We studied the hydrogen permeability of the surface nanocrystalline structures formed by the mechanical-pulse treatment on 45 steel with the use of various technological media. It is shown that these structures are characterized by a much lower hydrogen permeability as compared with the untreated steel, thus revealing the formation of a large number of hydrogen traps in the course of treatment. The hardened surface layer is more susceptible to the development of dissipated damage in the course of hydrogenation but may also serve as a barrier for the penetration of hydrogen into the matrix material.
Similar content being viewed by others
References
R. Z. Valiev, R. K. Islamgaliev, and I. V. Aleksandrov, “Bulk nanostructured materials from severe plastic deformation,” Progr. Mater. Sci., 45, 103 (2000).
K. J. Kurzydlowski, “Physical, chemical, and mechanical properties of nanostructured materials,” Fiz.-Khim. Mekh. Mater., 42, No. 1, 82–89 (2006); Mater. Sci., 42, No. 1, 85–94 (2006).
R. A. Andrievskii and A. M. Glezer, “Size effects in nanocrystalline materials. II. Mechanical and physical properties,” Fiz. Met. Metalloved., 89, No. 1, 91–112 (2000).
H. Nykyforchyn, V. Kyryliv, and O. Maksymiv, “Chapter 2: Physical and mechanical properties of surface nanocrystalline structures generated by severe thermal-plastic deformation,” in: Nanocomposites, Nanophotonics, Nanobiotechnology, and Applications, Springer, Inbunden (2014), pp. 31–41.
M. A. Vasil’ev, G. I. Prokopenko, and V. S. Filatova, “Nanocrystallization of metal surfaces by the methods of severe plastic deformation (survey),” Usp. Fiz. Met., 5, 345–399 (2004).
H. M. Nykyforchyn, V. I. Kyryliv, Dz. V. Slobodjan, et al., “Structural steels surface modification by mechanical pulse treatment for corrosion protection and wear resistance,” Surf. Coating Technol., 100–101, 125–127 (1998).
V. I. Kyryliv and Yu. M. Koval’, “Surface alloying of steels from special technological media,” Fiz.-Khim. Mekh. Mater., 37, No. 5, 103–105 (2001); English translation: Mater. Sci., 37, No. 5, 138–140 (2001).
V. I. Kyryliv, “Carbon surface saturation of steels during mechanical-pulse treatment,” Fiz.-Khim. Mekh. Mater., 35, No. 6, 88–91 (1999); English translation: Mater. Sci., 35, No. 6, 853–858 (1999).
O. V. Maksymiv and H. M. Nykyforchyn, ”Effect of hydrogen on the mechanical behavior of surface nanocrystalline steel structure,” in: E-MRS 2011 Fall Meeting. Symposium C: Mechanical Properties of Nanomaterials—Experiments and Modeling (CD), University of Technology, Warsaw (2011).
E. Lunarska and K. Nikiforov, “Effect of prestraining on the behavior of hydrogen in structural steel,” Fiz.-Khim. Mekh. Mater., 43, No. 5, 65–70 (2007); English translation: Mater. Sci., 43, No. 5, 667–674 (2007).
C. S. Barrett and T. B. Massalski, Structure of Metals, 3rd edn., Pergamon, Oxford (1980).
A. I. Ivanov, Yu. O. Mezhennyi, A. E. Ostrov, and E. I. Fomicheva, “Comparative determination of dislocation density in polycrystals by the width of X-ray lines and with the use of electron microscopy,” Zavod. Lab., No. 2, 43–48 (1987).
M. A. V. Devanathan and Z. J. Stachurski, “The mechanism of hydrogen evolution on iron in acid solutions by determination of permeation rates,” Electrochem. Soc., 111, 619–623 (1964).
G. M. Pressouyre and I. M. Bernstein, “A quantitative analysis of hydrogen trapping,” Metal. Trans., 9a, 1571–1576 (1978).
J. O’M. Bockris, Stress Corrosion Cracking and Hydrogen Embrittlement of Iron Base Alloys, NACE-5, Houston, TX (1977).
A Turnbull, “Factors affecting the reliability of hydrogen permeation measurement,” Mater. Sci. Forum, 63, 192–194 (1995).
A. Turnbull, M. W. Carroll, and D. H. Ferriss, “Analysis of hydrogen diffusion and trapping in a 13% chromium martensitic stainless steel,” Acta Metal., 37, 2039–2046 (1989).
M. Iino, “A more generalized analysis of hydrogen trapping,” Acta Metall., 30, 367–375 (1982).
G. Gabetta, H. M. Nykyforchyn, E. Lunarska, et al., “In-service degradation of gas trunk pipeline X52 steel,” Fiz.-Khim. Mekh. Mater., 44, No. 1, 88–99 (2007); Mater. Sci., 44, No. 1, 104–119 (2008).
H. Nykyforchyn, E. Lunarska, O. Tsyrulnyk, et al., “Effect of the long-term service of the gas pipeline on the properties of the ferrite-pearlite steel,” Mater. Corr., 60, No. 9, 716–725 (2009).
H. Nykyforchyn, E. Lunarska, O. Tsyrulnyk, et al., “Environmentally assisted ‘in-bulk’ steel degradation of long-term service gas trunkline,” Eng. Failure Anal., 17, No. 3, 624–632 (2010).
W. S. Gorsky, “Theorie der elastischen Nachwirkung in ungeordneten Mischkristallen (elastische Nachwirkung zweiter Art),“ Phys. 7 der Sowjetunion, 8, 451–471 (1935).
E. Lunarska and O. Chernyayeva, “Effect of the self-induced strain on the hydrogen permeation through Al,” Int. J. Hydrogen Energy, 31, 285–293 (2006).
D. Kocanda, H. Nykyforchyn, E. Lunarska, and V. Kyryliv, “Effect of friction-mechanical treatment on corrosion fatigue and hydrogen behavior of low-alloy marine steels,” Fiz.-Khim. Mekh. Mater., Special Issue “Problems of Corrosion and Corrosion Protection of Materials,” No. 9, 105–110 (2012).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 50, No. 5, pp. 67–73, September–October, 2014.
Rights and permissions
About this article
Cite this article
Nykyforchyn, H.M., Lunarska, Е., Kyryliv, V.І. et al. Hydrogen Permeability of the Surface Nanocrystalline Structures of Carbon Steel. Mater Sci 50, 698–705 (2015). https://doi.org/10.1007/s11003-015-9774-3
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11003-015-9774-3