Skip to main content
Log in

Novel temperature-sensitive label based on thermochromic ink for hot food packaging and serving applications

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Changes in the lifestyle of the millennials have started a revolution in the food industry. They started preferring to have effortless ready-to-eat or cook meals (RTE) or fast-food chains and restaurants, and at the same time, they expect the food to be served hot. Nonetheless, it is impossible to know whether the desired temperature has been maintained in the RTE pouches or delivered food. Employing thermochromic materials as temperature indicators on the packaging can communicate the temperature of food inside. This work proposes a thermochromic coating composed of silver tetraiodomercurate (STIM) and cellulose acetate in the form of a coated label as a temperature indicator. From the thermochromism property of STIM, it was observed that the phase transition occurs at temperatures between 323 and 333 K. Colorimetric analysis of the labels revealed that the color changes from yellow to orange to red, indicating normal temperature and higher temperatures, respectively. Microstructural analysis of the label via FESEM reveals a uniform coating formation with traces of STIM agglomerates. Rub resistance and adhesion tests proved that the solid particles have good adhesion with the substrate and no scuffing traces. Hence, silver tetraiodomercurate-based thermochromic pigment can be used as a temperature indicator label for hot beverages, ready-to-cook retort pouches, and hot-served food delivered through apps for better communication of products’ temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Deshmukh RK, Akhila K, Ramakanth D, Gaikwad KK. Guar gum/carboxymethyl cellulose based antioxidant film incorporated with halloysite nanotubes and litchi shell waste extract for active packaging. Int J Biol Macromol. 2022;201:1–13.

    Article  CAS  PubMed  Google Scholar 

  2. Ramakanth D, Akhila K, Gaikwad KK, Maji PK. UV-activated oxygen scavenging system based on natural rubber latex from Hevea brasiliensis for active packaging applications. Ind Crops Prod. 2022;178:114658.

    Article  CAS  Google Scholar 

  3. Yousefi H, Su HM, Imani SM, Alkhaldi K, Filipe CD, Didar TF. Intelligent food packaging: a review of smart sensing technologies for monitoring food quality. ACS Sensors Am Chem Soc. 2019;4:808–21.

    Article  CAS  Google Scholar 

  4. Kumar J, Akhila K, Gaikwad KK. Recent Developments in Intelligent Packaging Systems for Food Processing Industry : a Review. Int J Food Process Technol. 2021;12:21–3.

    Google Scholar 

  5. Kumar A, Gupta V, Singh S, Saini S, Gaikwad KK. Pine needles lignocellulosic ethylene scavenging paper impregnated with nanozeolite for active packaging applications. Ind Crops Prod. 2021;170:113752.

    Article  CAS  Google Scholar 

  6. Kumar L. Edible films and coatings for food packaging applications: a review. Environ Chem Lett Springer. 2021;1:1–26.

    Google Scholar 

  7. Sharma R, Ghoshal G. Emerging trends in food packaging. Nut Food Sci. 2018;48:764.

    Article  Google Scholar 

  8. Gaikwad KK, Deshmukh RK, Lee YS. Natural phenolic compound coated oxygen scavenging active polyolefin film for preserving quality of fish cake. Biomass Convers Biorefinery. 2022. https://doi.org/10.1007/s13399-022-02678-9.

    Article  Google Scholar 

  9. Poyatos-Racionero E, Ros-Lis JV, Vivancos JL, Martínez-Máñez R. Recent advances on intelligent packaging as tools to reduce food waste. J Clean Prod. 2018;172:3398–409.

    Article  Google Scholar 

  10. Gaikwad KK, Singh S, Lee YS. Oxygen scavenging films in food packaging. Environ Chem Lett. 2018;16:523–38.

    Article  CAS  Google Scholar 

  11. Singh S, Gaikwad KK, Lee YS. Anthocyanin – A Natural Dye for Smart Food Packaging Systems. Korean J Packag Sci Technol. 2018;24:167–80.

    Article  Google Scholar 

  12. Arman Kandirmaz E, Ozcan A, Er UD. Production of thermochromic microcapsulated inks for smart packaging and examination of printability properties. Pigment Resin Technol. 2020;49:273–81.

    Article  CAS  Google Scholar 

  13. De Bastiani M, Saidaminov MI, Dursun I, Sinatra L, Peng W, Buttner U, et al. Thermochromic perovskite inks for reversible smart window applications. Chem Mater Am Chem Soc. 2017;29:3367–70.

    Google Scholar 

  14. Anbukarasu P, Sauvageau D, Elias AL. Time-temperature indicator based on enzymatic degradation of dye-loaded polyhydroxybutyrate. Biotechnol J. 2017;12:1700050.

