Abstract
The Yb3+/Tm3+/Ho3+ tri-doped silica-based glasses are firstly prepared by the CO2 laser sintering method. The up-conversion (UC) luminescence and near-infrared emission properties are investigated under 980 nm excitation. Broad emission band with the full width at half maximum of 400 nm within the infrared spectral region around 2 μm is obtained. In addition, the energy transfer mechanism among Yb3+, Tm3+, and Ho3+ are discussed in detail. The experimental results show that the Yb/Tm/Ho tri-doped silica-based glasses prepared by the CO2 laser sintering method can be the potential materials for white light source and infrared laser operating at 2 μm.
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Barrera, E.W., Pujol, M.C., Carvajal, J.J., Mateos, X., Solé, R., Massons, J., Díaz, F.: White light upconversion in Yb-sensitized (Tm, Ho)-doped KLu (WO4)2 nanocrystals: the effect of Eu incorporation. Phys. Chem. Chem. Phys. 16, 1679–1686 (2014)
Creeden, D., Johnson, B.R., Setzler, S.D., Chicklis, E.P.: Resonantly pumped Tm-doped fiber laser with >90% slope efficiency. Opt. Lett. 39, 470–473 (2014)
Dhar, A., Pal, A., Das, S., Sen, R.: Tm–Yb doped optical fiber performance with variation of host-glass composition. Adv. Electr. Electron. Eng. 12, 582–589 (2014)
Du, X., Ji, L., Jiang1, Y.: Rapid CO2 laser sintering of Ba0.5 Sr1.5Na0.6K0.4Nb5O15 piezoelectric ceramic, ISAF 2009. In: Proceedings of the 18th IEEE International Symposium on the IEEE, pp. 1–3. (2009)
Gaft, M., Reisfeld, R., Panczer, G.: Modern luminescence spectroscopy of minerals and materials, pp. 22–88. Springer, New York (2005)
Halder, A., Paul, M.C., Damanhuri, S.S.A., Huri, N.A.D., Hamzah, A., Harun, S.W., Bhadra, S.K.: Upconversion luminescence in Tm3+/Yb3+ co-doped double-clad silica fibers under 980 nm cladding pumping. J. Mod. Opt. 59, 527–532 (2012)
He, X., Xu, S.H., Li, C., Yang, C.S., Yang, Q., Mo, S.P., Chen, D.D., Yang, Z.M.: 1.95 μm kHz-linewidth single-frequency fiber laser using self-developed heavily Tm3+-doped germanate glass fiber. Opt. Express 21, 20800–20805 (2013)
Huang, H., Zhong, H.: Synthesis and white light emission upconversion of Tm3+, Ho3+, Yb3+ co-doped YPO4 micro-nano tubes. Spectrosc. Spectr. Anal. 32, 2642–2646 (2012)
Huang, P., Liu, F., Chen, D., Wang, Y., Yu, Y.: Highly efficient near infrared to visible upconversion luminescence in transparent glass ceramics containing Yb3+/Er3+: NaYF4 nanocrystals. Phys. Status Solidi A 205, 1680–1684 (2008)
Johnson, L.F., Guggenheim, H.J.: Infrared-pumped visible laser(IR pumped stimulated light emission in semiconductors, noting upconversion due to energy transfer between impurity ions). Appl. Phys. Lett. 19, 44–47 (1971)
Kasprowicz, D., Brik, M.G., Majchrowski, A., Michalski, E., Głuchowski, P.: Up-conversion emission in triply-doped Ho3+/Yb3+/Tm 3+ KGd (WO4)2 single crystals. Opt. Commun. 284, 2895–2899 (2011)
Lan, A., Li, B., Shen, H., Zhang, J.: SrWO4: Ho3+, Yb3+, Tm3+ microspheres with white-light emission: synthesis and luminescence. J. Mater. Sci.: Mater. Electron. 26, 1695–1699 (2015)
Ledemi, Y., Manzani, D., Ribeiro, S.J., Messaddeq, Y.: Multicolor up conversion emission and color tunability in Yb3+/Tm3+/Ho3+ triply doped heavy metal oxide glasses. Opt. Mater. 33, 1916–1920 (2011)
