Skip to main content
Log in

Nitriding of Molten Chromium-Manganese Steels

  • Published:
Metallurgist Aims and scope

Theoretical and experimental studies are conducted in the field of nitriding high strength nonmagnetic steels. Temperature-time correlation of the degree nitrogen assimilation and nitrogen content in steel 04Cr20Ni6Mn11Mo2NVNb in the case of alloying with nitrogencontaining manganese and chromium ferroalloys in air and during purging with nitrogen are determined by experiment. Gas phase nitriding of this steel is possible at 1450 °C during 30 min reaching a nitrogen content of 0.42%. A twostage process for lowcost nitriding is developed. In the first stage melts are purged with highpurity nitrogen to reach a nitrogen content of 0.25–0.30%. In the second stage powder alloying additions are injected into a stream of nitrogen with a melt temperature as low as possible.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

References

  1. N. P. Chizhevskii, Iron and Nitrogen [in Russian], Sibir. Tovar. Pech. Dela, Tomsk (1914).

  2. M. V. Pridantsev, N. P. Talov, and F. M. Levin, High-Strength Austenitic Steels [in Russian], Metallurgiya, Moscow (1969).

  3. L. A. Baeva, M. V. Il’ichev, A. S. Tyuftyaev, et al., “Effect of nitrogen during plasma-arc remelting on the structure and mechanical properties and corrosion resistance of stainless steel,” Stal’, No. 12, 54–56 (2017).

  4. L. M. Panfilova and L. A. Smirnov, “Microalloying vanadium-containing steel with nitrogen for engineering,” Stal,’ No. 11, 80–85 (2015).

  5. I. M. Shatokhin, M. Kh. Ziatdinov, A. V. Kutishchev, and A. V. Besmertnykh, “Prospects of preparing alloy material of a new generation by the SHS method,” Vest. Magnitogorsk. Gos. Tekhn. Univ. im G. I. Nosova, No. 3(11), 16–23 (2005).

  6. M. V. Kostina, “Development of principles of alloy Cr-N steels and creation of corrosion resistant steels of a new generation with a structure of nitrided martensite and austenite for highly loaded components of contemporary engineering,” Author’s Abs., Diss. Cand. Techn, Sci., IMET RAN, Moscow (2003).

  7. O. A. Bannykh, V. M. Blinov, M. V. Kostina, et al., RF Patent 2205889, МPК C22C 38/58, High-strength non-magnetic corrosion resistant weldable steel, Claim 03.06.2002; Publ. 06.10.2003; Bull. No. 8.

  8. O. A. Bannykh, V. M. Blinov, M. V. Kostina, et al., RF Patent 2158319, МPК C22C 38/18, High-strength corrosion-resistant and wear-resistant steel, Claim 04.25.2000; Publ. 10.27.2000; Bull. No. 30.

  9. S. I. Efimenko, V. M. Panovko, E. M. Leshchinskaya, et al., RF Patent 2116374, МPК C22C 38/58, Corrosion-resistant nonmagnetic wear-resistant steel, Claim 12.25.1996; Publ. 07.27.1998; Bull. No. 21.

  10. V. V. Averin, A. V. Revyakin, V. I. Fedorchenko, and L. N. Kozina, Nitrogen in Metals [in Russian], Metallurgiya, Moscow (1976).

  11. A. M. Samarin, “Replacement of nickel by nitrogen in high-strength steel,” Izv. Akad. Nauk SSSR, OTN, No. 1–2 (1944).

  12. V. I. Prosvirin and N. P. Agapova, “Effect of nitrogen on properties of steel with a high chromium content,” Proc. TsNIITMASh, “Nitrogen in Steel,” Mashgiz, Moscow (1950).

  13. Ts. V. Rashev, High-Nitrogen Steels. Metallurgy under Pressure [in Russian], Izd. Bolg. Akad. Nauk, Prof. Marin Drinov, Sofia (1995).

  14. I. N. Poschitz and V. A. Kolesov, Use of HighNitrogen Non-Magnetic Steel for Production of SteelAluminum Conductor: Book of Abstracts, 5th Int. Conf. High Nitrogen Steels. Espoo, Finland (1998).

  15. H. Berns, Alloy Development and Processing: Book of Abstracts, Int. Conf. High Nitrogen Steels, HNS2004 (2004).

  16. N. Nakamura, T. Tsuchiyma, and S. Takaki, Effect of Structural Factors of the Mechanical Properties of the High Nitrogen Austenitic Steels: Book of Abstracts, 5th Int. Conf. High Nitrogen Steels. Espoo, Finland (1998).

  17. H. Schenck, M. Frohberg, and H. Heinemann, “Untersuchungen zur Stickstoffaufnahme in flüssigen Eisenlegierungen im Druckbericht bis zu vier Atmosphären,” Archiv für Eisenhüttenwesen, 33, No. 9, 503–602 (1962).

    Article  CAS  Google Scholar 

  18. A. A. Smirnov, I. I. Gobachev, V. V. Popov, et al., “Study of nitrogen solubility in austenitic nitrogen steels during melting and subsequent crystallization by means of CALPHAD method,” Vopros. Materialoved., No. 4(96), 56–66 (2018).

  19. A. A. Smirnov, O. V. Zayakin, V. I. Zhuchkov, et al., “Properties and se of nitrided ferroalloys,” Proc. Pract. Conf. with Internat. Participation and Elements of the School for Young Scientists “Prospects of Metallurgy and Engineering Using Completed Fundamental Research and NIOKR, FERROSPLAVY,” OOO Izd. Tipograf. Alfa Print, Ekaterinberg (2018).

  20. L. A. Smirnov, V. A. Rovnushkin, D. S. Shul’min, et al., “Effect of temperature on nitrogen solubility if chromium-nickelmanganese steels,” Proc. Internat. Conf., “Chemical-Metallurgical Process and Materials of the Metallurgical Industry,” Volgograd (2016).

  21. L. A. Smirnov and O. V. Zayakin, “The time and heat dependence of the nitrogen distribution upon steel alloying with nitrided manganese,” Materials Science Forum, No. 946, 406–410 (2019).

    Article  Google Scholar 

  22. V. I. Zhuchkov, O. V. Zayakin, E. Yu. Lozovaya, and S. V. Lazareva, “Study of the duration of melting chromium-containing ferroalloys in steel,” Stal,’ No. 8, 75 (2008).

  23. V. I. Zhuchkov, O. V. Zayakin, E. Yu. Lozovaya, and D. S. Renev, “Study of melting alloys of the Fe–Ni–Cr system and ironcarbon melt,” Butler. Soobshch., 47, No. 8, 56–62 (2016).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. A. Smirnov.

Additional information

Translated from Metallurg, Vol. 63, No. 8, pp. 20–25, August, 2019

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Smirnov, L.A., Zayakin, O.V., Zhuchkov, V.I. et al. Nitriding of Molten Chromium-Manganese Steels. Metallurgist 63, 785–791 (2019). https://doi.org/10.1007/s11015-019-00890-z

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11015-019-00890-z

Keywords

Navigation