Skip to main content
Log in

Pulse-electrodeposited Ni/W-Al2O3 nanocomposites at different current densities

  • Research paper
  • Published:
Journal of Nanoparticle Research Aims and scope Submit manuscript

Abstract

This study focuses on depositing Ni/W-Al2O3 nanocomposites onto a low-carbon substrate using the pulse electrodeposition technique. The effects of pulse current density on microstructural characteristics, microhardness, phase structure, and wear/corrosion properties of Ni/W-Al2O3 nanocomposites were investigated. Among the investigated nanocomposites, Ni/W-Al2O3 deposited at 0.6 A/dm2 current density showed the finest structure with average Ni-W grain and Al2O3 nanoparticle sizes of 66.7 nm and 39.1 nm, respectively. The Ni/W-Al2O3 nanocomposite deposited under the same conditions exhibited a maximum microhardness of ~ 825.7 HV, while also demonstrating the lowest corrosion current density of ~ 0.72 A/cm2. After 60 min of wear testing, wear loss of Ni/W-Al2O3 nanocomposite deposited at 0.6 A/dm2 was recorded as 42.8 mg, indicating its excellent wear resistance. In contrast, Ni/W-Al2O3 nanocomposite deposited at 0.8 A/dm2 displayed the highest wear loss value of 101.5 mg.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig.11

Similar content being viewed by others

Data availability

The data that support the findings of this study are available from the corresponding author upon reasonable request.

References

  1. You JH, Zhao Y, Wang L, Bao WT, He Y (2020) Atomic layer deposition of γ-Fe2O3 nanoparticles on modifed MWCNT for effcient adsorption of Cr(VI) ions from aqueous solution. J Phys Chem Solids 142:109441

    Article  CAS  Google Scholar 

  2. Padalkar S, Hulleman J, Kim SM, Tumkur T, Rochet JC, Stach E, Stanclu L (2009) Fabrication of ZnS nanoparticle chains on a protein template. J Nanopart Res 11:2031–2041

    Article  CAS  Google Scholar 

  3. You JH, Li JJ, Wang ZW, Baghayeri M, Zhang HZ (2023) Application of Co3O4 nanocrystal/rGO for simultaneous electrochemical detection of cadmium and lead in environmental waters. Chemosphere 335:139133

    Article  CAS  Google Scholar 

  4. Hsu LY, Chein HM (2007) Evaluation of nanoparticle emission for TiO2 nanopowder coating materials. J Nanopart Res 9:157–163

    Article  CAS  Google Scholar 

  5. Baowan D, Helms V (2015) Quantitative study of BSA coating silica nanoparticle. J Nanopart Res 53:29–40

    CAS  Google Scholar 

  6. Li C, Xia F, Ma C, Li Q (2021) Research on the corrosion behavior of Ni-SiC nanocoating prepared using a jet electrodeposition technique. J Mater Eng Perform 5:1–9

    Google Scholar 

  7. Krasikov A, Bykova A, Merkulova M (2020) Electrochemical deposition of nanocrystalline Ni-W coatings from citrate electrolytes. Voprosy Materialovedeniya 1(101):111–117

    Article  Google Scholar 

  8. Xia F, Li C, Ma C, Li Q, Xing H (2021) Effect of pulse current density on microstructure and wear property of Ni-TiN nanocoatings deposited via pulse electrodeposition. Appl Surf Sci 538:148139

    Article  CAS  Google Scholar 

  9. Zhang H, Wang J, Chen S, Wang H, He Y, Ma C (2021) Ni-SiC composite coatings with improved wear and corrosion resistance synthesized via ultrasonic electrodeposition. Ceram Int 47(7):9437–9446

    Article  CAS  Google Scholar 

  10. Wang M, Xue Z, Yan S, He J, Shao Q, Ge W, Lu B (2022) Pulse electrodeposited super-hydrophobic Ni-Co/WS2 nanocomposite coatings with enhanced corrosion-resistance. Coatings 12(12):1897

    Article  CAS  Google Scholar 

  11. He L, Tan Y, Zhou C, Gao L (2013) Tribological properties of nanostructured Al2O3-40%TiO2 multiphase ceramic particles reinforced Ni-based alloy composite coatings. Trans Nonferrous Metals Soc China 23(9):2618–2627

