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Specific features of photoinduced absorption and second harmonic generation of ferroic organic nanocomposites \([\hbox {C}_{3}\hbox {H}_{7}\hbox {NH}_{3}]_{2}\hbox {MnCl}_{4}\)

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Abstract

We have done the studies of the photoinduced absorption and of the related second harmonic generation (SHG) for the \([\hbox {C}_{3}\hbox {H}_{7}\hbox {NH}_{3}]_{2}\hbox {MeCl}_{4}\) (where Me=Cu, Mn). We have found substantial changes of the absorption under influence of the continuous wave lasers. The changes of the photoinduced optical SHG were stimulated by the two bicolour laser coherent beams. The results presented show that for the nanosecond 1,064 nm Nd:YAG laser beam principal changes were observed for the Cu-containing samples. The diethyl ammonium samples doped by Mn and Cu have shown substantially higher photo induced SHG up to the other samples. Simultaneously we have studied the pump-probe and size dependences. However for all the cases principal role was played by the octahedral \(\hbox {MeCl}_{6}\). Relation with the trapping levels actively interaction with phonon modes is principal here.

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Acknowledgments

This work was performed within a framework of National Grant and the authors wish to thank the Ministry of Science and Higher Education (Grants No. IP2011 039671) for financial support.

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Authors and Affiliations

  1. Faculty of Electrical Engineering, Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 , Czestochowa, Poland

    K. Ozga & A. Wojciechowski

  2. Institute of Physics, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 , Czestochowa, Poland

    M. Nabialek & M. Dospial

  3. Institute of Materials Science and Engineering, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 , Czestochowa, Poland

    M. Szota

  4. Physical Department, I. Franko State University, Dragomanowa 50, Lviv, Ukraine

    V. Kapustianyk & V. Rudyk

  5. Department of Chemistry, Army Academy Named After Hetman Petro Sahaydachnyi, 32 Gvardiyska St., Lviv, 79012, Ukraine

    A. O. Fedorchuk

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  1. K. Ozga
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  2. A. Wojciechowski
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  3. M. Nabialek
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  4. M. Szota
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  5. M. Dospial
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  6. V. Kapustianyk
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  7. V. Rudyk
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  8. A. O. Fedorchuk
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Correspondence to A. Wojciechowski.

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Ozga, K., Wojciechowski, A., Nabialek, M. et al. Specific features of photoinduced absorption and second harmonic generation of ferroic organic nanocomposites \([\hbox {C}_{3}\hbox {H}_{7}\hbox {NH}_{3}]_{2}\hbox {MnCl}_{4}\) . Opt Quant Electron 47, 743–753 (2015). https://doi.org/10.1007/s11082-014-9949-4

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