Abstract
The aging and photobleaching effects on the acid Fuchsin dye with different concentrations in the absence and the presence of poly(vinyl alcohol) were investigated. For studying the aging effect of the samples, the optical absorption properties were characterized by UV–Vis spectroscopy. Also, the photoluminescence spectrum of the samples was measured for considering the photobleaching effect. The absorbance of dye in the proximity of PVA is enhanced. Existence of PVA introducing a quenching effect in the photoluminescence intensity of dye with an increase in dye concentration. Results show that the aging value of AF dye in the presence of PVA is enhanced with an accompanying quenching of the photobleaching value.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11082-022-03778-6/MediaObjects/11082_2022_3778_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11082-022-03778-6/MediaObjects/11082_2022_3778_Fig2_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11082-022-03778-6/MediaObjects/11082_2022_3778_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11082-022-03778-6/MediaObjects/11082_2022_3778_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11082-022-03778-6/MediaObjects/11082_2022_3778_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11082-022-03778-6/MediaObjects/11082_2022_3778_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11082-022-03778-6/MediaObjects/11082_2022_3778_Fig7_HTML.png)
Similar content being viewed by others
References
Abboud, J.L., Notari, R.: Critical compilation of scales of solvent parameters Part I Pure, Non-Hydrogen Bond Donor Solvents. Pure Appl. Chem. 71, 645–718 (1999)
Ahmed, R.M., Saif, M.: Optical properties of rhodamine B dye doped in transparent polymers for sensor application. Chin. J. Phys. 51(3), 511–521 (2013)
bin Hussein, M.Z., Yahaya, A.H., Shamsul, M., Salleh, H.M., Yap, T., Kiu, J.: Acid fuchsin-interleaved Mg–Al-layered double hydroxide for the formation of an organic–inorganic hybrid nanocomposite. Mater. Lett. 58(3–4), 329–332 (2004)
Bosch, P., Catalina, F., Corrales, T., Peinado, C.: Fluorescent probes for sensing processes in polymers. Chem. A Eur. J. 11, 4314–4325 (2005)
Demchenko, A.P.: The red-edge effects: 30 years of exploration. Luminescence 17, 19–42 (2002)
Duxbury, D.F.: The photochemistry and photophysics of triphenylmethane dyes in solid and liquid media. Chem. Rev. 93(1), 381–433 (1993)
El-Zaidia, E.F.M., Al-Kotb, M.S., Yahia, I.S.: Physico-chemical properties of acid fuchsin as novel organic semiconductors: Structure, optical and electrical properties. Phys. B 571, 71–75 (2019)
Frobel, P.L., Suresh, S., Mayadevi, S., Sreeja, S., Mukherjee, C., Muneera, C.: Intense low threshold nonlinear absorption and nonlinear refraction in a new organic–polymer nanocomposite. Mater. Chem. Phys. 129(3), 981–989 (2011)
Geetha, K., Rajesh, M., Nampoori, V.P.N., Vallabhan, C.P.G., Radhakrishnan, P.: Loss characterization in rhodamine 6G doped polymer film waveguide by side illumination fluorescence. J. Opt. A Pure Appl. Opt. 6, 379–383 (2004)
Ishchencko, A.A.: Laser media based on polymethine dyes. Quantom Electron. 24, 471 (1994)
Ishchencko, A.A.: Physicochemical aspects of the creation of modern light-sensitive materials based on polymethine dyes. Theor. Exp. Chem. 34, 191–210 (1998)
Ishchenko, A.: Molecular engineering of dye-doped polymers for optoelectronics. Polym. Adv. Technol. 13(10–12), 744–752 (2002)
Ishikawa, M., Ye, J.Y., Maruyama, Y., Nakatsuka, H.: Triphenylmethane dyes revealing heterogeneity of their nanoenvironment: femtosecond, picosecond, and single-molecule studies. J. Phys. Chem. A 103(22), 4319–4331 (1999)