Ledemi, Y., Trudel, A.A., Rivera, V.A., Chenu, S., Véron, E., Nunes, L.A., Messaddeq, Y.: White light and multicolor emission tuning in triply doped Yb3+/Tm3+/Er3+ novel fluoro-phosphate transparent glass-ceramics. J. Mater. Chem. C 2, 5046–5056 (2014)
Lin, H., Xu, D., Teng, D., Yang, S., Zhang, Y.: Tunable multicolor and white light upconversion luminescence in Yb3+/Tm3+/Ho3+ tri-doped NaYF4 micro crystals. J. Lumin. 30, 723–728 (2014)
Liu, C., Ye, C.C., Luo, Z.Q., Cheng, H.H., Wu, D.D., Zheng, Y.L., Liu, Z., Qu, B.: High-energy passively Q-switched 2 μm Tm3+-doped double-clad fiber laser using graphene-oxide-deposited fiber taper. Opt. Express 21, 204–209 (2013)
Liu, B.Q., Wang, J., Zhu, L.L., Zhang, H., Chen, H.H., Xu, F.F., Zhao, J.T.: Remarkable enhancement of the near-infrared upconversion emission in the β-NaYF4: Yb3+/Tm3+ system with controllable morphology. Mater. Res. Bull. 51, 180–184 (2014)
Mahalingam, V., Naccache, R., Vetrone, F., Capobianco, J.A.: Enhancing upconverted white light in Tm3+/Yb3+/Ho3+-doped GdVO4 nanocrystals via incorporation of Li+ ions. Opt. Express 20, 111–119 (2012)
Modsching, N., Kadwani, P., AndrewSims, R., Leick, L., Broeng, J., Shah, L., Richardson, M.: Lasing in thulium-doped polarizing photonic crystal fiber. Opt. Lett. 36, 3873–3875 (2011)
Peng, B., Izumitani, T.: Optical properties, fluorescence mechanisms and energy transfer in Tm3+, Ho3+ and Tm3+–Ho3+ doped near-infrared laser glasses, sensitized by Yb3+. Opt. Mater. 4, 797–810 (1995)
Simpson, D.A., Gibbs, W.E., Collins, S.F., Blanc, W., Dussardier, B., Monnom, G., Baxter, G.W.: Visible and near infra-red up-conversion in Tm3+/Yb3+ co-doped silica fibers under 980 nm excitation. Opt. Express 16, 13781–13799 (2008)
Su, H.J., Zhang, J., Liu, L., Eckert, J., Fu, H.Z.: Rapid growth and formation mechanism of ultrafine structural oxide eutectic ceramics by laser direct forming. Appl. Phys. Lett. 99, 221913 (2011)
Sun, L.X., Gong, H., Chen, B.J., Lin, H., Pun, E.Y.B.: Multicolor upconversion and color tunability in Tm3+/Ho3+/Yb3+ doped opaque aluminum tellurite ceramics. J. Appl. Phys. 105, 106–109 (2009)
Tang, Y.L., Xu, L., Yang, Y., Xu, J.Q.: High-power gain-switched Tm3+-doped fiber laser. Opt. Express 18, 22964–22972 (2010)
Tang, J.F., Li, G.N., Yang, C., Gou, J., Luo, D.H., He, H.: Power driven tunable white upconversion luminescence from Lu2TeO6 tri-doped with Yb3+, Tm3+ and Ho3+. Cryst EngComm 17, 9048–9054 (2015)
Teng, Y., Zhou, J.J., Liu, X.F., Ye, S., Qiu, J.R.: Efficient broadband near-infrared quantum cutting for solar cells. Opt. Express 18, 9671–9676 (2010)
Tian, Y., Xu, R., Hu, L., Zhang, J.: Intense 2.0 μm emission properties and energy transfer of Ho3+/Tm3+/Yb3+ doped fluorophosphate glasses. J. Appl. Phys. 110, 033502–0335026 (2011)
Tsang, Y., Richards, B., Binks, D., Lousteau, J., Jha, A.: A Yb3+/Tm3+/Ho3+ triply-doped tellurite fibre laser. Opt. Express 16, 10690–10695 (2008)
Wang, N.Q., Zhao, X., Li, C.M., Pun, E.Y.B., Lin, H.: Upconversion and color tunability in Tm3+/Ho3+/Yb3+ doped low phonon energy bismuth tellurite glasses. J. Lumin. 130, 1044–1047 (2010)