    Article  Google Scholar 

  15. Raditoiu V, Radovici C, Raditoiu A, Nicolae CA, et al. Switching behavior of thermochromic copper and silver tetraiodomercurate embedded in silica hybrid materials. Opt Mater. 2013;35:2565–72.

    Article  CAS  Google Scholar 

  16. Soofivand F, Salavati-Niasari M. “Ag2HgI4” a thermochromic compound with superionic conducting properties: Synthesis, characterization and investigation of graphene-based nanocomposites. J Mol Liq. 2018;252:112–20.

    Article  CAS  Google Scholar 

  17. Gavilà L, Esposito D. Cellulose acetate as a convenient intermediate for the preparation of 5-acetoxymethylfurfural from biomass. Green Chem. 2017;19:2496–500.

    Article  Google Scholar 

  18. Huang S, Xiao J, Zhu Y, Qu J. Synthesis and properties of spray-applied high solid content two component polyurethane coatings based on polycaprolactone polyols. Prog Org Coatings. 2017;106:60–8.

    Article  CAS  Google Scholar 

  19. Hameed TA, Radaf IME, Sakr GB. Synthesis and characterization of thermochromic Ag2HgI4 thin films. Appl Phys A Mater Sci Process. 2018;124:0.

    Article  CAS  Google Scholar 

  20. Andrés E, Palacios JM, Tascón JMD. Characterization of precipitates formed from the tetraiodomercurate (II) anion and mercury(I) or silver(I) cations. J Chem Soc Faraday. 1995;91:1217–21.

    Article  Google Scholar 

  21. Kamal T, Ahmad I, Khan SB, Asiri AM. Synthesis and catalytic properties of silver nanoparticles supported on porous cellulose acetate sheets and wet-spun fibers. Carbohydr Polym. 2017;157:294–302.

    Article  CAS  PubMed  Google Scholar 

  22. Arthanareeswaran G, Thanikaivelan P, Srinivasn K, Mohan D, Rajendran M. Synthesis, characterization and thermal studies on cellulose acetate membranes with additive. Eur Polym J Pergamon. 2004;40:2153–9.

    Article  CAS  Google Scholar 

  23. Bruna JE, Galotto MJ, Guarda A, Rodríguez F. A novel polymer based on MtCu2+/cellulose acetate with antimicrobial activity. Carbohydr Polym. 2014;102:317–23.

    Article  CAS  PubMed  Google Scholar 

  24. Sharma B, Sauraj S, Kumar B, Pandey A, Dutt D, Negi YS, et al. Synthesis of waterborne acrylic copolymer resin as a binding agent for the development of water-based inks in the printing application. Polym Eng Sci. 2021;61:1569–80.

    Article  CAS  Google Scholar 

  25. Nielsen KH, Karlsson S, Limbach R, Wondraczek L. Quantitative image analysis for evaluating the abrasion resistance of nanoporous silica films on glass. Sci Rep. 2015;5:1–10.

    Article  Google Scholar 

  26. Lee YI, Choa YH. Adhesion enhancement of ink-jet printed conductive copper patterns on a flexible substrate. J Mater Chem. 2012;22:12517–22.

    Article  CAS  Google Scholar 

  27. Chocolatl-Torres M, Franco-Bacca AP, Ramírez-Rincón JA, Gómez-Heredia CL, Cervantes-Alvarez F, Alvarado-Gil JJ, et al. Study of structural and optical properties of the thermochromic silver and copper tetraiodomercurates (Ag2, Cu2) HgI4 ceramics. Appl Phys A Mater Sci Process. 2020;126:1–9.

    Article  Google Scholar 

Download references

Acknowledgements

Author Kirtiraj K. Gaikwad would like to sincerely thank the Science and Engineering Research Board (SERB), Government of India, for the financial support provided under the Start-Up Research Grant (SRG) (SRG/2021/001549).

Author information

Authors and Affiliations

Authors

Contributions

JK: Investigation, Formal analysis, Visualization, Data curation, Writing—Original Draft, KA: Investigation, Formal analysis, Visualization, Data curation Pardeep Kumar: Investigation, Formal analysis Experimental, Resources, RKDe: Experimental, KK. Gaikwad: Conceptualization, Methodology, Resources, Writing—Original Draft, Manuscript editing and review, Supervision, Project administration, Funding acquisition.

Corresponding author

Correspondence to Kirtiraj K. Gaikwad.

Ethics declarations

Conflict of interest

The authors declare that there are no conflicts of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kumar, J., Akhila, K., Kumar, P. et al. Novel temperature-sensitive label based on thermochromic ink for hot food packaging and serving applications. J Therm Anal Calorim 148, 6061–6069 (2023). https://doi.org/10.1007/s10973-023-12147-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-023-12147-8

Keywords

Navigation