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Study on the preparation of high adsorption activated carbon material and its application as phase change energy storage carrier material

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Abstract

A three-dimensional porous activated carbon (HSAC) with high adsorption properties was prepared by using hemp straw as raw material and phosphotungstate as catalyst through low-temperature hydrothermal carbonization combined with KOH high-temperature activation technology. The maximum specific surface area of activated carbon material was 2310.1 m2 g–1, and the maximum adsorption capacity of methylene blue was 2424.2 mg g–1. A series of PEG/HSAC phase change energy storage materials with different mass ratios were prepared by physical blending impregnation by using polyethylene glycol (PEG) as phase change material and porous activated carbon as carrier. Through the study of activated carbon pore structure, energy storage material structure analysis, and DSC comparative analysis, the experimental results showed that PEG and HSAC mass ratio (60/40) was the best. The latent heat of the composite was 51.5 J g–1, and the phase change temperature was 58.5 ℃. No obvious leakage occurred after 20 heat cycles. Composite phase change materials had potential applications in the field of intelligent buildings.

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References

  1. Amaducci S, Scordia D, Liu F-H, Zhang Q, Guo H, Testa G, Cosentino SL. Key cultivation techniques for hemp in Europe and China. Ind Crops Prod. 2015;68:2–16.

    Article  CAS  Google Scholar 

  2. Feng J-Y, Zhang J-C. Preparation and oil/air filtration properties of hemp paper. J Ind Text. 2015;45(1):3–32.

    Article  CAS  Google Scholar 

  3. Deng Q, Li C-Y, Deng Z-H, Zheng M-F, Li Y-M, Liu P-Q. Adsorption of activated carbon to Zn2+ and Cd2+ in heavy metal wastewater. New Chem Mater. 2019;4:204–7.

    Google Scholar 

  4. Li Y-L, Jo D, Kokogiannakis G, et al. Phase change material blind system for double skin façade integration: System development and thermal performance evaluation. Appl Energy. 2019;252:11–5.

    Article  Google Scholar 

  5. Su W-G, Jo D, Kokogiannakis G. Review of solid–liquid phase change materials and their encapsulation technologies. Renew Sustain Energy Rev. 2015;48:373–91.

    Article  CAS  Google Scholar 

  6. Darkwa J. O Sut Zhou. Development of non-deform micro-encapsulated phase change energy storage tablets. 2012;98:441–7.

    Google Scholar 

  7. Mesalhy O, Lafdi K, Elgafy A. Carbon foam matrices saturated with PCM for thermal protection purposes. Carbon. 2006;44(10):2080–8.

    Article  CAS  Google Scholar 

  8. Senthilkumar ST, Senthilkumar B, Balaji S, Sanjeeviraja C, Selvan RK. Preparation of activated carbon from sorghum pith and its structural and electrochemical properties. Mater Res Bull. 2011;46(3):413–9.

    Article  CAS  Google Scholar 

  9. Kruk M, Kohlhaas KM, Dufour B, et al. Partially graphitic high-surface-area mesoporous carbons from polyacrylonitrile templated by ordered and disordered mesoporous silicas. Microporous Mesoporous Mater. 2007;102(1–3):178–87.

    Article  CAS  Google Scholar 

  10. Yang J, Qiu K. Preparation of activated carbons from walnut shells via vacuum chemical activation and their application for methylene blue removal. Chem Eng J. 2010;165(1):209–17.

    Article  CAS  Google Scholar 

  11. Mahmoudi K, Hosni K, Hamdi N, et al. Kinetics and equilibrium studies on removal of methylene blue and methyl orange by adsorption onto activated carbon prepared from date pits-A comparative study [J]. Korean J Chem Eng. 2015;32(2):274–83.

    Article  CAS  Google Scholar 

  12. Senthilkumaar S, Varadarajan PR, Porkodi K, et al. Adsorption of methylene blue onto jute fiber carbon: kinetics and equilibrium studies. J Colloid Interface Sci. 2005;284(1):78–82.

    Article  CAS  Google Scholar 

  13. Bedin KC, Martins AC, Cazetta André L, et al. KOH-activated carbon prepared from sucrose spherical carbon: adsorption equilibrium, kinetic and thermodynamic studies for methylene blue removal. Chem Eng J. 2016;286:476–84.

    Article  CAS  Google Scholar 

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Correspondence to Xiao-Ming Zhou.

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Zhou, XM., Liu, YF. Study on the preparation of high adsorption activated carbon material and its application as phase change energy storage carrier material. J Therm Anal Calorim 147, 8169–8176 (2022). https://doi.org/10.1007/s10973-021-11122-5

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  • DOI: https://doi.org/10.1007/s10973-021-11122-5

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