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Charge states of size-selected silver nanoparticles produced by magnetron sputtering

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Abstract

Gas-phase aggregation of metal nanoparticles (nanoclusters), in particular, produced by magnetron sputtering, is a widely used method in research and industrial applications. Therefore, better understanding of the nucleation and growth processes as well as of nanoparticle dynamics in aggregation zone is required. One of the poorly understood issues is a charge state of nanocluster formed in magnetron-based sources. In the current work, an original approach to study charge states of silver nanoclusters after mass (size) filtering is suggested. The study reveals that particles can carry both negative and positive charges; anionic nanoparticles dominate over the cationic ones under the conditions used in our experiment. It is also found that a considerable fraction of nanoparticles has charges greater than unity, and this fraction increases with particle size. However, the tendency depends on polarity. For the cations, the doubly, triply and quadruply charged nanoclusters have very similar fractions for a given filtering condition, while for anions, an ability to carry higher than unity charges by individual particles gradually decreases. Thus, the study provides important insights on the formation of cationic and anionic nanoparticles in magnetron cluster sources as well as on the tendencies to carry multiple charges depending on particle size.

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References

  • Ahadi AM, Hinz A, Polonskyi O, Trottenberg T, Strunskus T, Kersten H, Faupel F (2016) Modification of a metal nanoparticle beam by a hollow electrode discharge. J Vac Sci Technol A 34 (2):021301

    Article  Google Scholar 

  • Bins C (2001) Nanoclusters deposited on surfaces. Surf Sci Rep 44:1–49

    Article  Google Scholar 

  • Blom MN, Schooss D, Stairs J, Kappes MM (2006) Experimental structure determination of silver cluster ions (Agn +, 19≤n≤79). J Chem Phys 124:244308

    Article  Google Scholar 

  • Carchini G, Almora N, Revilla-Lopez G, Bellarosa L, García-Muelas R, García Melchor M, Pogodin S, Błonski P, Nuria López N (2013) How theoretical simulations can address the structure and activity of nanoparticles. Top Catal 56:1262–1272

    Article  CAS  Google Scholar 

  • Chen J, Huang J, Toma A, Zhong L, Cui Z, Shao W, Li Z, Liang W, De Angelis F, Jiang L, Chi L (2017) Modulating the spatial electrostatic potential for 1D colloidal nanoparticles assembly. Adv Mater Interfaces 4:1700505

    Article  Google Scholar 

  • Denison DR (1971) Operating parameters of a quadrupole in a grounded cylindrical housing. J Vac Sci Technol 8:266–269

    Article  CAS  Google Scholar 

  • Fojan P, Hanif M, Bartling S, Hartmann H, Barke I, Popok VN (2015) Supported silver clusters as nanoplasmonic transducers for protein sensing. Sensors Actuators B 212:377–381

    Article  CAS  Google Scholar 

  • Ganeva M, Pipa AV, Smirnov BM, Kashtanov PV, Hippler R (2013) Velocity distribution of mass-selected nano-size cluster ions. Plasma Sources Sci Technol 22:045011

    Article  Google Scholar 

  • Haberland H (1994) Experimental methods. In: Haberland H (ed) Clusters of atoms and molecules. Springer-Verlag, Berlin, pp 205–252

    Google Scholar 

  • Haberland H, Karrais M, Mall M (1991) A new type of cluster and cluster ion source. Z Phys D 20:413–415

    Article  CAS  Google Scholar 

  • Haberland H, Karrais M, Mall M, Thurner Y (1992) Thin films from energetic cluster impact: a feasibility study. J Vac Sci Technol A 10:3266–3271

    Article  CAS  Google Scholar 

  • Häkkinen H, Moseler M, Kostko O, Morgner N, Hoffmann MA, von Issendorff B (2004) Symmetry and electronic structure of noble-metal nanoparticles and the role of relativity. Phys Rev Lett 93:093401

    Article  Google Scholar 

  • Hanif M, Juluri RR, Chirumamilla M, Popok VN (2016) Poly (methyl methacrylate) composites with size-selected silver nanoparticles fabricated using cluster beam technique. J Polym Sci B Polym Phys 54:1152–1159

    Article  CAS  Google Scholar 

  • Hartmann H, Popok VN, Barke I, von Oeynhausen V, Meiwes-Broer K-H (2012) Design and capabilities of an experimental setup based on magnetron sputtering for formation and deposition of size-selected metal clusters on ultra-clean surfaces. Rev Sci Instrum 83:073304