Islam, M.Z., Noori, A., Paul, S.C.: Photobleaching and its kinetics of fluorescein dyes in PVA polymer matrices: a review. Austin J Anal Pharm Chem 4(3), 1092–1097 (2017)
Jilani, W., Bouzidi, A., Yahia, I.S., Guermazi, H., Zahran, H.Y., Saker, G.: Effect of organic dyes on structural properties, linear optics and impedance spectroscopy of methyl orange (C.I. acid orange 52) doped polyvinyl alcohol composite thin films. J. Mater. Sci. Mater. Electron. 29(19), 16446–16453 (2018)
Kurian, A., George, N.A., Paul, B., Nampoori, V., Vallabhan, C.: Studies on fluorescence efficiency and photodegradation of rhodamine 6G doped PMMA using a dual beam thermal lens technique. Laser Chem. 20(2–4), 99–110 (2002)
Lakowicz, J.R.: Principles of Fluorescence Spectroscopy. Springer (2009)
Lillie, R.D., Gutierrez, A., Palmer, R.W.: Differential collagen stain by an acid fuchsin, iron, flavianic acid mixture. A note on ferrous sulfate hematoxylin. Anatom. Rec. 159(4), 365–370 (1967)
Mitschke, U., Bauerle, P.: The electroluminescence of organic materials. J. Mater. Chem. 10, 1471–1507 (2000)
Mohammed, M., Yahia, I.: Synthesis and optical properties of basic fuchsin dye-doped PMMA polymeric films for laser applications: wide scale absorption band. Opt. Quant. Electron. 50(3), 1–12 (2018)
Nierengarten, J., Hadziioannou, G.: Molecular photovoltaic devices. Mater. Today 4, 16–18 (2001)
Sreekumar, G., Frobel, P.L., Muneera, C., Sathiyamoorthy, K., Vijayan, C., Mukherjee, C.: Saturable and reverse saturable absorption and nonlinear refraction in nanoclustered Amido Black dye–polymer films under low power continuous wave He–Ne laser light excitation. J. Opt. A Pure Appl. Opt. 11(12), 125204 (2009)
Talhavini, M., Corradini, W., Atvars, T.D.Z.: The role of the triplet state on the photobleaching processes of xanthene dyes in a poly(vinyl alcohol) matrix. J. Photochem. Photobiol. A Chem. 139, 187–197 (2001)
Ushamani, M., Sreekumar, K., Kartha, C.S., Joseph, R.: Fabrication and characterization of methylene-blue-doped polyvinyl alcohol-polyacrylic acid blend for holographic recording. Appl. Opt. 43(18), 3697–3703 (2004)
Vinitha, G., Ramalingam, A.: Single-beam Z-scan measurement of the third-order optical nonlinearities of triarylmethane dyes. Laser Phys. 18(10), 1176–1182 (2008)
Viswanath, V., Nair, S.S., Subodh, G., Muneera, C.: Zinc oxide encapsulated poly(vinyl alcohol) nanocomposite films as an efficient third-order nonlinear optical material: Structure, microstructure, emission and intense low threshold optical limiting properties. Mater. Res. Bull. 112, 281–291 (2019)
Ye, J.Y., Ishikawa, M., Yogi, O., Okada, T., Maruyama, Y.: Bimodal site distribution of a polymer film revealed by flexible single-molecule probes. Chem. Phys. Lett. 288(5–6), 885–890 (1998)
Zeyada, H.M., El-Nahass, M.M., Makhlouf, M.M.: Electronic transport mechanisms in tetraphenyleprophyrin thin films. Curr. Appl. Phys. 11(6), 1326–1331 (2011)
Zhao, W., Yang, Z., Jiao, B., Wu, Z.: Organic alternating current electroluminescence device based on 4, 40-bis(N-phenyl-1-naphthylamino) biphenyl/1,4,5,8,9,11-hexaazatriphenylene charge generation unit. Org. Electron. 17, 44–50 (2015)
Zheng, J., Huang, F., Li, Y., Xu, T., Xu, H., Jia, J., Ye, Q., Gao, J.: The aggregation-induced emission enhancement properties of BF2 complex isatin-phenylhydrazone: synthesis and fluorescence characteristics. Dyes Pigm. 113, 502–509 (2015)
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Barzan, M., Hosseini, N.S. & Koohian, A. Assessment of aging and photobleaching effects on the acid Fuchsin dye-doped poly(vinyl alcohol). Opt Quant Electron 54, 481 (2022). https://doi.org/10.1007/s11082-022-03778-6
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11082-022-03778-6