    Article  CAS  Google Scholar 

  12. Mahesh R, Vora K, Hanumanthaiah M, Shroff A, Kulkarni P, Makuteswaran S, Ramdas S, Ramachandraih HL, Raghu AV (2023) Removal of pollutants from wastewater using alumina based nanomaterials: a review. Korean J Chem Eng 40:2035–2045

    Article  CAS  Google Scholar 

  13. Babu A, Somesh TE, Dechamma CD, Hemavathi AB, Kakarla RR, Kulkarni RV, Raghu AV (2023) Ternary structured magnesium cobalt oxide/graphene/polycarbazole nanohybrids for high performance electrochemical supercapacitors. Mater Sci Energy Techn 6:399–408

    CAS  Google Scholar 

  14. Madhavi J, Prasad V, Reddy KR, Reddy CV, Raghu AV (2021) Facile synthesis of Ni-doped ZnS-CdS composite and their magnetic and photoluminescence properties. J Environ Chem Eng 9(6):106335

    Article  CAS  Google Scholar 

  15. Hou KH, Chen YC (2011) Preparation and wear resistance of pulse electrodeposited Ni-W/Al2O3 composite coatings. Appl Surf Sci 257:6340–6346

    Article  CAS  Google Scholar 

  16. Masoudi M, Hashim M, Kamari HM (2014) Characterization of novel Ni-Al2O3-SiC nanocomposite coatings synthesized by co-electrodeposition. Appl Nanosci 4:649–656

    Article  CAS  Google Scholar 

  17. Xia F, Li Q, Ma C, Liu W, Ma Z (2020) Preparation and wear properties of Ni/TiN-SiC nanocoatings obtained by pulse current electrodeposition. Ceram Int 46(6):7961–7969

    Article  CAS  Google Scholar 

  18. Chiu SY, Chung ST, Lin CY, Tsai WT (2014) Electrodeposition of Ni-Al2O3 composite coatings employing supercritical CO2 baths. Surf Coat Technol 247:68–73

    Article  CAS  Google Scholar 

  19. Zhang H, Xia F, Wang J, Xu F (2021) Influence of duty cycle and pulse frequency on structures and performances of electrodeposited Ni-W/TiN nanocomposites on oil-gas X52 steels. Coatings 11(10):1182

    Article  CAS  Google Scholar 

  20. Guo C, Zhou F, Chen M, Wang J, Zhu S, Wang FI (2021) An in-situ formed ceramic/alloy/ceramic sandwich barrier to resist elements interdiffusion between NiCrAlY coating and a Ni-based superalloy. J Mater Sci Technol 70:1–11

    Article  CAS  Google Scholar 

  21. Wasekar NP, Bathini L, Ramakrishna L, Srinivasa Rao D, Padmanabham G (2020) Pulsed electrodeposition, mechanical properties and wear mechanism in Ni-W/SiC nanocomposite coatings used for automotive applications. Appl Surf Sci 527:146896

    Article  CAS  Google Scholar 

  22. Bhaskara S, Fakrudeen S, Raju VB, Anjanapura R (2021) Comparative studies of inhibitive effects of diamines on corrosion of aluminium alloy in presence of acid media. Rasayan J Chem Spec Issue 1:72–82

    Article  Google Scholar 

  23. Prabhu R, Roopashree B, Jeevananda T, Rao S, Reddy KR, Raghu AV (2021) Synthesis and corrosion resistance properties of novel conjugated polymer-Cu2Cl4L3 composites. Mater Sci Energy Technol 4:92–99

    CAS  Google Scholar 

  24. Liu W, Jiang K, Li Q, Ma C, Xia F (2021) Jet pulse electrodeposited Ni-SiC thin coatings by using experimental system designed for potential industrial application. Int J Electrochem Sci 16(4):21044

    Article  CAS  Google Scholar 

  25. Sun C, Liu X, Zhou C, Wang C, Cao H (2019) Preparation and wear properties of magnetic assisted pulse electrodeposited Ni-SiC nanocoatings. Ceram Int 45(1):1348–1355

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The research is supported by the National Natural Science Foundation of China (Granted no. 51974089).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Fafeng Xia or Chunyang Ma.

Ethics declarations

Conflicts of interest

The authors declare no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xia, F., Yan, P., Ma, C. et al. Pulse-electrodeposited Ni/W-Al2O3 nanocomposites at different current densities. J Nanopart Res 25, 208 (2023). https://doi.org/10.1007/s11051-023-05857-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11051-023-05857-5

Keywords

Navigation