Abstract
Sn and La co-doped TiO2 thin films were fabricated on surface of glass slide substrates. Co-doped titania thin films were prepared by a sol gel method using, TBT as a precursor. Morphology and crystallite size of the obtained co-doped thin films changed by changing the content of La. Accordingly, the doped titania thin films showed various water contact angles and optical band gaps. As, the optical band gap of the nanostructured doped titania thin films decreased with increasing in content of La from 3.4 to 2.32 eV. Moreover, the water contact angles changed from 69.0° to 13.5° by changing the content of La.
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Anera, R.M., Henriquea, A.J.L.M., Jose, R.G., Caue, R.: Deposition of TiO2 and Ag: tiO2 thin films by the polymeric precursor method and their application in the photodegradation of textile dyes. Appl. Catal. B 90, 205–212 (2009)
Choi, J., Park, H., Hoffman, M.R.: Effects of single metal-ion doping on the visible-light photoreactivity of TiO2. J. Phys. Chem. C 114, 783–792 (2010)
Colon, G., Hidalgom, C., Munuera, G., Ferino, I., Cutrufellom, G., Navioj, A.: Structural and surface approach to the enhanced photocatalytic activity of sulfated TiO2 photocatalyst. Appl. Catal. B 63, 45–59 (2006)
Cruzromera, D., Torres, G., Arevalo, J.C., Gomez, R., Aguilar, A.: Synthesis and characterization of TiO2 doping with rare earths by sol–gel method: photocatalytic activity for phenol degradation. J. Sol–Gel. Sci. Technol. 56, 219–226 (2010)
Das, C., Roy, P., Yang, M., Jha, H., Schmuki, P.: Nb doped TiO2 nanotubes for enhanced photoelectrochemical water-splitting. Nanoscale 3, 3094–3096 (2011)
Hoang, S., Guo, S., Hahn, N.T., Bard, A.J., Mullins, C.B.: Visible light driven photoelectrochemical water oxidation on nitrogen-modified TiO2 nanowires. Nano Lett. 12, 26–32 (2012)
Ilkhechi, N.N., Koozegar-Kaleji, B.: Effect of Cu2 +, Si4 + and Zr4 + dopant on structural, optical and photocatalytic properties of titania nanopowders. Opt. Quant. Electron. 48, 347–355 (2016)
Ilkhechi, N.N., Koozegar-Kaleji, B., Salahi, E., Hosseinabadi, N.: Comparison of optical and structural properties of Cu doped and Cu/Zr co-doped TiO2 nanopowders calcined at various temperatures. J. Sol–Gel. Sci. Technol. (2015a). doi:10.1007/s10971-015-3661-0
Ilkhechi, N.N., Dousi, F., Koozegar-Kaleji, B., Salahi, E.: Optical and structural properties of TiO2 nanocomposite doped by Si and Cu at high temperature. Opt. Quant. Electron. 47, 1751–1763 (2015b)
Ilkhechi, N.N., Azar, Z., Khajeh, M., Mozammel, M.: Enhanced Structural, Optical and Super-hydrophilic properties of TiO2 thin film co-doped by V and Sn. J. Mater. Sci.: Mater. Electron. (2016). doi:10.1007/s10854-016-5147-4
Jinga, J., Liuc, M., Colvin, V.L., Lia, W., William, W.: Photocatalytic degradation of nitrogen-containing organic compounds over TiO2. J. Mol. Catal. A: Chem. 351, 17–28 (2011)
Koozegar Kaleji, B., Sarraf-Mamoory, R., Nakata, K., Fujishima, A.: The effect of Sn dopant on crystal structure and photocatalytic behavior of nanostructured titania thin films. J. Sol–Gel. Sci. Technol. 60, 99–107 (2011)
Liqianga, J., Xiaojun, S., Baifu, X., Baiqi, W., Weimin, C., Honggang, F.: The preparation and characterization of La doped TiO2 nanoparticles and their photocatalytic activity. J. Solid State Chem. 10, 3375–3382 (2004)
Ochiai, T., Fujishima, A.: Photoelectrochemical properties of TiO2 photocatalyst and its applications for environmental purification. J. Photochem. Photobiol., C 13, 247–262 (2012)
Qiu, Y., Yan, K., Deng, H., Yang, S.: Secondary branching and nitrogen doping of ZnO nanotetrapods: building a highly active network for photoelectrochemical water splitting. Nano Lett. 12(1), 407–413 (2012)
Ratanatawanate, C., Xiong, C.R., Balkus, K.J.: Fabrication of PbS quantum dot doped TiO2 nanotubes. ACS Nano 2, 1682–1688 (2008)
Sun, B., Tielin, S., Peng, Z., Sheng, W., Jiang, T., Liao, G.: Controlled fabrication of Sn/TiO2 nanorods for photoelectrochemical water splitting. Nanoscale Res. Lett. 8, 462–469 (2013)
Wang, G., Linga, Y., Li, Y.: Oxygen-deficient metal oxide nanostructures for photoelectrochemical water oxidation and other applications. Nanoscale 4, 6682–6691 (2012)
Wangy, J., Luk, C., Feng, C.G.: Photocatalytic degradation of methyl orange by polyoxometalates supported on yttrium-doped TiO2. J. Rare Earths 29, 866–871 (2011)
Xu, M., Da, P., Wu, H., Zhao, D., Zheng, G.: Controlled Sn-doping in TiO2 nanowire photoanodes with enhanced photoelectrochemical conversion. Nano Lett. 12(3), 1503–1508 (2012)
Yamini, S.M., Wang, H., Gibbs, Z., Pei, Y., Doua, S.X.: Snyder GJ: Chemical composition tuning in quaternary p-type Pb-chalcogenides—a promising strategy for enhanced thermoelectric performance. Phys. Chem. Chem. Phys. 16, 1835–1840 (2014)
Yang, X.J., Wang, S., Sun, H.M., Wang, X.B., Lian, J.S.: Preparation and photocatalytic performance of Cu-doped TiO2 nanoparticles. Trans. Nonferrous Metals Soc. c 25(2), 504–509 (2015)
Yin, S., Ihara, K., Aita, Y., Komatsu, M., Sato, T.: Visible-light induced photocatalytic activity of TiO2−x A y (A = N, S) prepared by precipitation route. J. Photochem. Photobiol., A 179, 105–114 (2006)
Zhang, X., Wang, F., Huang, H., Li, H., Han, X., Liu, Y., Kang, Z.: Carbon quantum dot sensitized TiO2 nanotube arrays for photoelectrochemical hydrogen generation under visible light. Nanoscale 5, 2274–2278 (2013)
Zhao, Y., Liu, J., Shi, L., Yuan, S., Fang, J., Wang, Z., et al.: Solvothermal preparation of Sn4+ doped anatase TiO2 nanocrystals from peroxo-metal-complex and their photocatalytic activity. Appl. Catal. B 103(3), 436–443 (2011)
Zhou, M.H., Yu, J.G., Cheng, B.: Effects of Fe-doping on the photocatalytic activity of mesoporous TiO2 powders prepared by an ultrasonic method. J. Hazard. Mater. B 137, 1838–1847 (2006)
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Ilkhechi, N.N., Ghobadi, N., Kaleji, B.K. et al. Effect of Sn and La doping on optical and hydrophilic properties of TiO2 thin film. Opt Quant Electron 48, 416 (2016). https://doi.org/10.1007/s11082-016-0677-9
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DOI: https://doi.org/10.1007/s11082-016-0677-9