Wang, L., Qin, W., Liu, Z., Zhao, D., Qin, G., Di, W., He, C.: Improved 800 nm emission of Tm3+ sensitized by Yb3+ and Ho3+ in β-NaYF4 nanocrystals under 980 nm excitation. Opt. Express 20, 7602–7607 (2012)
Wu, J.L., Zhang, W., Zhou, G.Y., Xia, C.M., Liu, J.T., Zheng, Y., Hou, Z.Y.: Design and fabrication of ytterbium-doped photonic crystal fiber with low non-linearity. Laser Phys. 25, 055105–0551057 (2015)
Xia, C., Zhou, G., Han, Y., Zhao, X., Hou, L.: Luminescence of Yb 2+, Yb3+ co-doped silica glass for white light source. Opt. Mater. 34, 769–771 (2012)
Xia, C., Zhou, G., Han, Y., Zhao, X., Hou, L.: Investigation on preparation and spectroscopic properties of Yb2+-doped silica-based glass prepared by the oxyhydrogen flame fusing process. Opt. Mater. 35, 2561–2564 (2013)
Xia, C.M., Zhou, G.Y., Liu, J.T., Wang, C., Han, Y., Yuan, J.H.: Optical properties of Yb3+/Ho3+co-doped air cladding silica-based fiber fabricated with plasma non-chemical vapor deposition method. Appl. Phys. A 118, 525–530 (2015a)
Xia, C.M., Zhou, G.Y., Liu, J.T., Zhang, W., Han, Y., Yuan, J.H.: Blue and near-infrared up-conversion in double-air-cladding Tm3+-doped silica fiber under 1064 nm excitation. Opt. Quantum Electron. 47, 3435–3444 (2015b)
Xu, Y., Wang, Y., Shi, L., Xing, L., Tan, X.: Bright white upconversion luminescence in Ho3+/Yb3+/Tm3+ triple doped CaWO4 polycrystals. Opt. Laser Technol. 54, 50–52 (2013)
Yan, R.X., Li, Y.D.: Down/up conversion in Ln3+-doped YF3 nanocrystals. Adv. Funct. Mater. 15, 763–770 (2005)
Yang, L.W., Han, H.L., Zhang, Y.Y., Zhong, J.X.: White emission by frequency up-conversion in Yb3+–Ho3+–Tm3+ triply doped hexagonal NaYF4 nanorods. J. Phys. Chem. C 113, 18995–18999 (2009)
Zhan, H., Zhou, Z., He, J., Lin, A.: Intense red upconversion emission of Yb/Tm/Ho triply-doped tellurite glasses. Appl. Opt. 51, 3091–3095 (2012)
Zhang, Y., Yao, B.Q., Ju, Y.L., Wang, Y.Z.: Gain-switched Tm3+-doped double-clad silica fiber laser. Opt. Express 13, 1085–1089 (2005)
Zhang, W., Wu, J.L., Zhou, G.Y., Xia, C.M., Liu, J.T., Tian, H.C., Liang, W.T., Hou, Z.Y.: Yb-doped silica glass and photonic crystal fiber based on laser sintering technology. Laser Phys. 26, 035801–0358016 (2016)
Zhao, J., Qin, N., Bao, D.: Blue and near-infrared up-conversion photoluminescence and dielectric relaxation of Tm3+/Yb3+ co-doped (Bi, Y)2 Ti2O7 pyrochlore thin films. J. Lumin. 148, 121–128 (2014)
Zou, X., Izumitani, T.: Fluorescence mechanisms and dynamics of Tm3+ singly doped and Yb3+, Tm3+ doubly doped glasses. J. Non-Cryst. Solids 162, 58–67 (1993)
Acknowledgments
This work was supported by National Natural Science Foundation of China under Grant 61377100, 61405173 and 61575066, Major Instrument Project of National Natural Science Foundation of China Grant 61527822, Specialized Research Fund for the Doctoral Program of Higher Education under Grant 20134407120014.
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Xia, C., Liu, J., Zhang, W. et al. Yb3+/Tm3+/Ho3+ tri-doped silica-based glass: intense up-conversion and broad near-infrared emission. Opt Quant Electron 48, 257 (2016). https://doi.org/10.1007/s11082-016-0527-9
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DOI: https://doi.org/10.1007/s11082-016-0527-9