    Article  CAS  Google Scholar 

  • Huttel Y (ed) (2017) Gas-phase synthesis of nanoparticles. Wiley-VCH, Weinheim

    Google Scholar 

  • Jeon TY, Kim DJ, Park S-G, Kim S-H, Kim D-H (2016) Nanostructured plasmonic substrates for use as SERS sensors. Nano Convergence 3: 18

  • Kousal J, Shelemin A, Schwartzkopf M, Polonskyi O, Hanus J, Solar P, Vaidulych M, Nikitin D, Pleskunov P, Krtous Z, Stunskus T, Faupel F, Roth SV, Biederman H, Choukourov A (2018) Magnetron-sputtered copper nanoparticles: lost in gas aggregation and found by in situ X-ray scattering. Nanoscale 10:18275

    Article  CAS  Google Scholar 

  • Liamosa D, Ruano M, Martinez L, Mayoral A, Roman E, Garcia-Hernandez M, Huttel Y (2014) The ultimate step towards a tailored engineering of core@shell and core@shell@shell nanoparticles. Nanoscale 6:13483–13486

    Article  Google Scholar 

  • Marom S, Plesser M, Modi R, Manini N, Di Vice M (2019) Planetary’ silver nanoparticles originating from a magnetron sputter plasma. J Phys D Appl Phys 52:095301

    Article  Google Scholar 

  • McKee ML, Samokhvalov A (2017) Density functional study of neutral and charged silver clusters Agn with n=2−22. Evolution of properties and structure. J Phys Chem A 121:5018–5028

    Article  CAS  Google Scholar 

  • Momin T, Bhowmick A (2010) A new magnetron based gas aggregationsource of metal nanoclusters coupled to adouble time-of-flight mass spectrometer system. Rev Sci Instrum 81:075110

    Article  Google Scholar 

  • Nikitin D, Hanuš J, Ali-Ogly S, Polonskyi O, Drewes J, Faupel F, Biederman H, Choukourov A (2019) The evolution of Ag nanoparticles inside a gas aggregation cluster source. Plasma Proc Polym in press

  • Novikov SM, Popok VN, Evlyukhin AB, Hanif M, Morgen P, Fiutowski J, Beermann J, Rubahn H-G, Bozhevolnyi SI (2017) Highly-stable monocrystalline silver clusters for plasmonic applications. Langmuir 33:6062–6070

    Article  CAS  Google Scholar 

  • Polonskyi O, Ahadi AM, Peter T, Fujioka K, Abraham JW, Vasiliauskaite E, Hinz A, Strunskus T, Wolf S, Bonitz M, Kersten H, Faupel F (2018) Plasma based formation and deposition of metal and metal oxide nanoparticles using a gas aggregation source. Eur Phys J D 72:93

    Article  Google Scholar 

  • Popok V (2009) Energetic cluster-surface collisions. In: Sattler KD (ed) Handbook of nanophysics, V 2, clusters and fullerenes. CRC Press, Boca Raton, pp 19–1–19-19

    Google Scholar 

  • Popok VN, Hanif M, Ceynowa FA, Fojan P (2017) Immersion of low-energy deposited metal clusters into poly(methyl methacrylate). Nucl Instrum Meth Phys Res B 409:91–95

    Article  CAS  Google Scholar 

  • Pratontep S, Sj C, Xirouchaki C, Streun M, Palmer RE (2005) Size-selected cluster beam source based on radio frequency magnetron plasma sputtering and gas condensation. Rev Sci Instrum 76:045103

    Article  Google Scholar 

  • Scholl JA, Koh AL, Dionne JA (2012) Quantum plasmon resonances of individual metallic nanoparticles. Nature 483:421–427

    Article  CAS  Google Scholar 

  • Yang X, Cai W, Shao X (2007) Structural variation of silver clusters from Ag13 to Ag160. J Phys Chem A 111:5048–5056

    Article  CAS  Google Scholar 

  • Zeman HD (1977) Deflection of an ion beam in the two-dimensional electrostatic quadrupole field. Rev Sci Instrum 48:1079–1085

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Materials and Production, Aalborg University, Skjernvej 4A, 9220, Aalborg, Denmark

    Vladimir N. Popok & Leonid Gurevich

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  1. Vladimir N. Popok
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  2. Leonid Gurevich
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Correspondence to Vladimir N. Popok.

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Popok, V.N., Gurevich, L. Charge states of size-selected silver nanoparticles produced by magnetron sputtering. J Nanopart Res 21, 171 (2019). https://doi.org/10.1007/s11051-019-4615-1

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