak, M., Rout, C.S., Adarsh, K.V.: Nonlinear optical Limiting with hybrid nanostructures of NiCo2O4 and multiwall carbon nanotubes. arXiv preprint arXiv:2204.04751, (2022)
Shin, D., Tibuleac, S., Maldonado, T.A., Magnusson, R.: Thin-film optical filters with diffractive elements and waveguides. Opt. Eng. 37(9), 2634–2646 (1998)
Singh, J.: Electronic and optoelectronic properties of semiconductor structures. Mater. Today (2003)
Studenyak, I., Kranjčec, M., Kurik, M.: Urbach rule in solid state physics. Int. J. Opt. Appl. 4(3), 96–104 (2014)
Šurca, A., Orel, B., Dražič, G., Pihlar, B.: Ex situ and in situ infrared spectroelectrochemical investigations of V2O5 crystalline films. J. Electrochem. Soc. 146(1), 575–580 (1999)
Takeda, S., et al.: Structure and dynamical properties of molten V2O5. J. Non-Cryst. Solids 205, 151–154 (1996)
Tashtoush, N.M., Kasasbeh, O.: Optical properties of vanadium pentoxide thin films prepared by thermal evaporation method (2013)
Tooghi, A., Fathi, D., Eskandari, M.: Numerical study of a highly efficient light trapping nanostructure of perovskite solar cell on a textured silicon substrate. Sci. Rep. 10(1), 18699–18701 (2020)
Urbach, F.: The long-wavelength edge of photographic sensitivity and of the electronic absorption of solids. Phys. Rev. 92(5), 1324 (1953)
Wang, W., Luo, Y., Zhang, D., Luo, F.: Dynamic optical limiting experiments on vanadium dioxide and vanadium pentoxide thin films irradiated by a laser beam. Appl. Opt. 45(14), 3378–3381 (2006)
Wang, Y., Cao, G.: Li+-intercalation electrochemical/electrochromic properties of vanadium pentoxide films by sol electrophoretic deposition. Electrochim. Acta 51(23), 4865–4872 (2006)
Wemple, S.H., DiDomenico, M., Jr.: Behavior of the electronic dielectric constant in covalent and ionic materials. Phys. Rev. B 3(4), 1338 (1971)
Wright, A.C.: The structure of vitreous and liquid V2O5. Philos. Mag. B 50(3), L23–L28 (1984)
Yakuphanoglu, F., Cukurovali, A., Yilmaz, I.: Single-oscillator model and determination of optical constants of some optical thin film materials. Phys. B: Condens. Matter 353(3–4), 210–216 (2004)
Zhang, S., Zhu, N., Zuo, D., Lu, W.: Structural and optical properties of vanadium pentoxide nano-thin films with different thickness. Integr. Ferroelectr. 182(1), 139–147 (2017)
Zhang, W., Kuzyk, M.G.: Optical limiting using Laguerre-Gaussian beams. Appl. Phys. Lett. 91(20), 201110 (2007)
Zoubi, M.A., Farag, H.K., Endres, F.: Sol–gel synthesis of vanadium pentoxide nanoparticles in air-and water-stable ionic liquids. J. Mater. Sci. 44, 1363–1373 (2009)
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The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for funding this work through large group Research Project under grant number RGP1/395/44.
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Abdelrazek, M.M., Hannora, A.E., Kamel, R.M. et al. The influence of rare earth (La, Er and Yb) doped V2O5 films on the structural, linear and nonlinear optical properties and optical limiting for optoelectronic applications. Opt Quant Electron 56, 404 (2024). https://doi.org/10.1007/s11082-023-06075-y
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DOI: https://doi.org/10.1007/s11082-023-06075-y