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Synthesis and electrochemical analysis of S/ZIF-67@rGO composite cathodes for lithium-sulfur batteries

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Abstract

In this work, we developed ZIF-67@rGO composite by coating reduced graphene oxide (rGO) on the surface of ZIF-67 via the spray drying method to obtain a highly efficient sulfur host for lithium-sulfur (Li–S) batteries. The resulted ZIF-67@rGO composite possesses a hierarchical architecture, in which ZIF-67 polyhedron closely clustered and coated by rGO. The rGO coating shell could maintain the structural stability and provide high conductivity paths for effective charge transport. The ZIF-67 core possesses abundant adsorptive site to provide chemical interaction with lithium polysulfides (LiPSs). The size range of ZIF-67@rGO particles is about 2–5 μm, and the diameters of ZIF-67 nanoparticles are distributed between 500 and 900 nm. As results, the S/ZIF-67@rGO composite achieved the high initial discharge capacity of 1130.1 mAh g−1 and a capacity of 942.6 mAh g−1 remained after 100 cycles. This facile approach of spray-drying will open an alternative pathway to prepare an efficient and promising electrode material for advanced Li–S batteries.

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Funding

This work was supported by the Natural Science Foundation of Hebei Province of China (B2021202028; B2020202052); State Key Laboratory of Reliability and Intelligence of Electrical Equipment (No. EERI_PI2020007), Hebei University of Technology, China; the Program for the Outstanding Young Talents of Hebei Province, China (YG.Z.); Chunhui Project of Ministry of Education of the People’s Republic of China (No. Z2017010); National Key R&D Program of China (No.2019YFC1908504).

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  1. School of Materials Science and Engineering, State Key Laboratory of Reliability and Intelligence of Electrical Equipment, Hebei University of Technology, Tianjin, 300130, China

    Yanyu Liu, Xin Liu, Weilong Qiu, Yanli Song & Yongguang Zhang

  2. China Center for Information Industry Development, Beijing, 100048, China

    Junfeng Yang

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  1. Yanyu Liu
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  2. Xin Liu
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Liu, Y., Liu, X., Qiu, W. et al. Synthesis and electrochemical analysis of S/ZIF-67@rGO composite cathodes for lithium-sulfur batteries. J Nanopart Res 24, 137 (2022). https://doi.org/10.1007/s11051-022-05519-y

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